Asymmetric synthesis of (S)-alkylamines via reductive transamination of ketones over carbon-supported palladium catalysts

Journal of Molecular Catalysis A: Chemical

Volumn 146, Issue 1-2, 1999, Pages 129-138

  Gobolos S ^a   Tfirst, E ^a   Margitfalvi, J L ^a   Hayes, K S ^b  

^a CHEMICAL RESEARCH CENTER   (Hungary)

^b AIR PRODUCTS AND CHEMICALS INC   (United States)

Author keywords

2 Butanamine; Chiral modifiers; Conformational analysis; Enantioselective amination; Enantioselective hydrogenation; Methoxyacetone; Methoxyisopropylamine; Methylethylketone; Palladium catalyst; Reductive transamination; Schiff base

Indexed keywords

ACETONE; ALANINE DERIVATIVE; ALIPHATIC AMINE; AMINE; KETONE; PALLADIUM; PROPYLAMINE;

AMINATION; CATALYST; CHIRALITY; CONFERENCE PAPER; DIASTEREOISOMER; ENANTIOMER; HYDROGENATION; SYNTHESIS;

EID: 0242572620     PISSN: 13811169     EISSN: None     Source Type: Journal    
DOI: 10.1016/S1381-1169(99)00083-7     Document Type: Conference Paper

References (6)

1. Brown H.C., Kim K.W., Cole T.E., Singaram B. J. Am. Chem. Soc. 108:1986;6761.
2. Borszéky K., Mallát T., Aeschiman R., Schweizer W.B., Baiker A. J. Catal. 161:1996;451.
3. Mariella R.P., Leech J.L. J. Am. Chem. Soc. 71:1949;3558.
4. Hewes K.A., Martin D.F. J. Environ. Sci. Health, Part A. A19(6):1984;713-724.
5. Castiglioni M., Giordano R., Sappa E., Volpe P. J. Chromatogr. 349:1985;173.
6. Prelog V. Helv. Chim. Acta. 36:1953;308.