Homogeneous Catalyzed Ozone Decomposition in the Presence of Co (II)

Ozone: Science and Engineering

Volumn 25, Issue 4, 2003, Pages 261-271

  Rivas, F J ^a   Beltran F J ^a   Carbajo, M ^a   Gimeno, O ^b  

^a UNIVERSITY OF EXTREMADURA   (Spain)

^b University of Bath   (United Kingdom)

Author keywords

Catalytic Ozonation; Cobalt; Drinking Water Treatment; Homogeneous Catalysis; Kinetic Modeling; Ozone

Indexed keywords

ACTIVATION ENERGY; CATALYSTS; COBALT; COMPUTER SIMULATION; DECOMPOSITION; OPTIMIZATION; PH EFFECTS;

RADICAL MECHANISMS;

OZONE;

ARRHENIUS;

EID: 0242349781     PISSN: 01919512     EISSN: None     Source Type: Journal    
DOI: 10.1080/01919510390481586     Document Type: Article

References (19)

1. Andreozzi, R., Caprio, V., Damore, M. and Insola A., "Manganese Catalysis In Water Pollutants Abatement By Ozone", Environm. Technol. 16 (9): 885-891 (1995).
2. Anmdreoozi, R., Caprio, V., Marotta, R. and Tufano, V., "Kinetic modeling of pyruvic acid ozonation in aqueous solutions catalyzed by Mn(II) and Mn(IV) ions", Wat. Res. 35 (1): 109-120 (2001).
3. Andreozzi, R., Caprio, V., Insola, A., Marotta R. and Tufano, V., "The ozonation of pyruvic acid in aqueous solutions catalyzed by suspended and disolved manganese", Wat. Res. 32: 1492-1496 (1998).
4. Andreozzi, R., Insola, A., Caprio, V. and Amore, M., "The kinetics of Mn (II)-catalysed ozonation of oxalic acid in aqueous solution", Wat. Res. 26: 917-921 (1992).
5. Andreozzi, R., Marotta, R. and Sanchirico, R., "Manganese catalysed ozonation of glyoxalic acid in aqueous solutions", J. Chem. Technol. & Biotechnol. 75: 59-65 (2000).
6. Bader, H. and Hoigné, J., "Determination of ozone in water by the indigo method", Wat. Res. 15: 449-456 (1981).
7. Chelkowska, K., Grasso, D., Fabian, I. and Gordon G., "Numerical simulations of aqueous ozone decomposition", Ozone Science and Engineering. 14: 33-49 (1992).
8. Rivas, F.J., Beltrán, F.J., Gimeno O. and Frades J., "Treatment of olive oil mill wastewater by Fenton's reagent", J. Agric. Food. Chem. 49: 1873-1880 (2001).
9. Hill, G., "Kinetics, mechanism and activation energy of the cobaltous ion catalysed decomposition of ozone", J. Am. Chem. Soc. 70: 1306-1307 (1948).
10. Hill, G., "The kinetics of the oxidation of cobaltous ion by ozone", J. Am. Chem. Soc. 71: 2434-2435 (1949).
11. Legube, B. and Vel Leitner, K., "Catalytic ozonation: a promising advanced oxidation technology for water treatment", Catalysis Today. 53: 61-72 (1999).
12. Ma, J. and Graham, N., "Preliminary investigation of manganese catalyzed ozonation for the destruction of atrazine", Ozone Science & Engineering. 19: 227-240 (1997).
13. Ma, J. and Graham, N., "Degradation of atrazine by manganese-catalyzed ozonation: influence of humic substances", Wat. Res. 33: 785-793 (1999).
14. Rakitskaya, T., Ennan A., Granatyuk I., Bandurko A., Balvoine G., Geletii Y. and Paina V., "Kinetics and mechanism of low temperature ozone decomposition by Co-ions adsorbed on silica", Cat. Today. 53: 715-723 (1999).
15. Reckhow, D., Knocke, W., Kearney, M. and Parks C., "Oxidation of iron and manganese by ozone", Ozone Science & Engineering. 13: 675-695 (1991).
16. Seby, F., Potin-Gautier, M., Castetbon, A. and Astruc, M., "Study of the ozone - manganese reaction and the interactions of disulfonate indigo carmin/oxidized manganese forms as a function of pH", Ozone Science & Engineering. 17: 135-147 (1994).
17. 2 initiated", J. Phys. Chem. A. 102: 2667-2672 (1998).
18. Sotelo, J.L., Beltran, F., Gonzalez M. and Domínguez J., "Effect of high salt concentrations on ozone decomposition in water", J. Environ. Sci. Health. A24: 823-842 (1989).
19. Westerhoff, P., Song, R., Amy, G. and Minear R. "Applications of ozone decomposition models", Ozone Science & Engineering. 19: 55-73 (1997).