Lead-antimony sulfosalts from Tuscany (Italy): II - Crystal structure of scainiite, Pb14Sb30S54O5, an expanded monoclinic derivative of Ba12Bi24S48 hexagonal sub-type (zinkenite group)

European Journal of Mineralogy

Volumn 12, Issue 4, 2000, Pages 835-846

  Moëlo, Yves ^a   Meerschaut, Alain ^a   Orlandi, Paolo ^b   Palvadeau, Pierre ^a  

^a INSTITUT DES MATÉRIAUX JEAN ROUXEL   (France)

^b UNIVERSITY OF PISA   (Italy)

Author keywords

Crystal structure; Lead antimony sulfosalt; Oxysulfide; Scainiite; Zinkenite group

Indexed keywords

BARIUM COMPOUNDS; BISMUTH COMPOUNDS; CHROMIUM COMPOUNDS; CRYSTAL ATOMIC STRUCTURE; CRYSTAL STRUCTURE; IV-VI SEMICONDUCTORS; LAYERED SEMICONDUCTORS; LEAD COMPOUNDS; SINGLE CRYSTALS; SULFUR COMPOUNDS; TIN COMPOUNDS;

HEXAGONAL CHANNELS; OXYSULFIDE; PARENT STRUCTURE; SCAINIITE; SINGLE CRYSTAL X-RAY DATA; STRUCTURE ANALYSIS; SULFOSALTS; ZINKENITE GROUP;

ANTIMONY COMPOUNDS;

ANTIMONY; CRYSTAL STRUCTURE; LEAD; SULFOSALT;

ITALY; TUSCANY;

EID: 0343192509     PISSN: 09351221     EISSN: None     Source Type: Journal    
DOI: 10.1127/0935-1221/2000/0012-0835     Document Type: Article

References (22)

1. 4. Acta Chem. Scand., A37, 399-407.
2. 2, the synthetic analogue of pääkkönenite. Am. Mineral., 80, 1054-1058.
3. Brese, N. E. & O'Keeffe, M. (1991): Bond-valence parameters for solids. Acta Cryst., B47, 192-197.
4. 2. J. Solid State Chem., 116, 61-67.
5. 2O. Sond. Zeit. Naturwiss., 5, S. 114, 1-2.
6. 4. Acta Cryst., C42, 259-261.
7. Makovicky, E. (1985): Cyclically twinned sulphosalt structures and their approximate analogues. Z. Kristallogr., 173, 1-23.
8. _ (1989): Modular classification of sulphosalts - current status. Definition and application of homologous series. N. Jb. Miner. Abh., 160, 269-297.
9. _ (1993): Rod-based sulphosalt structures derived from the SnS and PbS archetypes. Eur. J. Mineral., 5, 545-591.
10. 24, and its implications for the andorite group and zinckenite. N. Jb. Miner. Abh., 147, 58-79.
11. Moëlo, Y. (1979): Quaternary compounds in the system Pb-Sb-S-Cl: dadsonite and synthetic phases. Can. Mineral., 17, 595-600.
12. _ (1983): Contribution à l'étude des conditions naturelles de formation des sulfures complexes d'antimoine et plomb. B.R.G.M. ed., Orléans, Document 55, 624 p.
13. 7: structural relationships and genesis of complex lead sulfosalt structures. Can. Mineral., 35, 1497-1508.
14. 5, the first Pb-Sb oxy-sulfosalt, from Buca della Vena mine. Eur. J. Mineral., 11, 949-954.
15. 5. Acta Cryst., B49, 258-266.
16. 27. Z. Kristallogr., 141, 79-96.
17. 2. Acta Cryst., B51, 275-287.
18. 2. Acta Cryst., B52, 389-397.
19. Sheldrick, G.M. (1996): SHELXTL Version 5. An integrated system for solving, refining and displaying crystal structures from diffraction data. Siemens Analytical X-ray Instruments Inc., Madison, Wisconsin (U.S.A.).
20. Stoe (1996): Imaging Plate Diffractometer System, version 2.75. Stoe & Cie edit., Darmstadt (Germany).
21. 3 structure type. Chem. Mater., 6, 1700-1704.
22. 2. Mat. Res. Bull., 27, 563-572.