Energy disposal in collisions of nitric oxide with molecular adlayers on transition metal single crystal surfaces: Translational energy disposal

Journal of Chemical Physics

Volumn 112, Issue 13, 2000, Pages 6031-6039

  Ainsworth, M K ^a   McCombie, J ^a   McCoustra, M R S ^a   Chesters, M A ^a  

^a UNIVERSITY OF NOTTINGHAM   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0342715606     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.481176     Document Type: Article

References (49)

1. (a) Dynamics of Gas-Surface Interactions, edited by C. T. Rettner and M. N. R. Ashfold (The Royal Society of Chemistry, Cambridge, 1991);
2. (b) Dynamics at the Gas-Solid Interface, Faraday Discussion Number 96 (The Royal Society of Chemistry, Cambridge, 1993);
3. (c) Heterogeneous Reaction Dynamics, S. L. Bernasek (VCH, New York, 1995);
4. (d) Catalysis and Surface Science at High Resolution, Faraday Discussion Number 105 (The Royal Society of Chemistry, Cambridge, 1996).
5. See for example (a) R. G. Bray, R. M. Hochstrasser, and J. E. Wessel, Chem. Phys. Lett. 27, 167 (1974); (b) W. M. Jackson and C. S. Lin, Int. J. Chem. Kinet. 10, 945 (1978); E. R. Sirkin, M. Asscher, and Y. Haas, Chem. Phys. Lett. 86, 265 (1982); F. Lahmani, C. Lardeux, D. Solgadi, A. Zehnacker, I. Dimicoli, M. Boivineua, M. Mons, and F. Piozzi, J. Phys. Chem. 89, 5646 (1985); (e) Y. Anezali, T. Ebata, N. Mikami, and M. Ito, Chem. Phys. 97, 153 (1985); (f) J. C. Miller and R. N. Compton, J. Chem. Phys. 84, 675 (1986); (g) J. W. J. Verschur, J. Kimman, H. B. van Linden van den Heuvell, and M. J. van der Weil, Chem. Phys. 103, 359 (1986); (h) D. C. Jacobs, R. J. Madix, and R. N. Zare, J. Chem. Phys. 85, 5469 (1986).
6. See for example (a) R. G. Bray, R. M. Hochstrasser, and J. E. Wessel, Chem. Phys. Lett. 27, 167 (1974); (b) W. M. Jackson and C. S. Lin, Int. J. Chem. Kinet. 10, 945 (1978); E. R. Sirkin, M. Asscher, and Y. Haas, Chem. Phys. Lett. 86, 265 (1982); F. Lahmani, C. Lardeux, D. Solgadi, A. Zehnacker, I. Dimicoli, M. Boivineua, M. Mons, and F. Piozzi, J. Phys. Chem. 89, 5646 (1985); (e) Y. Anezali, T. Ebata, N. Mikami, and M. Ito, Chem. Phys. 97, 153 (1985); (f) J. C. Miller and R. N. Compton, J. Chem. Phys. 84, 675 (1986); (g) J. W. J. Verschur, J. Kimman, H. B. van Linden van den Heuvell, and M. J. van der Weil, Chem. Phys. 103, 359 (1986); (h) D. C. Jacobs, R. J. Madix, and R. N. Zare, J. Chem. Phys. 85, 5469 (1986).
7. See for example (a) R. G. Bray, R. M. Hochstrasser, and J. E. Wessel, Chem. Phys. Lett. 27, 167 (1974); (b) W. M. Jackson and C. S. Lin, Int. J. Chem. Kinet. 10, 945 (1978); E. R. Sirkin, M. Asscher, and Y. Haas, Chem. Phys. Lett. 86, 265 (1982); F. Lahmani, C. Lardeux, D. Solgadi, A. Zehnacker, I. Dimicoli, M. Boivineua, M. Mons, and F. Piozzi, J. Phys. Chem. 89, 5646 (1985); (e) Y. Anezali, T. Ebata, N. Mikami, and M. Ito, Chem. Phys. 97, 153 (1985); (f) J. C. Miller and R. N. Compton, J. Chem. Phys. 84, 675 (1986); (g) J. W. J. Verschur, J. Kimman, H. B. van Linden van den Heuvell, and M. J. van der Weil, Chem. Phys. 103, 359 (1986); (h) D. C. Jacobs, R. J. Madix, and R. N. Zare, J. Chem. Phys. 85, 5469 (1986).
