Progress of sulfation in highly sulfated particles of lime

Industrial and Engineering Chemistry Research

Volumn 42, Issue 9, 2003, Pages 1840-1844

  Abanades, Juan C ^a   Anthony, Edward J ^b   García Labiano, Francisco ^a   Jia, Lufei ^b  

^a INSTITUTO DE CARBOQUÍMICA   (Spain)

^b NATURAL RESOURCES CANADA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

AGGLOMERATION; CALCINATION; CRACKING (CHEMICAL); FLUIDIZED BED COMBUSTION; PARTICLE SIZE ANALYSIS; SCANNING ELECTRON MICROSCOPY; THERMOGRAVIMETRIC ANALYSIS;

SHRINKING-CORE MODEL;

LIMESTONE;

CALCIUM OXIDE; SORBENT; SULFATE;

AGGLOMERATION; FLUIDIZED BED; FURNACE; LIMESTONE; SULFATE;

ARTICLE; ASH; BOILER; COMBUSTION; CONCENTRATION RESPONSE; FLUIDIZED BED; FURNACE; MODEL; PARTICLE SIZE; REACTION ANALYSIS; SCANNING ELECTRON MICROSCOPY; SOLID; SULFATION; THERMOGRAVIMETRY;

EID: 0242668769     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie020868t     Document Type: Article

References (17)

1. Anthony, E. J.; Granatstein, D. L. Sulfation Phenomena in Fluidised Bed Combustion Systems. Prog. Energy Combust. Sci. 2001, 27, 215.
2. Mattison, T.; Lyngfelt, A. A Sulfur Capture Model for Circulating Fluidized-Bed Boilers. Chem. Eng. Sci. 1998, 53, 1163.
3. Adánez, J.; Gayán, P.; García-Labiano, F. Comparison of Mechanistical Models for the Sulfation Reaction in a Broad Range of Particle Sizes of Sorbents. Ind. Eng. Chem. Res. 1996, 35, 2190.
4. 2 with Limestone Particles. Chem. Eng. Sci. 1986, 41, 25.
5. Dennis, J. S.; Hayhurst, A. N. Mechanism of the Sulphation of Calcined Limestone Particles in Combustion Gases. Chem. Eng. Sci. 1990, 45, 1175.
6. Laursen, K.; Duo, W.; Grace, J. R.; Lim, J. Sulfation and Reactivation Characteristics of Nine Limestones. Fuel 2000, 79, 153.
7. Abanades, J. C.; de Diego, L. F.; García-Labiano, F.; Adánez, J. Residual Activity of Sorbent Particles with a Long Residence Time in a CFBC. AIChE J. 2000, 46, 1888.
8. Anthony, E. J.; Jia, L. Agglomeration and Strength Development of Deposits in CFBC Boilers firing High Sulfur Fuels. Fuel 2000, 79, 1933.
9. Anthony, E. J.; Iribarne, A. P.; Iribarne, J. V. A New Mechanism for FBC Agglomeration and Fouling in 100% Firing of Petroleum Coke. J. Energy Resour. Technol. 1997, 119, 55.
10. Anthony, E. J.; Talbot, R. E.; Jia, L.; Granatstein, D. L. Agglomeration and Fouling in Three Industrial Petroleum-Coke Fired CFBC Boilers due to Carbonation and Sulfation. Energy Fuels 2000, 14, 1021.
11. Anthony, E. J.; Jia, L. Fouling in a 160 MWe FBC Boiler Firing Coal and Petroleum Coke. Fuel 2001, 80, 1009.
12. Zierold, D. M.; Voyles, R. W. NISCO Cogeneration Facility. In Proceedings of the 12th International Conference on Fluidized Bed Combustion; Rubow, L., Commonwealth, G., Eds.; ASME Press: New York, 1993; Vol. 1, p 501.
13. Abanades, J. C.; Anthony, E. J.; García-Labiano, F.; Jia, L. The Sulfation Reaction of Limestone Particles Over a Time Scale of Weeks. In Proceedings of the 16th International Conference on Fluidized Bed Combustion; Geiling, D. W., Ed.; ASME Press: New York, 2001; FBC01-0125.
14. Levenspiel, O. Chemical Reaction Engineering, 3rd ed.; John Wiley: New York, 1999.
15. Park, J. Y.; Levenspiel, O. The Crackling Core Model for the Reaction of Solid Particles. Chem. Eng. Sci. 1975, 30, 1207.
16. Borgwardt, R. H.; Bruce, K. R.; Blake, J. An Investigation of Product Layer Diffusivity for CaO Sulphation. Ind. Eng. Chem. Res. 1987, 26, 1993.
17. 2. AIChE J. 1993, 39, 698.