Light-Catalyzed Chromium(VI) Reduction by Organic Compounds and Soil Minerals

Journal of Environmental Quality

Volumn 32, Issue 6, 2003, Pages 2076-2084

  Tzou, Y M ^a   Loeppert, R H ^a   Wang, M K ^b  

^a TEXAS A AND M UNIVERSITY   (United States)

^b NATIONAL TAIWAN UNIVERSITY   (Taiwan)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; CHROMIUM; LIGHT; ORGANIC COMPOUNDS; REDUCTION; SEDIMENTS; SOILS;

AQUATIC SYSTEMS;

ENVIRONMENTAL ENGINEERING;

CHROMIUM; FERRIC ION; FERRIHYDRITE; FERROUS ION; MINERAL; ORGANIC COMPOUND; SILICON DIOXIDE; SOIL ORGANIC MATTER; TITANIUM DIOXIDE; UNCLASSIFIED DRUG;

AQUATIC ENVIRONMENT; ARTICLE; CATALYSIS; CHEMICAL REACTION KINETICS; COLLOID; DETOXIFICATION; ELECTRICITY; ELECTRON TRANSPORT; ENERGY; ENVIRONMENTAL RECLAMATION; FLUORESCENT LIGHTING; LABORATORY; LIGHT; PH; PHOTON; REDUCTION; SEDIMENT; SEMICONDUCTOR; SOIL POLLUTION; SURFACE SOIL; ULTRAVIOLET IRRADIATION; WASTE WATER;

EID: 0242543426     PISSN: 00472425     EISSN: None     Source Type: Journal    
DOI: 10.2134/jeq2003.2076     Document Type: Article

References (36)