8. See for example (a) R. G. Bray, R. M. Hochstrasser, and J. E. Wessel, Chem. Phys. Lett. 27, 167 (1974); (b) W. M. Jackson and C. S. Lin, Int. J. Chem. Kinet. 10, 945 (1978); E. R. Sirkin, M. Asscher, and Y. Haas, Chem. Phys. Lett. 86, 265 (1982); F. Lahmani, C. Lardeux, D. Solgadi, A. Zehnacker, I. Dimicoli, M. Boivineua, M. Mons, and F. Piozzi, J. Phys. Chem. 89, 5646 (1985); (e) Y. Anezali, T. Ebata, N. Mikami, and M. Ito, Chem. Phys. 97, 153 (1985); (f) J. C. Miller and R. N. Compton, J. Chem. Phys. 84, 675 (1986); (g) J. W. J. Verschur, J. Kimman, H. B. van Linden van den Heuvell, and M. J. van der Weil, Chem. Phys. 103, 359 (1986); (h) D. C. Jacobs, R. J. Madix, and R. N. Zare, J. Chem. Phys. 85, 5469 (1986).
9. See for example (a) R. G. Bray, R. M. Hochstrasser, and J. E. Wessel, Chem. Phys. Lett. 27, 167 (1974); (b) W. M. Jackson and C. S. Lin, Int. J. Chem. Kinet. 10, 945 (1978); E. R. Sirkin, M. Asscher, and Y. Haas, Chem. Phys. Lett. 86, 265 (1982); F. Lahmani, C. Lardeux, D. Solgadi, A. Zehnacker, I. Dimicoli, M. Boivineua, M. Mons, and F. Piozzi, J. Phys. Chem. 89, 5646 (1985); (e) Y. Anezali, T. Ebata, N. Mikami, and M. Ito, Chem. Phys. 97, 153 (1985); (f) J. C. Miller and R. N. Compton, J. Chem. Phys. 84, 675 (1986); (g) J. W. J. Verschur, J. Kimman, H. B. van Linden van den Heuvell, and M. J. van der Weil, Chem. Phys. 103, 359 (1986); (h) D. C. Jacobs, R. J. Madix, and R. N. Zare, J. Chem. Phys. 85, 5469 (1986).
10. See for example (a) R. G. Bray, R. M. Hochstrasser, and J. E. Wessel, Chem. Phys. Lett. 27, 167 (1974); (b) W. M. Jackson and C. S. Lin, Int. J. Chem. Kinet. 10, 945 (1978); E. R. Sirkin, M. Asscher, and Y. Haas, Chem. Phys. Lett. 86, 265 (1982); F. Lahmani, C. Lardeux, D. Solgadi, A. Zehnacker, I. Dimicoli, M. Boivineua, M. Mons, and F. Piozzi, J. Phys. Chem. 89, 5646 (1985); (e) Y. Anezali, T. Ebata, N. Mikami, and M. Ito, Chem. Phys. 97, 153 (1985); (f) J. C. Miller and R. N. Compton, J. Chem. Phys. 84, 675 (1986); (g) J. W. J. Verschur, J. Kimman, H. B. van Linden van den Heuvell, and M. J. van der Weil, Chem. Phys. 103, 359 (1986); (h) D. C. Jacobs, R. J. Madix, and R. N. Zare, J. Chem. Phys. 85, 5469 (1986).
11. See for example (a) R. G. Bray, R. M. Hochstrasser, and J. E. Wessel, Chem. Phys. Lett. 27, 167 (1974); (b) W. M. Jackson and C. S. Lin, Int. J. Chem. Kinet. 10, 945 (1978); E. R. Sirkin, M. Asscher, and Y. Haas, Chem. Phys. Lett. 86, 265 (1982); F. Lahmani, C. Lardeux, D. Solgadi, A. Zehnacker, I. Dimicoli, M. Boivineua, M. Mons, and F. Piozzi, J. Phys. Chem. 89, 5646 (1985); (e) Y. Anezali, T. Ebata, N. Mikami, and M. Ito, Chem. Phys. 97, 153 (1985); (f) J. C. Miller and R. N. Compton, J. Chem. Phys. 84, 675 (1986); (g) J. W. J. Verschur, J. Kimman, H. B. van Linden van den Heuvell, and M. J. van der Weil, Chem. Phys. 103, 359 (1986); (h) D. C. Jacobs, R. J. Madix, and R. N. Zare, J. Chem. Phys. 85, 5469 (1986).
