Kinetics of p-xylene liquid phase catalytic oxidation. (I) Reaction mechanism and kinetic model

Huagong Xuebao/Journal of Chemical Industry and Engineering (China)

Volumn 54, Issue 7, 2003, Pages 946-952

  Wang, Lijun ^a   Li, Xi ^a   Xie, Gang ^a   Cheng, Youwei ^a   Sima, Jian ^a  

^a ZHEJIANG UNIVERSITY   (China)

Author keywords

Kinetics; Oxidation; p xylene; Reaction mechanism

Indexed keywords

CATALYSIS; CATALYSTS; FREE RADICAL REACTIONS; MATHEMATICAL MODELS; OXIDATION; REACTION KINETICS;

COBALT MANGANESE BROMIDE CATALYST; GAS LIQUID SOLID REACTION; KINETIC MODEL; REACTION MECHANISM;

XYLENE;

EID: 0242364610     PISSN: 04381157     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (7)

1. Partenheimer W. Methodology and Scope of Metal/Bromide Autoxidation of Hydrocarbons. Catalysis Today, 1995, 23: 69-158
2. Partenheimer W. Catalysis of Organic Reactions, Chapter 20. New York: Marcel Dekker, 1990
3. Cincotti A, Orru R, Broi A, Cao G. Effect of Catalyst Concentration and Simulation of Precipitation Processes on Liquid-phase Catalytic Oxidation of p-Xylene to Terephthalic Acid. Chemical Engineering Science, 1997, 4205-4213
4. Cincotti A, Orru R, Broi A, Cao G. Kinetics and Related Engineering Aspects of Catalytic Liquid-phase Oxidation of p-Xylene. Catalysis today, 1999, 52: 331-347
5. Roger A Sheldon, Jay K Kochi. Metal-catalyzed Oxidation of Organic Compounds. New York: Academic Press Inc., 1981
6. Scott E J Y, Chester A W. Kinetics of the Cobalt-catalyzed Autoxidation of Toluene in Acetic Acid. The Journal of Physical Chemistry, 1978, 76: 1520-1524
7. Ou Canqi, Lu Dewei. Engineering and Process of Oxidation Reaction in Petrochemical. Beijing: Sinopec Press, 1990