Facilitated transport separation of benzene and cyclohexane with poly(vinyl alcohol)-AgNO3 membranes

Journal of Membrane Science

Volumn 127, Issue 2, 1997, Pages 161-170

  Bryant, Debra L ^a   Noble, Richard D ^b   Koval, Carl A ^a  

^a UNIVERSITY OF COLORADO   (United States)

^b UCB 450   (United States)

Author keywords

Facilitated transport; Organic separations

Indexed keywords

BENZENE; CYCLOHEXANE; POLYVINYL ALCOHOL; SILVER NITRATE;

ARTICLE; ARTIFICIAL MEMBRANE; CROSS LINKING; HYDRATION; MEMBRANE STRUCTURE; MEMBRANE TRANSPORT; PRIORITY JOURNAL; ULTRAVIOLET SPECTROSCOPY;

BENZENE; COMPLEXATION; CROSSLINKING; HYDRATION; ION EXCHANGE MEMBRANES; MECHANICAL PERMEABILITY; PARAFFINS; POLYVINYL ALCOHOLS; SILVER COMPOUNDS; TRANSPORT PROPERTIES;

FACILITATED TRANSPORT MEMBRANES; HYDROCARBONS SEPARATION;

POLYMERIC MEMBRANES;

MEMBRANES; ORGANIC COMPOUNDS; TRANSPORT;

EID: 0342547259     PISSN: 03767388     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0376-7388(96)00267-0     Document Type: Article

References (14)

1. T. Yamaguchi, S. Nakao and S. Kimura, Plasma-graft filling polymerization: preparation of a new type of pervaporation membrane for organic liquid mixtures, Macromolecules, 24 (1991) 5522-5527.
2. F. Suzuki, K. Onozato, H. Yaigashi and T. Masuko, Pervaporation of organic solvents by poly[bis(2,2.2-trifluoroethoxy)phosphazene] membrane, J. Appl. Polym. Sci., 34 (1987) 2197-2204.
3. L. Enneking, W. Stephan and A. Heintz, Sorption and diffusivity measurements of cyclohexane+benzene and cyclohexene+toluene mixtures in polyurethane membranes. Model calculations of the pervaporation process, Ber. Bunsenges. Phys. Chem., 97 (1993) 912-922.
4. H.R. Acharya, S.A. Stern, Z.Z. Liu and I. Cabasso, Separation of liquid benzene/cyclonexane mixtures by perstraction and pervaporation, J. Membrane Sci., 37 (1988) 205-232.
5. F. Sun and E. Ruckenstein, Sorption and pervaporation of benzene-cyclohexane mixtures through composite membranes prepared via concentrated emulsion polymerization, J. Membrane Sci., 99 (1995) 273-284.
6. W. Stephan, R.D. Noble and C.A. Koval, Design methodolgy for a membrane/distillation column hybrid process, J. Membrane Sci., 99 (1995) 259-272.
7. J. Davis, R. Valus, R. Eshraghi and A. Velikoff, Facilitated transport membrane hybrid systems for olefin purification, Sep. Sci. Tech., 28 (1993) 463-476.
8. M. Mulder, Basic Principles of Membrane Technology, Kluwer Academic, Dordrecht, 1991.
9. C.A. Koval, D.L. Bryant, H. Engelhardt, D. Manley, R. Rabago, P. Thoen, R.D. Noble, Facilitated transport of unsaturated hydrocarbons in perfluorosulfonic acid (Nafion) membranes, ACS Sym. Ser., 642 (1996) 286-302.
10. W.E. Silverthorne, Arene transition metal chemistry, Adv. Organomet. Chem., 13 (1975) 47-137.
11. C.A. Finch (Ed.), Polyvinyl Alcohol - Developments, Wiley, New York, 1992.
12. +-containing polymer membranes, J. Membrane Sci., 91 (1994) 13.
13. R. Rabago, R.D. Noble and C.A. Koval, Effects of incorporation of fluorocarbon and hydrocarbon surfactants into perfluorosulfonic acid (Nafion) membranes, Chem. Mater. Sci., 6 (1994) 947-951.
14. C. Koval, P. Thoen and R.D. Noble, zUnexpectedly large selectivities for olefin separations utilizing silver ion in ion-exchange membranes, J. Phys. Chem., 98 (1994) 1262-1269.