Experimental aspects of mechanistic studies on aqueous ozone decomposition in alkaline solution

Ozone: Science and Engineering

Volumn 22, Issue 3, 2000, Pages 287-304

  Nemes, Attila ^a   Fábián, István ^a   Gordon, Gilbert ^b  

^a UNIVERSITY OF DEBRECEN   (Hungary)

^b MIAMI UNIVERSITY   (United States)

Author keywords

Kinetic Models; Ozone; Ozone Decomposition; Parameter Fitting; Simulation

Indexed keywords

ABSORPTION; DECOMPOSITION; MATHEMATICAL MODELS; PH EFFECTS; REACTION KINETICS; SOLUTIONS; THERMAL EFFECTS;

OZONE DECOMPOSITION; STOPPED FLOW METHOD;

OZONE;

EID: 0342647321     PISSN: 01919512     EISSN: None     Source Type: Journal    
DOI: 10.1080/01919510008547212     Document Type: Article

References (40)

1. Alder, M.G. and Hill, G.R. "The Kinetics and Mechanism of Hydroxide Ion Catalyzed Ozone Decomposition in Aqueous Solution", J. Am. Chem. Soc. 72:1884 (1950).
2. Adams, G.E., Boag, J.W. and Michael, B.D. "Transient species produced in irradiated water and aqueous solutions containing oxygen", Proc. Royal. Soc. A 289:321 (1966).
3. Bahnemann, D. and Hart, E.J. "Rate Constants of the Reaction of the Hydrated Electron and Hydroxyl radical with Ozone in Aqueous Solution", J. Phys. Chem. 86:252 (1982).
4. Behar, D. and Czapski, G. "Flash Photolysis of Hydrogen Peroxide I: The Reaction of Ozonide with Hydrogen Peroxide" Isr. J. Chem. 6:43 (1968).
5. -H, Trans. Farad. Soc. 65:2150 (1969).
6. -) in Aqueous Solution", J. Phys. Chem. Ref. Data, 17:513 (1988).
7. - as Intermediates", J. Phys. Chem. 88:2560 (1984); Correction: 88:5450 (1984).
8. Chelkowska, K., Grasso, D., Fábián, I. and Gordon, G. Proc. of the International Ozone Association (Shreveport, Louisiana, U.S.: International Ozone Association, 1990), pp. 427-437.
9. Chelkowska, K., Grasso, D., Fábián, I. and Gordon, G. "Numerical Simulations of Aqueous Ozone Decomposition", Ozone Sci. and Eng. 14:33 (1992).
10. Czapski, G., Samuni, A. and Yellin, R. "The Disappearance of Ozone in Alkaline Solution", Isr. J. Chem. 6:969 (1968).
11. Eigen, M., and DeMaeyer, L. "Kinetics of neutralization", Z. Electrochem., 59:986 (1955)
12. Farhataziz and Ross, A.B. "Selected Specific Rates of Reactions of Transients from Water in Aqueous Solution. III. Hydroxyl Radical and Perhydroxyl Radical and Their Radical Ions.", Natl. Stand. Ref. Data Ser., Natl. Bur. Stand. 59:113 (1977).
13. Fábián, I. "Mechanistic Aspects of Ozone Decomposition in Aqueous Solution", Progress in Nuclear Energy, 29:167 (1995).
14. Forni, L., Bahnemann, D. and Hart, E.J. "Mechanism of the Hydroxide Ion Initiated Decomposition of Ozone in Aqueous Solution", J. Phys. Chem. 86:255 (1982).
15. Gall, B.L. and Dorfman, L.M. "Pulse Radiolysis Studies. XV. Reactivity of the Oxide Radical Ion and the Ozonide Ion in Aqueous Solution", J. Am. Chem. Soc. 91:2199 (1969).
16. Gaugal, S.V. Tetrafluoroethylene Polymers in Encyclopedia of Polimer Sciences and Engineering (New York, U.S.: John Wiley & Sons, Vol. 16, 1989), pp. 577-642.
17. Gran, G. "Determination of the Equivalence Point in Potentiometric Titrations. II.", Analyst 77:661 (1952).
18. Gordon, G. and Fábián, I. Proc. of the 10th Ozone World Congress, (Monaco: International Ozone Association, 1991), pp. 113-124.
