Synthesis, Characterization, and Fluorescent Properties of Ln(III), Ln(III)-Zn(II) (Ln=Gd, Eu), and Eu(III)-Cu(II) Cryptates

Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry

Volumn 33, Issue 9, 2003, Pages 1701-1715

  Chen, Qiu Yun ^a,c   Li, Chang Jiang ^a   Luo, Qing Hui ^b  

^a HUANGSHAN UNIVERSITY   (China)

^b NANJING UNIVERSITY   (China)

^c Huangshan College   (China)

Author keywords

Cryptate; D F Heterodinuclear; Fluorescence; Lanthanide

Indexed keywords

COPPER COMPLEX; EUROPIUM; GADOLINIUM; ZINC COMPLEX;

ABSORPTION; ARTICLE; CHEMICAL ANALYSIS; COLOR; ENERGY; FLUORESCENCE; PHOSPHORESCENCE; PHOTOLUMINESCENCE; SPECTRUM; SYNTHESIS;

EID: 0242658720     PISSN: 00945714     EISSN: None     Source Type: Journal    
DOI: 10.1081/SIM-120025449     Document Type: Article

References (36)

1. Alexander, V. Design and synthesis of macrocyclic ligands and their complexes of lanthanides and actinides. Chem. Rev. 1995, 95, 237-342.
2. Bunzli, J.C.G.; Piguet, C. Lanthanide-containing molecular and supermolecular polymetallic functional assemblies. Chem. Soc. Rev. 1999, 28, 347-358.
3. Alpha, B.; Lehn, J.M. Energy transfer luminescence of europium(III) and terbium(III) cryptates of macrobicyclic polypyridine ligands. Angew. Chem. Int., Ed. Engl. 1987, 26 (3), 266-267.
4. Piguet, C.; Edder, C.; Rigault, S.; Bernardinelli, G.; Bunzli, J.-C.G.; Hopfgartner, G. Isolated d-f pairs in superamolecular complexes with tunable structural and electronic properties. J. Chem. Soc., Dalton Trans. 2000, 22, 3999-4008.
5. Hamacek, J.; Blanc, S.; Elhabiri, M.; Leize, E.; Dorsselaer, A.V.; Piguet, C.; Albrecht-Gary, A.-M. Self-assembly mechanism of a bimetallic europium triple-stranded helicate. J. Am. Chem. Soc. 2003, 125, 1541-1550.
6. Rodriguez-Cortnas, R.; Avecilla, F.; Platas-Iglesias, C.; Imbert, D.; Bunzli, J.C.G.; Blas, A.D.; Rodriguez-Blas, T. Structure and photophysical properties of heterobimetallic 4f-Zn iminophenolate cryptates. Inorg. Chem. 2002, 41, 5336-5349.
7. 3+-catalyzed methanolysis of hydroxypropyl-p-nitrophenyl phosphate as a model for the RNA transesterification reaction. J. Am. Chem. Soc. 2003, 125, 1159-1566.
8. Aime, S.; Batta, M.; Fasano, M.; Terreno, E. Lanthanide(III) chelates for NMR biomedical application. Chem. Soc. Rev. 1998, 27, 19-30.
9. Nikolov, P.; Timtcheva, I. Photophysical properties of some derivatives of 3-arylmethylene-1-(3H)-isobenzofuranone indication of intermolecular hydrogen-bond formation in the singlet excited state. J. Photochem. Photobio, A Chem. 2002, 131, 23-26.
10. Parker, D.; Dickins, R.S.; Puschmann, H.; Crossland, C.; Howard, J.A.K. Being excited by lanthanide coordination complexes: aqua species, chirality, excited-state chemistry and exchange dynamics. Chem. Rev. 2002, 102, 1977-2010.
11. Ghosh, P.; Bharadwaj, P.K.; Ghosh, J.; Roy, S. Transition metal(II)/(III), Eu(III) and Tb(III) ions induced molecular photonic OR gates using trianthryl cryptands of varying cavity dimension. J. Am. Chem Soc. 1997, 118, 11903-11909.
12. Archer, R.D.; Chen, H. Synthesis, characterization, and luminescence of europium(III) Schiff base complexes. Inorg. Chem. 1998, 37, 2089-2095.
13. Sabbatini, N.; Guardigi, M. Luminescent lanthanide complexes as photochemical supramolecular devices. Coord. Chem. Rev. 1993, 123, 201-245.
14. Petoud, S.; Bunzli, J.-G.G.; Ganzman, T.; Piguet, C.; Xiang, Q.; Thummel, P.R. Influence of charge-transfer states on the Eu(III) luminescence in mononuclear triplet helical complexes with tridentate aromatic ligands. J. Lumin. 1999, 82, 69-76.
15. 2(MeCN (Ln = Gd, Eu, Tb, Dy, Y) - synthesis, characterization, magnetic and electrochemical properties. J. Chem. Soc., Dalton Trans. 2002, 14, 2873-2878.
16. Wang, S.-X.; Luo, J.-H.; Zhou, X.-X.; Zeng, Z.-Z. Synthesis, characterization and luminescence properties of lanthanide(III) complexes with 2,6-bis(benzimidazol-2′-yl′)pyridine. Polyhedron 1993, 12, 1939-1945.
