Auxiliary accelerated reactions: Catalytic hydrogenation

Journal of the Chemical Society - Perkin Transactions 1

Volumn , Issue 1, 1996, Pages 1-2

  Westwell, Andrew D ^a   Williams, Jonathan M J ^a  

^a LOUGHBOROUGH UNIVERSITY   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0242717186     PISSN: 0300922X     EISSN: None     Source Type: Journal    
DOI: 10.1039/p19960000001     Document Type: Article

References (8)

1. H. Takaya and R. Noyori, in Comprehensive Organic Synthesis, eds. B. M. Trost and I. Fleming, Pergamon Press, Oxford, 1991, vol. 3, pp. 443-469.
2. R. Crabtree, Acc. Chem. Res., 1979, 12, 331.
3. For a recent example of accelerated transmetallation effected by chelation to palladium, see G. T. Crisp and M. G. Gebauer, Tetrahedron Lett., 1995, 36, 3389.
4. A. D. Westwell and J. M. J. Williams, J. Chem. Soc., Chem. Commun., 1994, 2501.
5. Allyl benzyl ether 4 and allyl picolyl ether 8 were prepared by the treatment of the appropriate alcohol with allyl bromide in the presence of sodium hydride; see R. B. Moffett, J. Org. Chem., 1963, 28, 2885.
6. 2-Allyloxypyridine 7 was prepared by reaction of 2-bromopyridine with the sodium salt of allyl alcohol; see F. J. Dinan and H. Tieckelmann, J. Org. Chem., 1964, 29, 892.
7. For examples of the inhibition of transition metal catalysed hydrogenation using pyridine, see (a) J. A. Osborn, F. H. Jardine, J. F. Young and G. Wilkinson, J. Chem. Soc., A, 1964, 1711;
8. (b) J. P. Candlin and A. R. Oldham, Discuss. Faraday Soc., 1968, 46, 60.