12. See for example (a) R. G. Bray, R. M. Hochstrasser, and J. E. Wessel, Chem. Phys. Lett. 27, 167 (1974); (b) W. M. Jackson and C. S. Lin, Int. J. Chem. Kinet. 10, 945 (1978); E. R. Sirkin, M. Asscher, and Y. Haas, Chem. Phys. Lett. 86, 265 (1982); F. Lahmani, C. Lardeux, D. Solgadi, A. Zehnacker, I. Dimicoli, M. Boivineua, M. Mons, and F. Piozzi, J. Phys. Chem. 89, 5646 (1985); (e) Y. Anezali, T. Ebata, N. Mikami, and M. Ito, Chem. Phys. 97, 153 (1985); (f) J. C. Miller and R. N. Compton, J. Chem. Phys. 84, 675 (1986); (g) J. W. J. Verschur, J. Kimman, H. B. van Linden van den Heuvell, and M. J. van der Weil, Chem. Phys. 103, 359 (1986); (h) D. C. Jacobs, R. J. Madix, and R. N. Zare, J. Chem. Phys. 85, 5469 (1986).
13. See for example (a) A. W. Kleyn, A. C. Luntz, and D. J. Auerbach, Phys. Rev. Lett. 47, 1169 (1981); (b) A. C. Luntz, A. W. Kleyn, and D. J. Auerbach, J. Chem. Phys. 76, 737 (1982); A. W. Kleyn, A. C. Luntz, and D. J. Auerbach, Surf. Sci. 117, 33 (1982); M. Asscher and G. A. Somorjai, in Dynamics on Surfaces, edited by B. Pullman et al. (D. Reidel Publishing, Utrecht, 1984), p. 117; (e) J. Misewich, H. Zacharias, and M. M. T. Loy, in Laser Spectrosropy VII, edited by T. W. Hänsch and Y. R. Shen (Springer-Verlag, Berlin, 1985), p. 333; (f) R. J. Hamers, P. L. Houston, and R. P. Merrill, J. Chem. Phys. 88, 6548 (1988); (g) D. C. Jacobs, K. W. Kolasinski, S. F. Shane, and R. N. Zare, ibid. 91, 3182 (1989); (h) M. G. Tenner, F. H. Geuzebroek, E. W. Kuipers, A. E. Wiskerke, A. W. Kleyn, S. Stolte, and A. Namiki, Chem. Phys. Lett. 168, 45 (1990); C. T. Rettner, J. Kimman, and D. J. Auerbach, J. Chem. Phys. 94, 734 (1991); (j) A. E. Wiskerke and A. W. Kleyn, J. Phys.: Condens. Matter 7, 5195 (1995).
14. See for example (a) A. W. Kleyn, A. C. Luntz, and D. J. Auerbach, Phys. Rev. Lett. 47, 1169 (1981); (b) A. C. Luntz, A. W. Kleyn, and D. J. Auerbach, J. Chem. Phys. 76, 737 (1982); A. W. Kleyn, A. C. Luntz, and D. J. Auerbach, Surf. Sci. 117, 33 (1982); M. Asscher and G. A. Somorjai, in Dynamics on Surfaces, edited by B. Pullman et al. (D. Reidel Publishing, Utrecht, 1984), p. 117; (e) J. Misewich, H. Zacharias, and M. M. T. Loy, in Laser Spectrosropy VII, edited by T. W. Hänsch and Y. R. Shen (Springer-Verlag, Berlin, 1985), p. 333; (f) R. J. Hamers, P. L. Houston, and R. P. Merrill, J. Chem. Phys. 88, 6548 (1988); (g) D. C. Jacobs, K. W. Kolasinski, S. F. Shane, and R. N. Zare, ibid. 91, 3182 (1989); (h) M. G. Tenner, F. H. Geuzebroek, E. W. Kuipers, A. E. Wiskerke, A. W. Kleyn, S. Stolte, and A. Namiki, Chem. Phys. Lett. 168, 45 (1990); C. T. Rettner, J. Kimman, and D. J. Auerbach, J. Chem. Phys. 94, 734 (1991); (j) A. E. Wiskerke and A. W. Kleyn, J. Phys.: Condens. Matter 7, 5195 (1995).
