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0242484727
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7
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0242653178
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0242401397
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note
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This energy shift is equivalent to raising the energy of the ground-state product by the reorganization energy.
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There is no evidence that reactions between the radical anions themselves produce other than a normal E/A polarization. It is not possible to form only the radical anions, but mixtures with an OH adduct (hydroxycyclohexadienyl radical) can be made.
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0242653179
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Under the condition for 5 and 50 mM solutions, about 50 and 100% of incident photons were absorbed by phenolate, respectively. For the 50 mM solution, the initial radical concentration at high laser doses approaches 1 mM. The initial half-life of the radicals is about 100 ns under such a condition. The initial yield of the hydrated electron will be underestimated when extrapolation from the electron decay curve on a longer time scale to time zero is used.
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36
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0001563020
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