The First Example of a Seven-Coordinate Vanadium(III) Thiolate Complex Containing the Hydrazine Molecule, an Intermediate of Nitrogen Fixation

Inorganic Chemistry

Volumn 42, Issue 23, 2003, Pages 7369-7371

  Hsu, Hua Fen ^a   Chu, Wei Cheng ^a   Hung, Chen Hsiung ^b   Liao, Ju Hsiou ^c  

^a NATIONAL CHENG KUNG UNIVERSITY   (Taiwan)

^b NATIONAL CHANGHUA UNIVERSITY OF EDUCATION   (Taiwan)

^c NATIONAL CHUNG CHENG UNIVERSITY   (Taiwan)

Author keywords

[No Author keywords available]

Indexed keywords

HYDRAZINE DERIVATIVE; IMIDAZOLE DERIVATIVE; THIOLACID; VANADIUM DERIVATIVE;

ARTICLE; CATALYSIS; CHEMICAL ANALYSIS; HYDROGEN BOND; NITROGEN FIXATION; STRUCTURE ANALYSIS; X RAY CRYSTALLOGRAPHY;

EID: 0242693866     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic034992w     Document Type: Article

References (24)

1. Rehder, D.; Jantzen, S. Structure, Function, and Models of Biogenic Vanadium Compounds; Nriagu, J. O., Ed.; John Wiley & Sons Inc.: New York, 1998; p 251.
2. Nekola, H.; Wang, D.; Gruning, C.; Gatjens, J.; Behrens, A.; Rehder, D. Inorg. Chem. 2002, 41, 2379.
3. Howard, J. B.; Rees, D. C. Chem. Rev. 1996, 96, 2965-2982.
4. Einsle, O.; Tezcan, F. A.; Andrade, S. L. A.; Benedikt-Schmid; Yoshida, M.; Howard, J. B.; Rees, D. C. Science 2002, 297, 1696.
5. Eady, R. R. Coord. Chem. Rev. 2003, 237, 23.
6. Davies, S. C.; Hughes, D. L.; Janas, Z.; Jerzykiewicz, L.; Richards, R. L.; Sanders, J. R.; Sobota, P. Chem. Commun 1997, 1261.
7. Davies, S. C.; Hughes, D. L.; Janes, Z.; Jerzykiewicz, L. B.; Richards, R. L.; Sanders, J. R.; Silverstone, J. E.; Sobota, P. Inorg. Chem. 2000, 39, 3485.
8. Floc'h, C. L.; Henderson, R. A.; Hitchcock, P. B.; Hughes, D. L.; Janas, Z.; Richards, R. L.; Sobota, P.; Szafert, S. J. Chem. Soc., Dalton Trans. 1996, 2755.
9. Manzer, L. E. Inorg. Synth. 1982, 21, 138.
10. Block, E.; Ofori-Okai, G.; Zubieta, J. J. Am. Chem. Soc. 1989, 111, 2327.
11. -1): 467(2652), 880(457).
12. int = 0.0746). Final R indices [I > 2σ(I)]: RI = 0.0462, wR2 = 0.0839, GOF= 0.964.
13. Okamoto, K.-I.; Hidaka, J.; Fukagawa, M.; Kanamori, K. Acta Crystallogr. 1992, C48, 1025.
14. Randall, C. R.; Armstrong, W. H. J. Chem. Soc., Chem. Commun 1988, 986.
15. Higgs, T. C.; Ji, D.; Czernuszewicz, R. S.; Matzanke, B. F.; Schunemann, V.; Trautwein, A. X.; Helliwell, M.; Ramirez, W.; Carrano, C. J. Inorg. Chem. 1998, 37, 2383.
16. Farahbakhsh, M.; Nekola, H.; Schmidt, H.; Rehder, D. Chem. Ber. 1997, 130, 1129.
17. Tsagkalidis, W.; Rehder, D. JBIC, J. Biol. Inorg. Chem. 1996, 1, 507.
18. Dean, N. S.; Folting, K.; Lobkovsky, E.; Christou, G. Angew. Chem., Int. Ed. Engl. 1993, 32, 594.
19. Szeymies, D.; Krebs, B.; Henkel, G. Angew. Chem., Int. Ed. Engl. 1983, 22, 885.
20. Wang, D.; Behrens, A.; Farahbakhsh, M.; Gätjens, J.; Rehder, D. Chem. Eur. J. 2003, 9, 1805.
21. Shimoi, M.; Miyamoto, S.; Ogino, H. Bull. Chem. Soc. Jpn. 1991, 64, 2549.
22. Kanamori, K.; Kameda, E.; Okamoto, K.-i. Bull. Chem. Soc. Jpn. 1996, 69, 2901.
23. Shimoi, M.; Saito, Y.; Ogino, H. Chem. Lett. 1989, 1675-1678.
24. Robles, J. C.; Matsuzaka, Y.; Inomata, S.; Shimoi, M.; Mori, W.; Ogino, H. Inorg. Chem. 1993, 32, 13.