15. See for example (a) A. W. Kleyn, A. C. Luntz, and D. J. Auerbach, Phys. Rev. Lett. 47, 1169 (1981); (b) A. C. Luntz, A. W. Kleyn, and D. J. Auerbach, J. Chem. Phys. 76, 737 (1982); A. W. Kleyn, A. C. Luntz, and D. J. Auerbach, Surf. Sci. 117, 33 (1982); M. Asscher and G. A. Somorjai, in Dynamics on Surfaces, edited by B. Pullman et al. (D. Reidel Publishing, Utrecht, 1984), p. 117; (e) J. Misewich, H. Zacharias, and M. M. T. Loy, in Laser Spectrosropy VII, edited by T. W. Hänsch and Y. R. Shen (Springer-Verlag, Berlin, 1985), p. 333; (f) R. J. Hamers, P. L. Houston, and R. P. Merrill, J. Chem. Phys. 88, 6548 (1988); (g) D. C. Jacobs, K. W. Kolasinski, S. F. Shane, and R. N. Zare, ibid. 91, 3182 (1989); (h) M. G. Tenner, F. H. Geuzebroek, E. W. Kuipers, A. E. Wiskerke, A. W. Kleyn, S. Stolte, and A. Namiki, Chem. Phys. Lett. 168, 45 (1990); C. T. Rettner, J. Kimman, and D. J. Auerbach, J. Chem. Phys. 94, 734 (1991); (j) A. E. Wiskerke and A. W. Kleyn, J. Phys.: Condens. Matter 7, 5195 (1995).
16. See for example (a) A. W. Kleyn, A. C. Luntz, and D. J. Auerbach, Phys. Rev. Lett. 47, 1169 (1981); (b) A. C. Luntz, A. W. Kleyn, and D. J. Auerbach, J. Chem. Phys. 76, 737 (1982); A. W. Kleyn, A. C. Luntz, and D. J. Auerbach, Surf. Sci. 117, 33 (1982); M. Asscher and G. A. Somorjai, in Dynamics on Surfaces, edited by B. Pullman et al. (D. Reidel Publishing, Utrecht, 1984), p. 117; (e) J. Misewich, H. Zacharias, and M. M. T. Loy, in Laser Spectrosropy VII, edited by T. W. Hänsch and Y. R. Shen (Springer-Verlag, Berlin, 1985), p. 333; (f) R. J. Hamers, P. L. Houston, and R. P. Merrill, J. Chem. Phys. 88, 6548 (1988); (g) D. C. Jacobs, K. W. Kolasinski, S. F. Shane, and R. N. Zare, ibid. 91, 3182 (1989); (h) M. G. Tenner, F. H. Geuzebroek, E. W. Kuipers, A. E. Wiskerke, A. W. Kleyn, S. Stolte, and A. Namiki, Chem. Phys. Lett. 168, 45 (1990); C. T. Rettner, J. Kimman, and D. J. Auerbach, J. Chem. Phys. 94, 734 (1991); (j) A. E. Wiskerke and A. W. Kleyn, J. Phys.: Condens. Matter 7, 5195 (1995).
17. See for example (a) A. W. Kleyn, A. C. Luntz, and D. J. Auerbach, Phys. Rev. Lett. 47, 1169 (1981); (b) A. C. Luntz, A. W. Kleyn, and D. J. Auerbach, J. Chem. Phys. 76, 737 (1982); A. W. Kleyn, A. C. Luntz, and D. J. Auerbach, Surf. Sci. 117, 33 (1982); M. Asscher and G. A. Somorjai, in Dynamics on Surfaces, edited by B. Pullman et al. (D. Reidel Publishing, Utrecht, 1984), p. 117; (e) J. Misewich, H. Zacharias, and M. M. T. Loy, in Laser Spectrosropy VII, edited by T. W. Hänsch and Y. R. Shen (Springer-Verlag, Berlin, 1985), p. 333; (f) R. J. Hamers, P. L. Houston, and R. P. Merrill, J. Chem. Phys. 88, 6548 (1988); (g) D. C. Jacobs, K. W. Kolasinski, S. F. Shane, and R. N. Zare, ibid. 91, 3182 (1989); (h) M. G. Tenner, F. H. Geuzebroek, E. W. Kuipers, A. E. Wiskerke, A. W. Kleyn, S. Stolte, and A. Namiki, Chem. Phys. Lett. 168, 45 (1990); C. T. Rettner, J. Kimman, and D. J. Auerbach, J. Chem. Phys. 94, 734 (1991); (j) A. E. Wiskerke and A. W. Kleyn, J. Phys.: Condens. Matter 7, 5195 (1995).
