Oxidative Addition of the Carbon-Hydrogen Bonds of Neopentane and Cyclohexane to a Photochemically Generated Iridium(I) Complex

Journal of the American Chemical Society

Volumn 104, Issue 13, 1982, Pages 3723-3725

  Hoyano, James K ^a   Graham, William A G ^a  

^a UNIVERSITY OF ALBERTA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0242524722     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00377a032     Document Type: Article

References (22)

1. Shortly after the submission of this communication, we learned that similar results had been reported for a closely related iridium system: Janowicz, A. H.; Bergman, R. G. J. Am. Chem. Soc. 1982, 104, 352;
2. 3P species should have an even greater tendency than the carbonyl to undergo oxidative-addition reactions, although the behavior seems roughly similar in the reactions so far examined. Differences in selectivities might be expected, and distinctions may arise in secondary reactions of the phosphine and carbonylindium(III) complexes.
3. 6.
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