Rhodium (II)-Catalyzed Reactions of α-Aryl-α-diazo ketones. Stereoselective Synthesis of Ketoepoxides Related to anti-HIV Compounds

Synlett

Volumn 1996, Issue 11, 1996, Pages 1134-1136

  Fernandez Mateos A ^a   Pascual Coca, G ^a   Perez Alonso J J ^a   Rubio Gonzalez R ^a   Tapia Hernandez C ^a  

^a UNIVERSITY OF SALAMANCA   (Spain)

Author keywords

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Indexed keywords

EID: 0342881493     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-1996-5677     Document Type: Article

References (18)

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13. Taber, D.F.; You, K.K.; Rheingold, A.L. J. Am. Chem.Soc. 1996, 118, 547.
14. Overall yields 1 → 8 a (41%), b (33%), c (25%).
15. Overall yields 8 → 12 a (75%), b (64%), c (70%).
16. Fernández-Mateos, A.; de la Fuente, J.A. J. Org. Chem. 1990, 55, 1349.
17. 2 (2 ml). The mixture was evaporated under vacuo. Chromatography (hexane-ether 9-1) of the residue afforded the dimer 9 (24 mg, 10%) as a yellow liquid and indenone 8 (47 mg, 62%) as a colorless liquid.
18. 3: C, 71.54; H, 6.46. Found: C, 71.57; H, 6.44.