18. See for example (a) A. W. Kleyn, A. C. Luntz, and D. J. Auerbach, Phys. Rev. Lett. 47, 1169 (1981); (b) A. C. Luntz, A. W. Kleyn, and D. J. Auerbach, J. Chem. Phys. 76, 737 (1982); A. W. Kleyn, A. C. Luntz, and D. J. Auerbach, Surf. Sci. 117, 33 (1982); M. Asscher and G. A. Somorjai, in Dynamics on Surfaces, edited by B. Pullman et al. (D. Reidel Publishing, Utrecht, 1984), p. 117; (e) J. Misewich, H. Zacharias, and M. M. T. Loy, in Laser Spectrosropy VII, edited by T. W. Hänsch and Y. R. Shen (Springer-Verlag, Berlin, 1985), p. 333; (f) R. J. Hamers, P. L. Houston, and R. P. Merrill, J. Chem. Phys. 88, 6548 (1988); (g) D. C. Jacobs, K. W. Kolasinski, S. F. Shane, and R. N. Zare, ibid. 91, 3182 (1989); (h) M. G. Tenner, F. H. Geuzebroek, E. W. Kuipers, A. E. Wiskerke, A. W. Kleyn, S. Stolte, and A. Namiki, Chem. Phys. Lett. 168, 45 (1990); C. T. Rettner, J. Kimman, and D. J. Auerbach, J. Chem. Phys. 94, 734 (1991); (j) A. E. Wiskerke and A. W. Kleyn, J. Phys.: Condens. Matter 7, 5195 (1995).
19. See for example (a) A. W. Kleyn, A. C. Luntz, and D. J. Auerbach, Phys. Rev. Lett. 47, 1169 (1981); (b) A. C. Luntz, A. W. Kleyn, and D. J. Auerbach, J. Chem. Phys. 76, 737 (1982); A. W. Kleyn, A. C. Luntz, and D. J. Auerbach, Surf. Sci. 117, 33 (1982); M. Asscher and G. A. Somorjai, in Dynamics on Surfaces, edited by B. Pullman et al. (D. Reidel Publishing, Utrecht, 1984), p. 117; (e) J. Misewich, H. Zacharias, and M. M. T. Loy, in Laser Spectrosropy VII, edited by T. W. Hänsch and Y. R. Shen (Springer-Verlag, Berlin, 1985), p. 333; (f) R. J. Hamers, P. L. Houston, and R. P. Merrill, J. Chem. Phys. 88, 6548 (1988); (g) D. C. Jacobs, K. W. Kolasinski, S. F. Shane, and R. N. Zare, ibid. 91, 3182 (1989); (h) M. G. Tenner, F. H. Geuzebroek, E. W. Kuipers, A. E. Wiskerke, A. W. Kleyn, S. Stolte, and A. Namiki, Chem. Phys. Lett. 168, 45 (1990); C. T. Rettner, J. Kimman, and D. J. Auerbach, J. Chem. Phys. 94, 734 (1991); (j) A. E. Wiskerke and A. W. Kleyn, J. Phys.: Condens. Matter 7, 5195 (1995).
20. See for example (a) A. W. Kleyn, A. C. Luntz, and D. J. Auerbach, Phys. Rev. Lett. 47, 1169 (1981); (b) A. C. Luntz, A. W. Kleyn, and D. J. Auerbach, J. Chem. Phys. 76, 737 (1982); A. W. Kleyn, A. C. Luntz, and D. J. Auerbach, Surf. Sci. 117, 33 (1982); M. Asscher and G. A. Somorjai, in Dynamics on Surfaces, edited by B. Pullman et al. (D. Reidel Publishing, Utrecht, 1984), p. 117; (e) J. Misewich, H. Zacharias, and M. M. T. Loy, in Laser Spectrosropy VII, edited by T. W. Hänsch and Y. R. Shen (Springer-Verlag, Berlin, 1985), p. 333; (f) R. J. Hamers, P. L. Houston, and R. P. Merrill, J. Chem. Phys. 88, 6548 (1988); (g) D. C. Jacobs, K. W. Kolasinski, S. F. Shane, and R. N. Zare, ibid. 91, 3182 (1989); (h) M. G. Tenner, F. H. Geuzebroek, E. W. Kuipers, A. E. Wiskerke, A. W. Kleyn, S. Stolte, and A. Namiki, Chem. Phys. Lett. 168, 45 (1990); C. T. Rettner, J. Kimman, and D. J. Auerbach, J. Chem. Phys. 94, 734 (1991); (j) A. E. Wiskerke and A. W. Kleyn, J. Phys.: Condens. Matter 7, 5195 (1995).
