Interfacial Interactions-Controlled Thermoelasticity and Stress Relaxation Behavior of Synthetic Rubber/Organoclay Nanocomposites

Journal of Macromolecular Science - Physics

Volumn 42 B, Issue 6, 2003, Pages 1183-1196

  Privalko, V P ^a   Ponomarenko, S M ^a   Privalko, E G ^a   Schon F ^b   Gronski, W ^b  

^a INSTITUTE OF MACROMOLECULAR CHEMISTRY   (Ukraine)

^b UNIVERSITY OF FREIBURG   (Germany)

Author keywords

Filler clusters; Interfacial inter actions; Stress relaxation; Synthetic rubber organoclay nanocomposites; Thermo elasticity

Indexed keywords

CLAY; STRESS RELAXATION; STRETCHING; SYNTHETIC RUBBER; THERMAL EFFECTS; THERMOELASTICITY; X RAY SCATTERING;

ORGANOCLAY;

NANOSTRUCTURED MATERIALS;

EID: 0242413837     PISSN: 00222348     EISSN: None     Source Type: Journal    
DOI: 10.1081/MB-120024813     Document Type: Article

References (16)

1. Mullins, L. Reinforcement of Elastomers; Kraus, G., Ed.; Interscience Publ.: New York, 1965.
2. Bartenev, G.M. Structure and Relaxation Behavior of Elastomers; Khimia: Moscow, 1979 (in Russian).
3. Mullins, L.; Tobin, N.R. Stress softening in rubber vulcanizates. Part I. Use of a strain amplification factor to describe the elastic behavior of filler-reinforced vulcanized rubber. J. Appl. Polymer Sci. 1965, 9, 2993-3009.
4. Harwood, J.A.; Mullins, L.; Payne, A.R. Stress softening in rubber vulcanizates. Part II. Stress softening effects in pure gum and filler loaded rubbers. J. Appl. Polymer Sci. 1965, 9, 3011-3021.
5. Govingee, S.; Simo, J. Micro-mechanically based continuum damage model for carbon black-filled rubbers incorporating Mullins effect. J. Mech. Phys. Solids 1991, 39, 87-112.
6. Ambacher, H.; Strauss, M.; Kilian, H.-G.; Wolff, S. Reinforcement in filler-loaded rubbers. Kautschuk-Gummi-Kunststoffe 1991, 44, 1111-1120.
7. Witten, T.A.; Rubinstein, M.; Colby, R.H. Reinforcement of rubber by fractal aggregates. J. Phys. II (France) 1993, 3, 367-383.
8. Klueppel, M.; Schramm, J. A generalized tube model of rubber elasticity and stress softening of filler reinforced elastomer systems. Macromol. Theor. Simul. 2000, 9, 742-754.
9. Klueppel, M.; Schuster, R.H.; Heinrich, G. Rubber Chem. Technol. 1997, 70, 243.
10. Schön, F.; Thomann, R.; Gronski, W. Shear controlled morphology of rubber/organoclay nanocomposites and dynamic mechanical analysis, Macromol. Symp. 2002, 189, 105-110.
11. Ganter, M.; Gronski, W.; Reichert, P.; Mülhaupt, R. Rubber nanocomposites: morphology and mechanical properties of BR and SBR vulcanizates reinforced by organophilic layered silicates. Rubber Chem Technol. 2001, 74, 221-235.
12. Mirontsov, L.I. Thermodynamics of Deformation of Segmented Polyurethanes. PhD thesis, Institute of Macromolecular Chemistry, National Academy of Sciences of Ukraine, Kyiv, 1987.
13. Sukhorukov, D.I. Thermodynamics of Reversible and Irreversible Deformations at the Uniaxial Loading of Filled Polymers. PhD thesis, Institute of Macromolecular Chemistry, National Academy of Sciences of Ukraine, Kyiv, 2001.
14. Lepoittevin, B.; Devalckenaere, M.; Pantoustier, N.; Alexandre, M.; Kubies, D.; Calberg, C.; Jerome, R.; Dubois, P. Poly(ε-caprolactone)/clay nanocomposites prepared by melt intercalation: mechanical, thermal and rheological properties. Polymer 2002, 43, 4017-4023.
15. Godovsky, Yu.K. Thermal Physics of Polymers; Springer Verlag: Munich, 1991.
16. Ferry, J.D. Viscoelastic Properties of Polymers; John Wiley & Sons: New York, 1970.