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For example, traces of 2a catalyse carbon-carbon double bond shifts, even at room temperature[4b]
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For example, traces of 2a catalyse carbon-carbon double bond shifts, even at room temperature[4b].
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4-alkyne) butterfly substructure, the lengths of the metal coordipated alkyne carbon-carbon bonds range from 1.339 to 1.534 A, with the maximum of the distribution around 1.44 A. The extreme values belong to isolated cases with questionable accuracy based on a search of the Cambridge Crystallographic Database
-
4-alkyne) butterfly substructure, the lengths of the metal coordipated alkyne carbon-carbon bonds range from 1.339 to 1.534 A, with the maximum of the distribution around 1.44 A. The extreme values belong to isolated cases with questionable accuracy (based on a search of the Cambridge Crystallographic Database).
-
-
-
-
50
-
-
33745339299
-
-
3-phenylacetylene cluster complexes 3 and 4 only a less rigorous statement could be made (one of the two processes must be slow on the NMR time scale), due to the higher symmetry of these alkynes[5]
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3-phenylacetylene cluster complexes 3 and 4 only a less rigorous statement could be made (one of the two processes must be slow on the NMR time scale), due to the higher symmetry of these alkynes[5].
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55
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33745373795
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c)/2.0823 J. Sandström, Dynamic NMR Spectroscopy, Academic Press, London 1982
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c)/2.0823 (J. Sandström, Dynamic NMR Spectroscopy, Academic Press, London 1982).
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Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-100I53. Copies of the data may be obtained free of charge on application to the Director, CCDC, 12 Union Road, Cambridge CB2 1EZ, UK [fax: int. code +44(1223)336-033, e-mail: deposit@chemcrys.cam.ac.uk]
-
Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-100I53. Copies of the data may be obtained free of charge on application to the Director, CCDC, 12 Union Road, Cambridge CB2 1EZ, UK [fax: int. code +44(1223)336-033, e-mail: deposit@chemcrys.cam.ac.uk].
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