21. See for example (a) A. W. Kleyn, A. C. Luntz, and D. J. Auerbach, Phys. Rev. Lett. 47, 1169 (1981); (b) A. C. Luntz, A. W. Kleyn, and D. J. Auerbach, J. Chem. Phys. 76, 737 (1982); A. W. Kleyn, A. C. Luntz, and D. J. Auerbach, Surf. Sci. 117, 33 (1982); M. Asscher and G. A. Somorjai, in Dynamics on Surfaces, edited by B. Pullman et al. (D. Reidel Publishing, Utrecht, 1984), p. 117; (e) J. Misewich, H. Zacharias, and M. M. T. Loy, in Laser Spectrosropy VII, edited by T. W. Hänsch and Y. R. Shen (Springer-Verlag, Berlin, 1985), p. 333; (f) R. J. Hamers, P. L. Houston, and R. P. Merrill, J. Chem. Phys. 88, 6548 (1988); (g) D. C. Jacobs, K. W. Kolasinski, S. F. Shane, and R. N. Zare, ibid. 91, 3182 (1989); (h) M. G. Tenner, F. H. Geuzebroek, E. W. Kuipers, A. E. Wiskerke, A. W. Kleyn, S. Stolte, and A. Namiki, Chem. Phys. Lett. 168, 45 (1990); C. T. Rettner, J. Kimman, and D. J. Auerbach, J. Chem. Phys. 94, 734 (1991); (j) A. E. Wiskerke and A. W. Kleyn, J. Phys.: Condens. Matter 7, 5195 (1995).
22. See for example (a) A. W. Kleyn, A. C. Luntz, and D. J. Auerbach, Phys. Rev. Lett. 47, 1169 (1981); (b) A. C. Luntz, A. W. Kleyn, and D. J. Auerbach, J. Chem. Phys. 76, 737 (1982); A. W. Kleyn, A. C. Luntz, and D. J. Auerbach, Surf. Sci. 117, 33 (1982); M. Asscher and G. A. Somorjai, in Dynamics on Surfaces, edited by B. Pullman et al. (D. Reidel Publishing, Utrecht, 1984), p. 117; (e) J. Misewich, H. Zacharias, and M. M. T. Loy, in Laser Spectrosropy VII, edited by T. W. Hänsch and Y. R. Shen (Springer-Verlag, Berlin, 1985), p. 333; (f) R. J. Hamers, P. L. Houston, and R. P. Merrill, J. Chem. Phys. 88, 6548 (1988); (g) D. C. Jacobs, K. W. Kolasinski, S. F. Shane, and R. N. Zare, ibid. 91, 3182 (1989); (h) M. G. Tenner, F. H. Geuzebroek, E. W. Kuipers, A. E. Wiskerke, A. W. Kleyn, S. Stolte, and A. Namiki, Chem. Phys. Lett. 168, 45 (1990); C. T. Rettner, J. Kimman, and D. J. Auerbach, J. Chem. Phys. 94, 734 (1991); (j) A. E. Wiskerke and A. W. Kleyn, J. Phys.: Condens. Matter 7, 5195 (1995).
23. See for example (a) A. Mödl, H. Robota, J. Segner, W. Vielhaber, M. C. Lin, and G. Ertl, J. Chem. Phys. 83, 4800 (1985); (b) J. Häger, Y. R. Shen, and H. Walther, Phys. Rev. A 31, 1962 (1985); A. Mödl, T. Gritsch, F. Budde, T. J. Chuang, and G. Ertl, Phys. Rev. Lett. 57, 384 (1986); F. Budde, T. Gritsch, A. Mödl, T. J. Chuang, and G. Ertl, Surf. Sci. 178, 798 (1986); (e) F. Budde, A. Mödl, A. V. Hamza, P. M. Ferm, and G. Ertl, ibid. 192, 507 (1987); (f) C. Flytzanis, H. Kuze, M. Chatelet, J. Häger, and H. Walther, Phys. Rev. Lett. 61, 730 (1988).
