Multiple glass transition and nanophase separation in poly(ra-alkyl methacrylate) homopolymers

Macromolecules

Volumn 32, Issue 19, 1999, Pages 6278-6282

  Beiner, M ^a   Schroter K ^a   Hempel, E ^a   Reissig, S ^a   Donth, E ^a  

^a MARTIN LUTHER UNIVERSITY HALLE WITTENBERG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ANNEALING; CHEMICAL BONDS; DIELECTRIC PROPERTIES; DIFFERENTIAL SCANNING CALORIMETRY; ELASTIC MODULI; FREE RADICAL POLYMERIZATION; GLASS TRANSITION; PHASE SEPARATION; POLYETHYLENES; SPECTROSCOPY; TEMPERATURE; X RAY SCATTERING;

HOMOPOLYMERS; NANOPHASE SEPARATION; POLYALKYL METHACRYLATE; POLYETHYLENE LIKE GLASS TRANSITION; SHEAR CURVES;

ORGANIC POLYMERS;

EID: 0342732864     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma981780n     Document Type: Article

References (64)

1. Hoff, E. A. W.; Robinson, D. W.; Willbourn, A. H. J. Polym. Sei. 1955, 18, 161.
2. Dannhauser, W.; Child, W. C.; Ferry, J. D. J. Colloid Sei. 1958, 13, 103;
3. Meyer, H. H.; Mangin, P.-M.; Ferry, J. D. J. Polym. Sei. 1965, 3, 1785;
4. Ferry, J. D., Strella, S. J. Colloid Sei. 1958, 13, 459.
5. Strella, S., Zand, R. J. Polym. Sei. 1957, 25, 97, 105.
6. Mikhailov, G. P.J. Polym. Sei. 1958, 30, 605.
7. Ishida, Y.; Yamafuji, K. Kolloid-Z. 1961, 777, 98.
8. Heijboer, J. In Physics of Non-Crystalline Solids; Prins, J. A., Ed.; North-Holland: Amsterdam, 1965; p 231; Heijboer, J. Makromol. Cliem. 1960, 35A, 86.
9. Williams, G. Trans. Faraday Soc. 2 1966, 62,2091.
10. Williams, G.; Edwards, D. A. Trans. Faraday Soc. 2 1966, 62, 1329.
11. Williams, G.; Watts, D. C. Trans. Faraday Soc. 2 1971, 67, 2793.
12. Rogers, S. S.; Mandelkern, L. J. Phys. Chem. 1957, 61, 985.
13. Haldon, R. A.; Simha, J. J. Appl. Phys. 1968, 39, 1890.
14. McCrum, N. G.; Read, B. E., Williams, G. Anelastic and Dielectric Effects in Polymeric Solids; Wiley: London, 1967.
15. Heijboer, J.; Pineri, M. In Nonmetallic Materials and Composites of Low Temperatures 2; Hartwig, G., Evans, D., Eds.; Plenum Press: New York, 1982; p 89.
16. Heijboer, J. Stat. Dyn. Prop. Polym.'Solid State 1982, 94, 197.
17. r (C=18) ≈ -125 °C). An additional loss peak at ≈-50°C was also observed by Hoff et al. in poly(stearyl methacrylate).
18. Pineri, M.; Beticat, P.; Marchai, E. J. Polym. Sei., Polym. Phys. Ed. 1976, 14, 1325.
19. Baralles-Rienda, J. M.; Gonzâles de la Campa, J. I. J. Macromol. Sci.-Phys. 1980, B18, 625.
20. Cowie, J. M. G.; Haq, Z.; McEwen, I. J.; Velîckovic, J. Polymer 1981,22, 327.
21. Cowie, J. M. G.; Henshall, S. A. E.; McEwen, I. J.; Velîckovic, J. Polymer 1977, 18, 612.
22. Meier, G.; Fytas, G.; Dorfmüller, T. Macromolecules 1984, 17, 957.
23. Fytas, G.; Wang, C. H.; Fischer, E. W. Macromolecules 1988,21,2253.
24. Giebel, L.; Meier, G.; Fytas, G.; Fischer, E. W. J. Polym. Sei. B: Polym. Phys. 1992,30, 1291.
25. Meier, G.; Kremer, F.; Fytas, G.; Rizos, A. J. Polym. Sei. B: Polym. Phys. 1996, 34, 1391.
26. Patterson, G. D.; Stevens, J. R.; Lindsey, C. P. J. Macromol. Sci.-Phys. 1980, BIS, 641. Patterson, G. D.; Carroll, P. J.; Stevens, J. R. J. Polym. Sei., Polym. Phys. Ed. 1983,21,613.
27. Patterson, G. D.; Jue, P. K; Ramsay, D. J.; Stevens, J. R. J. Polym. Sei. B: Polym. Phys. 1994, 32, 1137.
