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note
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The photoacoustic method consists of illuminating the sample with chopped monochromatic light in an airtight cell connected to a microphone. The light is absorbed and converted to heat. The chopped heat then flows to the surface of the sample where it produces an acoustic wave. The wave is detected with a lock-in voltmeter. The signal, which is acquired as a function of wavelength, is normalized against the absorption of carbon black powder, a 100% absorber. The instrument operates over the wavelength region 300-1600 nm. The spectrum is independent of the nature of the sample unlike reflectance spectroscopy, where the nature of the surface can have a marked effect on the spectrum. The photoacoustic spectra show features that are much better resolved than in the absorption spectra.
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