24. See for example (a) A. Mödl, H. Robota, J. Segner, W. Vielhaber, M. C. Lin, and G. Ertl, J. Chem. Phys. 83, 4800 (1985); (b) J. Häger, Y. R. Shen, and H. Walther, Phys. Rev. A 31, 1962 (1985); A. Mödl, T. Gritsch, F. Budde, T. J. Chuang, and G. Ertl, Phys. Rev. Lett. 57, 384 (1986); F. Budde, T. Gritsch, A. Mödl, T. J. Chuang, and G. Ertl, Surf. Sci. 178, 798 (1986); (e) F. Budde, A. Mödl, A. V. Hamza, P. M. Ferm, and G. Ertl, ibid. 192, 507 (1987); (f) C. Flytzanis, H. Kuze, M. Chatelet, J. Häger, and H. Walther, Phys. Rev. Lett. 61, 730 (1988).
25. See for example (a) A. Mödl, H. Robota, J. Segner, W. Vielhaber, M. C. Lin, and G. Ertl, J. Chem. Phys. 83, 4800 (1985); (b) J. Häger, Y. R. Shen, and H. Walther, Phys. Rev. A 31, 1962 (1985); A. Mödl, T. Gritsch, F. Budde, T. J. Chuang, and G. Ertl, Phys. Rev. Lett. 57, 384 (1986); F. Budde, T. Gritsch, A. Mödl, T. J. Chuang, and G. Ertl, Surf. Sci. 178, 798 (1986); (e) F. Budde, A. Mödl, A. V. Hamza, P. M. Ferm, and G. Ertl, ibid. 192, 507 (1987); (f) C. Flytzanis, H. Kuze, M. Chatelet, J. Häger, and H. Walther, Phys. Rev. Lett. 61, 730 (1988).
26. See for example (a) A. Mödl, H. Robota, J. Segner, W. Vielhaber, M. C. Lin, and G. Ertl, J. Chem. Phys. 83, 4800 (1985); (b) J. Häger, Y. R. Shen, and H. Walther, Phys. Rev. A 31, 1962 (1985); A. Mödl, T. Gritsch, F. Budde, T. J. Chuang, and G. Ertl, Phys. Rev. Lett. 57, 384 (1986); F. Budde, T. Gritsch, A. Mödl, T. J. Chuang, and G. Ertl, Surf. Sci. 178, 798 (1986); (e) F. Budde, A. Mödl, A. V. Hamza, P. M. Ferm, and G. Ertl, ibid. 192, 507 (1987); (f) C. Flytzanis, H. Kuze, M. Chatelet, J. Häger, and H. Walther, Phys. Rev. Lett. 61, 730 (1988).
27. See for example (a) A. Mödl, H. Robota, J. Segner, W. Vielhaber, M. C. Lin, and G. Ertl, J. Chem. Phys. 83, 4800 (1985); (b) J. Häger, Y. R. Shen, and H. Walther, Phys. Rev. A 31, 1962 (1985); A. Mödl, T. Gritsch, F. Budde, T. J. Chuang, and G. Ertl, Phys. Rev. Lett. 57, 384 (1986); F. Budde, T. Gritsch, A. Mödl, T. J. Chuang, and G. Ertl, Surf. Sci. 178, 798 (1986); (e) F. Budde, A. Mödl, A. V. Hamza, P. M. Ferm, and G. Ertl, ibid. 192, 507 (1987); (f) C. Flytzanis, H. Kuze, M. Chatelet, J. Häger, and H. Walther, Phys. Rev. Lett. 61, 730 (1988).
28. See for example (a) A. Mödl, H. Robota, J. Segner, W. Vielhaber, M. C. Lin, and G. Ertl, J. Chem. Phys. 83, 4800 (1985); (b) J. Häger, Y. R. Shen, and H. Walther, Phys. Rev. A 31, 1962 (1985); A. Mödl, T. Gritsch, F. Budde, T. J. Chuang, and G. Ertl, Phys. Rev. Lett. 57, 384 (1986); F. Budde, T. Gritsch, A. Mödl, T. J. Chuang, and G. Ertl, Surf. Sci. 178, 798 (1986); (e) F. Budde, A. Mödl, A. V. Hamza, P. M. Ferm, and G. Ertl, ibid. 192, 507 (1987); (f) C. Flytzanis, H. Kuze, M. Chatelet, J. Häger, and H. Walther, Phys. Rev. Lett. 61, 730 (1988).