17. Bazzicalupi, C.; Bencini, A.; Bianchi, A.; Giorgi, C.; Fusi, V.; Masotti, A.; Valtancoli, B.; Rogue, A.; Pina, F.J. pH modulation of the luminescence emission of a new europium cryptate complex. J. Chem. Soc., Chem. Commun. 2000, 7, 561-562.
18. Sabbatini, N.; Ciano, M.; Dellonte, S.; Bonazzi, A.; Bolletta, F.; Balzani, V. Photopyysical properties of europium(II) cryptates. J. Phys. Chem. 1984, 88, 1534-1537.
19. Prodi, L.; Maestri, M.; Balzani, V. Luminescence properties of cryptate europium(III) complexes incorporating heterocyclic N-oxide groups. Chem. Phys. 1991, 180, 45-50.
20. Prodi, L.; Maestri, M.; Ziessi, R.; Balzani, V. Luminescent europium(III), terbium(III) and gadonium(III) complexes triazacyclononane ligand containing three 2,2′-bipyridine units. Inorg. Chem. 1991, 30, 3798-3802.
21. Sabbatini, N.; Guardigilli, M.; Manet, I.; Bolletta, F. Synthesis and luminescence of lanthanide complexes of a branched macrocyclic ligand containing 2,2′-bipyridine and 9-methyl-1,10-phenanthroline subunits. Inorg. Chem. 1994, 33, 955-959.
22. Bazzicalupi, C.; Bencini, A.; Bianchi, A.; Giorgi, C.; Fusi, V.; Masotti, A.; Valtancoli, B.; Roque, A.; Pina, F. pH modulation of the luminescnece emission of a new europium cryptate complex. Chem. Commun. 2000, 7, 561-562.
23. Gawryszewska, P.; Jerzykiewicz, L.; Pietraszkiewicz, M.; Legendziewicz, J.; Riehl, J.P. Photophysics and crystal structure of a europium(III) cryptate incorporating 3,3′-Biisoquinoline-2,2′-dioxide. Inorg. Chem. 2000, 39, 5365-5372.
24. Steemer, F.J.; Verboom, W.; Reinhoudt, D.N.; Van Der Tol, E.B.; Verhoeven, J.W. New sensitizer-modified calix [4] arenes enabling near-UV excitation of complexed luminescent lanthanide ions. J. Am. Chem. Soc. 1995, 117, 9114-9408.
25. Platas, C.; Avecilla, F.; de Blas, A.; Rodriguez-Blas, T.; Geraldes, C.F.G.C.; Toth, E.; Merbach, A.E.; Bunzli, J.-C.G. Mono-and bimetallic lanthanide(III) phenolic cryptates obtained by template reaction: solid state structure, photophysical properties and relaxivity. J. Chem. Soc., Dalton Trans. 2000, 4, 611-618.
26. Chen, Q.-Y.; Feng, C.-J.; Luo, J.-H.; Duan, C.-Y.; Yu, X.-S.; Liu, D.-J. The syntheses and luminescent properties of Eu(III) and Tb(III) cryptates in solution. Eur. J. Inorg. Chem. 2001, 4, 1063-1069.
27. Winpenny, R.E.P. The structures and magnetic properties of complexes containing 3d and 4f metals. Chem. Soc. Rev. 1998, 27, 447-452.
28. Edder, C.; Piguet, C.; Bunzli, J.-C.G.; Hopfgartner, G. High-spin iron(II) as a semitransparent partner for tuning europium(III) luminescence in heterodimetallic d-f complexes. Chem. Eur. J. 2001, 7, 3014-3024.
29. Chen, Q.-Y.; Luo, Q.-H.; Wang, Z.-L.; Chen, J.-T. Synthesis and crystal structure of the first d-f heterodinuclear Dy(III)-Cu(II) cryptate. J. Chem. Soc., Chem. Commun. 2000, 12, 1033-1034.
30. 2+ in competitive aqueous media. J. Chem. Soc., Perkin Trans., II 2000, 9, 1819-1831.
31. Sakamoto, M.; Manseki, K.; Okawa, H. d-f Heterodinuclear complexes: synthesis, structures and physicochemical aspects. Coord. Chem. Rev. 2001, 219-221, 379-414.
32. Taniguchi, S. Acylating reaction of 4-methylphenol. Bull. Chem. Soc. Jpn. 1984, 57, 2683-2684.
33. Kimura, E.; Young, S.; Collman, J.P. Research on the preparation of tris(2-aminoethyl)-amine. Inorg. Chem. 1970, 9, 118-124.
34. Miller, R.R.; Brandt, W.W.; Puke, M. Metal-amine coordination compounds. V. The ruthenium-2,2′-bipyridine system. J. Chem. Soc. 1955, 11, 3178-3180.
35. Houten, J.V.; Watts, R.J. Temperature dependence of the photophysical and photochemical properties of the tris(2,2′-bipyridyl)ruthenium(II) ion in aqueous solution. J. Am. Chem. Soc. 1976, 98, 4853-4858.
36. Eaton, D.F. Reference materials for fluorescence measurement. Pure Appl. Chem. 1988, 60, 1107-1114.