1. Barnhart, R.J. 1997. Occurrences, uses, and properties of chromium. Regul. Toxicol. Pharmacol. 26:53-57.
2. Bartlett, R.J., and B.R. James. 1996. Chromium. p. 683-701. In D.L. Sparks (ed.) Methods of soil analysis. Part 3. SSSA Book Ser. 5. SSSA, Madison, WI.
3. Blowes, D.W., C.J. Ptacek, and J.L. Jambor. 1997. In-situ remediation of Cr(VI)-contaminated groundwater using permeable reactive walls: Laboratory studies. Environ. Sci. Technol. 31:3348-3357.
4. Cary, E.E., and J. Kubota. 1990. Chromium concentration in plants: Effects of soil chromium concentration and tissue contamination by soil. J. Agric. Food Chem. 38:108-114.
5. Cornell, R.M., and P.W. Schindler. 1987. Photochemical dissolution of goethite in acid oxalate solution. Clays Clay Miner. 35:347-352
6. Davies, S.H.R., and J.J. Morgan. 1988. Manganese(II) oxidation kinetics on oxide surfaces. J. Colloid Interface Sci. 129:63-77.
7. Della Guardia, R.A., and J.K. Thomas. 1983. Photoprocesses on colloidal clay systems. Tris(2,2′-bipyridine)ruthenium(II) bound to colloidal kaolin and montomorillonite. J. Phys. Chem. 87:990-998.
8. 2-Cr(VI)-mandelic acid system. Environ. Sci. Technol. 30:463-472.
9. Deng, B., and A.T. Stone. 1996b. Surface-catalyzed chromium(VI) reduction: Reactivity comparisons of different organic reductants and different oxide surfaces. Environ. Sci. Technol. 30:2484-2494.
10. 2 in the absence of Mn-bacteria or surface catalysts? Geochim. Cosmochim. Acta 48:1571-1573.
11. Eaton, A.D., L.S. Clesceri, and A.E. Greenberg. (ed.) 1995. Standard methods for the examination of water and wastewater. Am. Public Health Assoc., Washington, DC.
12. Elovitz, M.S., and W. Fish. 1994. Redox interactions of Cr(VI) and substituted phenols-Kinetic investigation. Environ. Sci. Technol. 28:2161-2169.
13. Elovitz, M.S., and W. Fish. 1995. Redox interactions of Cr(VI) and substituted phenols - Products and mechanism. Environ. Sci. Technol. 29:1933-1943.
14. 2 as photocatalyst. J. Photochem. Photobiol. A 114:81-88.
15. Gimenez, J., M.A. Aguado, and S. Cervera-March. 1996. Photocatalytic reduction of chromium(VI) with titania powders in a flow system, kinetics and catalyst activity. J. Mol. Catal. A Chem. 105:67-78.
16. Hug, S.J., H.U. Laubscher, and B.R. James. 1997. Iron(III) catalyzed photochemical reduction of chromium(VI) by oxalate and citrate in aqueous solutions. Environ. Sci. Technol. 31:160-170.
17. Ishibashi, Y., C. Cervantes, and S. Silver. 1990. Chromium reduction in pseudomonas-putida. Appl. Environ. Microbiol. 56:2268-2270.
18. Johnson, C.A., L. Sigg, and U. Lindauer. 1992. The chromium cycle in a seasonally anoxic lake. Limnol. Oceanogr. 37:315-321.
19. Krenske, D., S. Abdo, H. Van Damme, M. Cruz, and J.J. Fripiat. 1983. Photochemical and photocatalytic properties of adsorbed organometallic compounds. 1. Luminescence quenching of tri(2,2′-bipyridine)ruthenium(II) and -chromium(III) in clay membranes. J. Phys. Chem. 84:2447-2457.
20. Loeppert, R.H., and W.P. Inskeep. 1996. Iron. p. 639-664. In D.L. Sparks (ed.) Methods of soil analysis. Part 3. SSSA Book Ser. 5. SSSA, Madison, WI.
21. Marcus, R.A. 1965. The theory of electron-transfer reactions. VI. Unified treatment for homogeneous and electrode reactions. J. Chem. Phys. 43:679-691.
22. Miles, C.J., and P.L. Brezonik. 1981. Oxygen-consumption in humic-colored waters by a photochemical ferrous-ferric catalytic cycle. Environ. Sci. Technol. 15:1089-1095.
23. Patterson, R.R., and S. Fendorf. 1997. Reduction of hexavalent chromium by amorphous iron sulfide. Environ. Sci. Technol. 31:2039-2044.
24. Peterson, M.L., G.E. Brown, Jr., and G.A. Parks. 1996. Direct XAFS evidence for heterogeneous redox reaction at the aqueous chromium/magnetite interface. Colloids Surf. A 107:77-88.
25. 2 particles in contact with Cr(VI) aqueous solutions. J. Colloid Interface Sci. 230:181-185.
26. Schwertmann, U., and R.M. Cornell. 1991. Iron oxides in the laboratory. VCH Publ., New York.
27. Siffert, C., and B. Sulzberger. 1991. Light-induced dissolution of hematite in the presence of oxalate-A case study. Langmuir 7:1627-1634.
28. Stumm, W. 1992. Chemistry of the solid-water interface, processes at the mineral-water and particle-water interface in natural systems. John Wiley & Sons, New York.
29. Sung, W., and J.J. Morgan. 1980. Kinetics and product of ferrous iron oxygenation in aqueous systems. Environ. Sci. Technol. 14:561-568.
30. Torrents, A., and A.T. Stone. 1991. Hydrolysis of phenyl picolinate at the mineral/water interface. Environ. Sci. Technol. 25:143-149.
31. Tzou, Y.M. 2001. Surface and solution abiotic processes in the redox transformations of chromium. Ph.D. diss. Texas A&M Univ., College Station.
32. Tzou, Y.M., M.K. Wang, and R.H. Loeppert. 2003. Effect of phosphate, HEDTA, and light sources on Cr(VI) retention by goethite. Soil Sediment Contam. 12:69-84.
33. Waite, T.D. 1990. Photochemistry of colloids and surfaces in natural waters and water treatment. p. 27-44. In R. Beckett (ed.) Chemistry of colloids and surfaces in natural waters and water treatment. Plenum Press, New York.
34. Wehrli, B., B. Sulzberger, and W. Stumm. 1989. Redox processes catalyzed by hydrous oxide surfaces. Chem. Geol. 78:167-179.
35. Wittbrodt, P.R., and C.D. Palmer. 1995. Reduction of Cr(VI) in the presence of excess soil fulvic-acid. Environ. Sci. Technol. 29:255-263.
36. Wittbrodt, P.R., and C.D. Palmer. 1996. Effect of temperature, ionic strength, background electrolytes, and Fe(III) on the reduction of hexavalent chromium by soil humic substances. Environ. Sci. Technol. 30:2470-2477.