29. See for example (a) J. Misewich, H. Zacharias, and M. M. T. Loy, Phys. Rev. Lett. 55, 1919 (1985); (b) J. Misewich, H. Zacharias, and M. M. T. Loy, J. Vac. Sci. Technol. B 3, 1474 (1985); E. Kolodney, D. Baugh, P. S. Powers, H. Reisler, and C. Wittig, Chem. Phys. Lett. 145, 177 (1988); C. Roth, J. Häger, and H. Walther, J. Chem. Phys. 97, 6880 (1992).
30. See for example (a) J. Misewich, H. Zacharias, and M. M. T. Loy, Phys. Rev. Lett. 55, 1919 (1985); (b) J. Misewich, H. Zacharias, and M. M. T. Loy, J. Vac. Sci. Technol. B 3, 1474 (1985); E. Kolodney, D. Baugh, P. S. Powers, H. Reisler, and C. Wittig, Chem. Phys. Lett. 145, 177 (1988); C. Roth, J. Häger, and H. Walther, J. Chem. Phys. 97, 6880 (1992).
31. See for example (a) J. Misewich, H. Zacharias, and M. M. T. Loy, Phys. Rev. Lett. 55, 1919 (1985); (b) J. Misewich, H. Zacharias, and M. M. T. Loy, J. Vac. Sci. Technol. B 3, 1474 (1985); E. Kolodney, D. Baugh, P. S. Powers, H. Reisler, and C. Wittig, Chem. Phys. Lett. 145, 177 (1988); C. Roth, J. Häger, and H. Walther, J. Chem. Phys. 97, 6880 (1992).
32. See for example (a) J. Misewich, H. Zacharias, and M. M. T. Loy, Phys. Rev. Lett. 55, 1919 (1985); (b) J. Misewich, H. Zacharias, and M. M. T. Loy, J. Vac. Sci. Technol. B 3, 1474 (1985); E. Kolodney, D. Baugh, P. S. Powers, H. Reisler, and C. Wittig, Chem. Phys. Lett. 145, 177 (1988); C. Roth, J. Häger, and H. Walther, J. Chem. Phys. 97, 6880 (1992).
33. J. Segner, H. Robota, W. Vielhaber, G. Ertl, F. Frenkel, J. Häger, W. Kreiger, and H. Walther, Surf. Sci. 131, 273 (1983).
34. (a) S. R. Cohen, R. Naaman, and J. Sagiv, Phys. Rev. Lett. 58, 1208 (1987);
35. (b) S. R. Cohen, R. Naaman, and J. Sagiv, J. Chem. Phys. 88, 2757 (1988);
36. (c) S. R. Cohen, R. Naaman, and G. G. Balint-Kurti, Chem. Phys. Lett. 152, 269 (1988);
37. (d) S. R. Cohen, R. Naaman, and G. G. Balint-Kurti, Chem. Phys. 134, 119 (1989).
38. M. K. Ainsworth, J. McCombie, M. R. S. McCoustra, and M. A. Chesters (unpublished).
39. D. J. Oakes, M. R. S. McCoustra, and M. A. Chesters, Faraday Discuss. 96, 325 (1993).
40. D. J. Oakes, Ph. D. thesis, University of East Anglia, 1994.
41. H. E. Newell, D. J. Oakes, F. J. M. Rutten, M. R. S. McCoustra, and M. A. Chesters, Faraday Discuss. 105, 193 (1996).
42. D. C. Jacobs and R. N. Zare, J. Chem. Phys. 85, 5457 (1986).
43. M. K. Ainsworth, Ph. D. thesis, University of Nottingham, 1998.
44. P. Gardner, Ph. D. thesis, University of East Anglia, 1988.
45. M. Tüshaus, E. Schweizer, P. Hollins, and A, M. Bradshaw, J. Electron Spectrosc. Relat. Phenom. 44, 305 (1987).
46. U. Starke, A. Barbieri, N. Materer, M. A. Van Hove, and G. A. Somorjai, Surf. Sci. 286, 1 (1993).
47. D. J. Auerbach, in Atomic and Molecular Beam Methods, Volume I, edited by G. Scoles (Oxford University Press, Oxford, 1988), Chap. 14, p. 363ff.
48. D. J. Auerbach, in Atomic and Molecular Beam Methods, Volume 2, edited by G. Scoles (Oxford University Press, Oxford, 1992), Chap. 15, p. 451ff.
49. E. K. Grimmelmann, J. C. Tully, and M. J. Cardillo, J. Chem. Phys. 72, 1039 (1980).