Deuterium Migration Mechanism in Chiral Thiolactam Formation by Neutron Diffraction Analysis

Chemistry Letters

Volumn 32, Issue 8, 2003, Pages 742-743

  Hosoya, Takaaki ^a   Uekusa, Hidehiro ^a   Ohashi, Yuji ^a   Ohhara, Takashi ^b   Kimura, Hiroyuki ^c   Noda, Yukio ^c  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

^b INSTITUTE OF MATERIALS STRUCTURE SCIENCE   (Japan)

^c TOHOKU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON; CYCLOHEXENE DERIVATIVE; DEUTERIUM; LACTAM DERIVATIVE; N,N DIBENZYL 1 CYCLOHEXENECARBOTHIOMIDE; UNCLASSIFIED DRUG;

ARTICLE; ATOM; CHEMICAL BOND; CHIRALITY; CRYSTAL STRUCTURE; DIFFRACTION; LIGHT; MOLECULAR DYNAMICS; NEUTRON;

EID: 0242636239     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2003.742     Document Type: Article

References (14)

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10. 7)amine. Yellow prismatic crystals for neutron diffraction were obtained from diethyl ether solution.
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12. 2 (the molecule geometry was refined as a rigid body and the thermal parameters of non-hydrogen atoms and H3′ and D3′ were also refined). Crystallographic data reported in this paper have been deposited with Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-211585, 2U586. Copies of the data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12, Union Road, Cambridge CB2 1EZ, UK; fax:+44 1223 336033;or deposit@ccdc.cam.ac.uk).
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14. The X-ray analysis of 2a indicates that the positions of H3′ and D3′ are almost on the plane of H3-C3-C3′.