A Novel, Stereocontrolled Synthesis of 1,2-trans-Cyclopropanes: Cyclopropyl Boronate Esters as Partners in Suzuki Couplings with Aryl Halides

Synlett

Volumn 1996, Issue 9, 1996, Pages 893-894

  Hildebrand, Jens P ^a   Marsden, Stephen P ^a  

^a IMPERIAL COLLEGE LONDON   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0342538255     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-1996-5608     Document Type: Article

References (21)

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6. (a) (E)-1,2-disubstituted: Brown, H. C.; Bhat, N. G.; Somayji, V. Organometallics, 1983, 2, 1311
7. (b) (Z)-1,2-disubstituted: Deloux, L.; Srebnik, M. J. Org. Chem., 1994, 59, 6871
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17. 5a while compound 3 was prepared according to: Brown, H. C.; Gupta, S. K. J. Am Chem. Soc., 1972, 94, 4370
18. tBuOH, DME, reflux, (69%)
19. This system was recently reported to accelerate the coupling of bulky aryl boronic esters with halopyridines: Zhang, H.; Chan, K. S. Tetrahedron Lett., 1996, 37, 1043
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