19. Gordon, G., Cooper, W.J., Rice, R.G. and Pacey, G.E. Disinfectant Residual Measurements Methods, (Denver, CO, U.S.: AWWA Research Foundation, 1987), and references therein.
20. Hoigné, J. and Bader, H. "Beeinflussung der Oxidationswirkung von Ozon und OH Radikalen durch Carbonat", Vom Wasser 48:283 (1977).
21. Landi, V.R. and Heidt, L.J. "Flash Photolysis Study of the Mechanism of Ozonide Ion Decay in Basic Aqueous Hydrogen Peroxide", J. Phys. Chem. 73:2361 (1969).
22. Nagy, I. and Bazsa, G. "Artifacts Caused by Plastics in Chemical Experiments: Absorption, Degradation, Catalysis and Irreproducible Behavior", React. Kinet. Catal. Lett. 45:15 (1991).
23. Nakareseisoon, S. and Gordon, G. "The Very Slow Decomposition of Aqueous Ozone in Highly Basic Solutions", Ozone Sci. and Eng. 11:49 (1989).
24. Neta, P., Huie, R.E., and Ross, A.B. "Rate Constants for Reactions of Inorganic Radicals in Aqueous Solutions", J. Phys. Chem. Ref. Data, 17:1027 (1988).
25. Peintler, G. and Zita A Comprehensive Program Package for Fitting Parameters of Chemical Reaction Mechanisms (Szeged, Hungary, 1990).
26. Rabani, J. and Atheson, M.S. "The Pulse Radiolysis of Aqueous Solutions of Potassium Ferrocyanide", J. Phys. Chem. 70:761 (1966).
27. Razumovskii, S.D. and Zaikov, G.E. Ozone and its Reactions with Organic Compounds, Studies in Organic Chemistry 15 (New York, U.S.: Elsevier, 1984).
28. Ross, A.B. and Neta, P. "Rate Constants for Inorganic Radicals in Aqueous Solution", Natl. Stand. Ref. Data Ser., Natl. Bur. Stand. 65:62 (1979).
29. -, in Strong Alkaline Solution", J. Phys. Chem. 86:2066 (1982).
30. 3 in Aqueous Medium", J. Phys. Chem. 88:269 (1984).
31. 2-Initiated", J. Phys. Chem. A, 102:2667 (1998).
32. Staehelin. J. and Hoigné, J. "Decomposition of Ozone in Water: Rate of Initiation by Hydroxide Ions and Hydrogen Peroxide", Environ. Sci. Technol. 16:676 (1982).
33. 4 as Chain Intermediates", J. Phys. Chem. 88:5999 (1984).
34. Taube, H. and Bray, W.C. "Chain Reactions in Aqueous Solutions Containing Ozone, Hydrogen Peroxide and Acid", J. Am. Chem. Soc. 62:3357 (1940).
35. Tomiyasu, H., Fukutomi, H. and Gordon, G. "Kinetics and Mechanism of Ozone Decomposition in Basic Aqueous Solution", Inorg. Chem. 24:2962 (1985).
36. Tomiyasu, H. and Gordon, G. "Colorimetric Determination of Ozone in Water Based on Reaction with Bis(terpyridine)iron(II)", Anal. Chem. 56:752 (1984).
37. Tomiyasu, H. and Gordon, G. "Kinetics and Mechanism of the Oxidation of Bis(terpyridine)-iron(II) by Ozone in Acidic Aqueous Solutions", Ozone Sci. and Eng. 11:59 (1989).
38. Tonomura, B., Nakatani, H., Ohnishi, M., Yamaguchi-Ito. J. and Hiromi, K. "Test Reactions for Stopped-Flow Apparatus. Reduction of 2,6-dichlorophenolindo-phenol and Potassium Ferricyanide by L-ascorbic Acid", Anal. Biochem. 84:370, (1978).
39. White, G.C. Handbook of Chlorination and Alternative Disinfectants (New York, U.S.: Van Nostrand Reinhold, 1992).
40. Wittmann, G., Ilisz, and Dombi, A. Abst. of the Regional Conference on Ozone, Ultraviolet Light, Advanced Oxidation Processes in Water Treatment (Amsterdam, The Netherlands: International Ozone Association, 1996), p. 411.