Hollow fiber membranes obtained by simultaneous spinning of two polymer solutions: A morphological study

Journal of Membrane Science

Volumn 226, Issue 1-2, 2003, Pages 35-50

  Pereira, Cristina C ^a   Nobrega, Ronaldo ^a   Peinemann, K V ^b   Borges, Cristiano P ^a  

^a FEDERAL UNIVERSITY OF RIO DE JANEIRO   (Brazil)

^b INSTITUTE OF MATERIALS RESEARCH   (Germany)

Author keywords

Double layer membranes; Gas separation; Membrane preparation and structure; Simultaneous casting

Indexed keywords

ADHESION; FIBERS; POLYETHERIMIDES; POLYSULFONES; PRECIPITATION (CHEMICAL); SCANNING ELECTRON MICROSCOPY; SOLUBILITY;

CLOUD-POINT EXPERIMENTS;

POLYMERIC MEMBRANES;

1 METHYL 2 PYRROLIDINONE; ADIPIC ACID; BASE; LEWIS ACID; LEWIS BASE; POLYETHERIMIDE; POLYETHERSULFONE; POLYMER; POVIDONE; TETRAHYDROFURAN; UNCLASSIFIED DRUG; VOLATILE AGENT; WATER;

ARTICLE; CHEMICAL COMPOSITION; LIQUID; MEMBRANE STRUCTURE; MISCIBILITY; MOLECULAR STABILITY; PRECIPITATION; PRIORITY JOURNAL; SCANNING ELECTRON MICROSCOPY;

EID: 0242490901     PISSN: 03767388     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.memsci.2003.07.011     Document Type: Article

References (29)

1. Pinnau I. Recent advances in the formation of ultrathin polymeric membranes for gas separation. Polymer Adv. Technol. 5:1994;733.
2. W.J. Koros, R. Mahajan, Pushing the limits on possibilities for large scale gas separation: which strategies?, 175 (2000) 181.
3. R.W. Baker, E.L. Cussler, W. Eykamp, W.J. Koros, R.L. Riley, H. Strathmann, Membrane Separation Systems. Recent Development and Future Directions, Noyes Data Corporation, 1991.
4. Koros W.J., Fleming G.K. Membrane-based gas separation. J. Membrane Sci. 83:1993;1.
5. Ghosal K., Freeman B.D. Gas separation using polymer membranes: an overview. Polymers Adv. Technol. 5:1994;673.
6. Clausi D.T., Koros W.J. Formation of defect-free polyimide hollow fiber membranes for gas separations. J. Memb. Sci. 167:2000;79.
7. Loeb S., Sourirajan S. Adv. Chem. Ser. 38:1962;117.
8. Van't Hof J.A., Reuvers A.J., Boom R.M., Rolevink H.H.M., Smolders C.A. Preparation of asymmetric gas separation membranes with high selectivity by dual bath coagulation method. J. Membr. Sci. 70:1992;17-30.
9. A.J. Reuvers, Membrane formation. Diffusion induced demixing processes in ternary systems, Ph.D. thesis, University of Twente, The Netherlands, 1987.
10. Li S.-G., Koops G.H., Mulder M.H.V., Boomgard Th.V.D., Smolders C.A. Wet spinning of integrally skinned hollow fiber membranes by a modified dual-bath method using a triple layer spinneret. J. Membr. Sci. 94:1994;329-340.
11. G.H. Koops, S.-G. Li, Th.V.D. Boomgard, M.H.V. Mulder, C.A. Smolders, Dutch Patent 91.02151 (1991).
12. Y. Kusuki, T. Yoshinaga, H. Shimazaki, Aromatic polyimide double layered hollow filamentary membrane and producing same, US Patent 5,141,642 (1992).
13. Strathmann H. Membrane separation processes: current relevance and future opportunities. AIChe J. 47:2001;1077.
14. Fritzsche A.K., Cruse C.A., Kesting R.E., Murphy M.K. Polysulfone hollow fiber membranes spun from Lewis acid:base complexes. II. The effect of Lewis acid to base ratio on membrane structure. J. Appl. Pol. Sci. 39:1990;1949.
15. Fritzsche A.K., Cruse C.A., Kesting R.E., Murphy M.K. Hollow fiber membranes spun from Lewis acid:base complexes. I. Structure determination by oxygen plasma ablation. J. Appl. Pol. Sci. 40:1990;19.
16. Pereira C.C., Souza J.N.M., Nobrega R., Borges C.P. Hollow fiber formation by using Lewis acid:base complex in the polymer solution. J. Appl. Pol. Sci. 81(4):2001;908.
17. Pereira C.C., Nobrega R., Borges C.P. Membrane with presence of Lewis acid:base complexes in polymer solution. J. Appl. Pol. Sci. 83:2002;2022.
18. Pinnau I., Wind J., Peinemann K.V. Ultrathin multicomponent poly(ether sulfone) membranes for gas separation made by dry/wet phase inversion. Ind. Eng. Chem. Res. 29:1990;2028.
19. Pesek S.C. Aqueous quenched asymmetric polysulfone membranes prepared by dry/wet phase separation. J. Memb. Sci. 88:1994;1.
20. Pereira C.C., Nobrega R., Borges C.P. Membranes obtained by simultaneous casting of two polymer solutions. J. Memb. Sci. 192:2001;11.
21. C.P. Borges, Fibras ocas compostas para a remoção de poluentes orgânicos de soluções aquosas pelo processo de pervaporação, D.Sc. thesis, COPPE/Federal University of Rio de Janeiro, Brazil, 1993.
22. Peinemann K.-V., Maggioni J.F., Nunes S.P. Poly(ether imide) membranes obtained from solution in cosolvent mixtures. Polymer. 39(15):1998;3411.
23. P. Manos, Membrane drying process, US Patent 4,080,743, E.I. Du Pont de Nemours, 1978.
24. P. Manos, Solvent exchange drying of membrane for gas separation, US Patent 4,120,098, E.I. Du Pont de Nemours, 1978.
25. R.M. Boom, Membrane formation by immersion precipitation: the role of a polymeric additive, University of Twente, The Netherlands, 1992.
26. Machado P.S.T., Habert A.C., Borges C.P. Membrane formation mechanism based on precipitation kinetics and membrane morphology: flat and hollow fiber polysulfone membranes. J. Memb. Sci. 155:1999;171.
27. Pereira C.C., Nobrega R., Borges C.P. Spinning process variables and polymer solution effects in the die-swell phenomenon during hollow fiber membranes formation. Braz. J. Chem. Eng. 17(4):2000;599.
28. Boom R.M., Wienk I.M., Van den Boomgaard T. Microstructures in phase inversion membranes. 2. The role of a polymeric additive. J. Memb. Sci. 73:1992;277.
29. Di Luccio M., Nobrega R., Borges C.P. Microporous anisotropic phase inversion membranes from bisphenol a polycarbonate: effect of additives to the polymer solution. J. Appl. Polymer Sci. 86:2002;3085.