28. Hwang, Y.; Patterson, G. D.; Stevens, J. R. J. Polym. Sei. B: Polym. Phys. 1996, 34, 2291.
29. Gömez Ribelles, J. L.; Monleön Pradas, M.; Vidaurre Garayo, A.; Romero Colomer, F.; Mas Estellés, J.; Meseguer Duefias, J. M. Macromolecules 1995,28,5878.
30. Tribone, J. J.; O'Reilly, J. M.; Greener, J. Macromolecules 1986, 19, 1732.
31. Hempel, E.; Beiner, M.; Renner, T.; Donth, E. Acta Polym. 1996, 47, 525.
32. Garwe, F.; Schönhals, A.; Beiner, M.; Schröter, K.; Donth, E. J. Phys.: Condens. Matter 1994, 6, 6941.
33. Garwe, F.; Schönhals, A.; Lockwenz, H.; Beiner, M.; Schröter, K.; Donth, E. Macromolecules 1996, 29, 247.
34. Beiner, M.; Kahle, S.; Hempel, E.; Schröter, K; Donth, E. Europhys. Lett. 1998,44,321;
35. Macromoleules 1998 31,8973.
36. Bergman, R.; Alvarez, F.; Alegria, A.; Colmenero, J. J. Chem. Phys. 1998, 709, 7546;
37. J. Non-Cryst. Solids 1998,235-237, 580.
38. Schmidt-Rohr, K; Kudlik, A. S.; Beckham, H. W.; Ohlcmacher, A.; Pawelzik, U.; Boeffel, C.; Spiess, H. W. Macromolecules 1994, 27, 4733.
39. Kudlik, A. S.; Beckham. H. W.: Schmidt-Rohr, K; Radloff, D.; Pawelzik, U.; Boeffel, C.; Spiess, H. W. Macromolecules 1994,27,4746.
40. Kuebler, S. C.; Schaefer, D. J.; Boeffel, C.; Pawelzik, U.; Spiess, H. W. Macromolecules 1997, 30, 6597.
41. Floudas, G.; Placke, P.; Stepanek, P.; Brown, W.; Fytas, G.; Ngai, K. L. Macromolecules 1995, 28, 6799.
42. Floudas, G.; Stepanek, P. Macromolecules 1998, 31, 6951.
43. Ute, K; Miyatake, N.; Hatada, K. Polymer 1995, 36, 1415.
44. Thompson, E. V. J. Polym. Sei. A-2 1966, 4, 199.
45. Reissig, S., .Beiner, M.; Zeeb, S.; Höring, S.; Donth, E. Macromolecules 1999, 32, 5701.
46. Cowie, J. M. G. J. Macromol. Sti.-Phys. 1980, BIS, 569.
47. Beiner, M.; Garwe, F.; Schröter, K.; Donth, E. Colloid Polym. Sei. 1994, 272, 1439.
48. Böhmer, R.; Ngai, K. L.; Angell, C. A.; Plazek, D. J. J. Chem. Phys. 1993, 99, 4201.
49. Kahle, S., Hempel, E.; Beiner, M.; Unger, R.; Schröter, K.; Donth, E. J. Mol. Struct. 1999, 479, 179.
50. Adam, G.; Gibbs, J. H. J. Chem. Phys. 1965, 43,139.
51. Donth, E. J. Non-Cryst. Solids 1982, 53, 325.
52. Kishimoto, K; Suga, H.; Seki, S. Bull. Chem. Soc. Jpn. 1973, 46, 3020.
53. Fredrickson, G. H.; Bates, F. S. Annu. Rev. Mater. Sei. 1996, 26, 501.
54. Bates, F. S., Fredrickson, G. H. Annu. Rev. Phys. Chem. 1990 41, 525.
55. Donth, E. Relaxation and Thermodynamics in Polymers. Glass Transition; Akademie: Berlin, 1992.
56. Miller, R. L.; Bbyer, R. F.; Heijboer, J. J. Polym. Sei., Polym. Phys. Ed. 1984, 22, 2021.
57. The characteristic lengths of the glass transitions in polyfadecyl methacrylate) estimated by the fluctuation formula34 are about 0.8 and 0.6 nm for a and O.PE, respectively.
58. Havriliak, S., Polymer 1968, 9, 289.
59. Donth, E. J. Polym. Sei. B, Polym. Phys. 1996, 34, 2881.
60. Tracht, U.; Wilhelm, M.; Heuer, A.; Feng, F.; Schmidt-Rohr, K.; Spiess, H. W. Phys. Rev. Lett. 1998, 81, 2727.
61. Arbe, A; Colmenero, J.; Monkenbusch, M.; Richter, D. Phys. Rev. Lett. 1998, 81, 590; 1999, 82,1336.
62. Heuer, A.; Spiess, H. W. Phys. Rev. Lett. 1999, 82, 1335.
63. Sillescu, H. J. Non-Cryst. Solids 1999, 243, 81.
64. Note added in proof. A review on related topics was recently published by: Chen, W.; Wunderlich, B. Macromol. Chem. Phys. 1999, 200, 283.