Chemistry of Constrained Dioxocyclam Ligands with Co(III): Unusual Examples of C-H and C-N Bond Cleavage

Inorganic Chemistry

Volumn 42, Issue 23, 2003, Pages 7602-7607

  Hu, Chuanjiang ^a   Chin, Robert M ^a,c   Nguyen, Thoi D ^a   Nguyen, Khoi T ^a   Wagenknecht, Paul S ^a   Nathan, Lawrence C ^b  

^a SAN JOSE STATE UNIVERSITY   (United States)

^b SANTA CLARA UNIVERSITY   (United States)

^c UNIVERSITY OF NORTHERN IOWA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BASE; COBALT DERIVATIVE; CYCLAM DERIVATIVE; DIAZACYCLOOCTANE; DIOXOCYCLAM; OCTANE; UNCLASSIFIED DRUG;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL BOND; CHEMICAL COMPOSITION; CHEMICAL STRUCTURE; REACTION ANALYSIS; STRUCTURE ANALYSIS; X RAY CRYSTALLOGRAPHY;

CARBON; COBALT; CRYSTALLOGRAPHY, X-RAY; HETEROCYCLIC COMPOUNDS; HYDROGEN; LIGANDS; MOLECULAR CONFORMATION; MOLECULAR STRUCTURE; NITROGEN; ORGANOMETALLIC COMPOUNDS;

EID: 0242693436     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic0302027     Document Type: Article

References (35)

1. (a) Musker, W. K.; Hussain, M. S. Inorg. Chem. 1966, 5, 1416-1419.
2. (b) Legg, J. I.; Nielson, D. O.; Smith, D. L.; Larson, M. L. J. Am. Chem. Soc. 1968, 90, 5030-5031.
3. (c) Nielson, D. O.; Larsen, M. L.; Willett, R. D.; Legg, J. I. J. Am. Chem. Soc. 1971, 93, 5079-5082.
4. (d) Averill, D. F.; Legg, J. I.; Smith, D. L. Inorg. Chem. 1972, 11, 2344-2349.
5. (e) Darensbourg, M. Y.; Font, I.; Mills, D. K.; DaPala, M.; Reibenspies, J. H. Inorg. Chem. 1992, 31, 4965-4971.
6. (f) Goodman, D. C.; Tuntulani, T.; Farmer, P. J.; Darensbourg, M. Y.; Reibenspies, J. H. Angew. Chem., Int. Ed. Engl. 1993, 32, 116-119.
7. (a) Kanamori, K.; Broderick, W. E.; Jordan, R. F.; Willett, R. D.; Legg, J. I. J. Am. Chem. Soc. 1986, 108, 7122-7124.
8. (b) Broderick, W. E.; Kanamori, K.; Willett, R. D.; Legg, J. I. Inorg. Chem. 1991, 30, 3875-3881.
9. Chin, M.; Wone, D.; Nguyen, Q.; Nathan, L. C.; Wagenknecht, P. S. Inorg. Chim. Acta 1999, 292, 254-259.
10. Hu, C.; Nguyen, T. D.; Wagenknecht, P. S.; Nathan, L. C. Inorg. Chem. 2003, 42, 742-749.
11. (a) Brookhart, M.; Green, H. L. H. J. Organomet. Chem. 1983, 250, 395-408.
12. (b) Timmers, F.; Brookhart, M. Organometallics 1985, 4, 1365-1371.
13. For additional reviews on transition metal complexes of C-H σ bonds, see: (a) Hall, C.; Perutz, R. N. Chem. Rev. 1996, 96, 3125-3146.
14. (b) Crabtree, R. H. Angew. Chem., Int. Ed. Engl. 1993, 32, 789-805.
15. Parkin, S.; Moezzi, B.; Hope, H. J. Appl. Crystallog. 1995, 28, 53-56.
16. SHELXTL Software, Version 5.03; (Siemens) Bruker Analytical X-ray Systems, Inc.: Madison, WI, 1994.
17. Toscano, P. J.; Marzilli, L. G. Prog. Inorg. Chem. 1984, 31, 105-205.
18. Billo, E. Inorg. Nucl. Chem. Lett. 1974, 10, 613-617.
19. Gianotti, C.; Gaudemer, A.; Fontaine, C. Tetrahedron Lett. 1970, 11 (37), 3209-3212.
20. (a) Bied-Charreton, C.; Septe, B.; Gaaudemer, A. Org. Magn. Reson. 1975, 7, 116-124.
21. (b) Needham, T. E.; Matwiyoff, N. A.; Walker, T. E.; Hogenkamp, H. P. C. J. Am. Chem. Soc. 1973, 95, 5019-5024.
22. (c) Hogenkamp, H. P. C.; Tkachuck, R. D.; Grant, M. E. Biochemistry 1975, 14, 3707-3714.
23. 2dc3 yields ligand uncontaminated with dioxocyclam, precluding the possibility that Co(dc)(acac) formed from fortuitous dioxocyclam in the starting material.
24. (a) Riley, D. P.; J. Chem. Soc., Chem. Commun. 1983, 1530-1532.
25. (b) Riley, D. P.; Fields, D. L.; Rivers, W. J. Am. Chem. Soc. 1991, 113, 3371-3378.
26. (a) Calafat, A. M.; Marzilli, L. G. Inorg. Chem. 1993, 32, 2906-2911.
27. (b) Yashiro, M.; Mori, T.; Sekigushi, M.; Yoshikawa, S.; Shiraishi, S. J. Chem. Soc., Chem. Commun. 1992, 1167-1168.
28. (c) Sonnberger, B.; Hühn, P.; Wasserburger, A.; Wasgestian, F. Inorg. Chim. Acta 1992, 196, 65-71.
29. (a) Bosnich, B.; Poon, C. K.; Tobe, M. L. Inorg. Chem. 1965, 4, 1102-1108.
30. (b) Donnelly, M. A.; Zimmer, M. Inorg. Chem. 1999, 38, 1650-1658.
31. Simon, E.; L'Haridon, P.; Pichon, R.; L'Her, M. Inorg. Chim. Acta 1998, 282, 173-179.
32. (a) Chiang, C.; Leon, A.; Marzilli, L. G. Inorg. Chem. 1979, 18, 791-795.
33. (b) Kruger, G. J.; Reynardt, E. C. Acta Crystallogr., Sect. B 1974, 30, 822-824.
34. (c) Suzuki, T.; Kashiwabara, K.; Kita, M.; Fujita, J.; Kaizaki, S. Inorg. Chim. Acta, 1998, 281, 77-84.
35. Bu, X. H.; Cao, X. C.; An, D. L.; Zhang, R. H.; Thomas, C.; Kimura, E. J. Chem. Soc., Dalton Trans. 1998, 433-438.