Spin states of C603- and C120On- (n = 2, 3, 4) anions using electron spin transient nutation spectroscopy

Journal of Physical Chemistry B

Volumn 107, Issue 41, 2003, Pages 11353-11359

  Drew, Simon C ^a,b,d   Boas, John F ^a   Pilbrow, John R ^a   Boyd, Peter D W ^b   Paul, Parimal ^c,e   Reed, Christopher A ^c  

^a MONASH UNIVERSITY   (Australia)

^b UNIVERSITY OF AUCKLAND   (New Zealand)

^c UNIVERSITY OF CALIFORNIA   (United States)

^d UNIVERSITY OF QUEENSLAND   (Australia)

^e Bhavnagar 364002   (India)

Author keywords

[No Author keywords available]

Indexed keywords

CALCULATIONS; ELECTRON SPIN RESONANCE SPECTROSCOPY; ELECTRON TRANSITIONS; GROUND STATE; MOLECULAR STRUCTURE; NEGATIVE IONS;

ELECTRON SPIN TRANSIENT NUTATION SPECTROSCOPY; EXCITED STATE; MOLECULAR ORBITAL CALCULATION;

FULLERENES;

EID: 0242365449     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp035632x     Document Type: Article

References (25)

1. Allemand, P.-M.; Khemani, K. C.; Koch, U.; Wudl, F.; Holczer, K.; Donovan, G.; Grüner, G.; Thompson, J. D. Science 1991, 253, 301.
2. Hebard, A. F.; Rosseinsky, M. J.; Haddon, R. C.; Murphy, D. W.; Glarum, S. H.; Palstra, T. T. M.; Ramirez, A. P.; Kortan, A. R. Nature 1991, 350, 600.
3. Haddon, R. C.; Brus, L. E.; Raghavachari, K. Chem. Phys. Lett. 1986, 125, 450.
4. Eaton, S. S.; Eaton, G. G. Appl. Magn. Reson. 1996, 11, 155.
5. Reed, C. A.; Bolskar, R. D. Chem. Rev. 2000, 100, 1075.
6. Boas, J. F.; Drew, S. C.; Pilbrow, J. R.; Boyd, P. D. W.; Paul, P.; Sun, D.; Reed, C. A. Proceedings of 27th Annual A & NZ IP condensed Matter and Materials Meeting (Wagga 2003); Cashion, J. D., Finlayson, T. R., Paganin, D. G., Smith, A. E., Troup, G. J., Eds.; www.aip.org.au; in press, 2003.
7. Eaton, S. S.; Kee, A.; Konda, R.; Eaton, G. R.; Trulove, P. C.; Carlin, R. T. J. Phys. Chem. 1996, 100, 6910.
8. Boas, J. F.; Drew, S. C.; Pilbrow, J. R.; Boyd, P. D. W.; Paul, P.; Sun, D.; Reed, C. A. manuscript in preparation, 2003.
9. Paul, P.; Kim, K.-Q.; Sun, D.; Boyd, P. D. W.; Reed, C. A. J. Am. Chem. Soc. 2002, 124, 4394.
10. n- with solvent (or solvent impurities) occurs. See Rapta, P.; Bartl, A.; Gromov, A.; Stasko, A.; Dunsch, L. ChemPhysChem, 2002, 3, 351.
11. 60 and Other Icosahedral Complexes; Princeton University Press: 1997.
12. Astashkin, A. V.; Schweiger, A. Chem. Phys. Lett. 1990, 174, 595.
13. Schweiger, A.; Jeschke, G. Principles of Pulse Electron Paramagnetic Resonance; Oxford University Press: 2001; Chapter 14.
14. Candida, M.; Shohoji, B. L.; Luisa, M.; Franco, T. M. B.; Celina, M.; Lanzana, R. L. R.; Nakazawa, S.; Sato, K.; Shiomi, D.; Takui, T. J. Am. Chem. Soc. 2000, 122, 2962.
15. Stoll, S.; Jeschke, G.; Willer, M.; Schweiger, A. J. Magn. Reson. 1998, 130, 86.
16. Wertz, J. E.; Orton, J. W.; Auzins, P. Discuss. Faraday Soc. 1961, 30, 140.
17. Weil, J. A.; Bolton, J. R.; Wertz, J. E. Electron Paramagnetic Resonance: Elementary Theory and Practical Applications; Wiley-Interscience: New York, 1994; p 511.
18. Schweiger, A.; Jeschke, G. Principles of Pulse Electron Paramagnetic Resonance; Oxford University Press: 2001; p. 183.
19. prep. There are circumstances where an analogue of the PEANUT pulse, sequence, without a preparation pulse, may be employed with advantage, see for example Tregenna-Piggot, P. L. W.; Noble, C. J.; Pilbrow, J. R. J. Chem. Phys. 2000, 113, 3289.
20. Stoll, S. Diploma Thesis, TU Graz, 1996.
21. Schweiger, A.; Jeschke, G. Principles of Pulse Electron Paramagnetic Resonance; Oxford University Press: 2001; p 429.
22. 1 ∼ |D| is discussed by Kentgens, A. P. M.; Lemmens, J. J. M.; Guerts, F. M. M.; Veeman, W. S. J. Magn. Reson. 1987, 71, 62.
23. Weger, M. Bell Syst. Tech. J. 1960, 39, 1013.
24. Drew, S. C. Ph.D. Thesis, Monash University, 2002, Chapter 7.
25. Pake, G. E.; Estle, S. C. The Physical Principles of Electron Paramagnetic Resonance, 2nd ed.; Benjamin: Reading, MA, 1973. Equations 5.29 and 5.36 have been combined and some symbols changed.