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It is however not surprising that such large equivalent packing fractions still correspond to fluid oxygen in thermodynamic equilibrium. This is due to the fact that the real fluid has degrees of freedom which are unaccounted for in the spherical approximation, i.e., rotational and vibrational, resulting in a larger entropy than its spherically modeled counterpart.
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We note that for this reason correcting the kinetic contribution to the thermal conductivity to account for the internal degrees of freedom as proposed by Eucken for polyatomic gases [26] is largely irrelevant at high densities; it would lead in fact to an extremely small increase in the overall Enskog theory prediction.
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