Laser flash photolysis study of chlorofluorocarbene

Journal of Physical Chemistry A

Volumn 107, Issue 41, 2003, Pages 8547-8551

  Tippmann, Eric M ^a   Platz, Matthew S ^a  

^a OHIO STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHLOROFLUOROCARBENE; CYCLOPROPANE; LASER FLASH PHOTOLYSIS; TETRAMETHYLETHYLENE;

ABSORPTION; DENSITY (OPTICAL); FOURIER TRANSFORM INFRARED SPECTROSCOPY; GROUND STATE; LASER APPLICATIONS; PHOTOLYSIS; PROBABILITY DENSITY FUNCTION; RATE CONSTANTS; SYNTHESIS (CHEMICAL); THERMAL EFFECTS; ULTRAVIOLET SPECTROSCOPY;

FLUOROCARBONS;

EID: 0242333975     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp0345598     Document Type: Article

References (20)

1. Robert, M.; Toscano, J. P.; Platz, M. S.; Abbot, S. C.; Kirchhoff, M. M.; Johnson, R. P. J. Phys. Chem. 1996, 100, 18426.
2. Chateauneuf, J. E.; Johnson, R. P.; Kirchhoff, M. M. J. Am. Chem. Soc. 1990, 112, 3217.
3. For a review of fluorinated carbene chemistry, see Brahms, D. S.; Dailey, W. P. Chem. Rev. 1996, 96, 1585.
4. Gristan, N. P.; Zhaui, H. B.; Yuzawa, T.; Karweik, D.; Brooke, J.; Platz, M. S. J. Phys. Chem. A 1997, 101, 2833.
5. Yuzawa, T.; Kano, C.; George, M. W.; Hamaguchi, H. Appl. Spectrosc. 1994, 48, 684-690.
6. Iwata, K.; Hamaguchi, H. Appl. Spectrosc. 1990, 44, 1431.
7. Toscano, J. P. Adv. Photochem. 2001, 26, 41.
8. Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Zakrzewski, V. G.; Montgomery, J. A., Jr.; Stratmann, R. E.; Burant, J. C.; Dapprich, S.; Millam, J. M.; Daniels, A. D.; Kudin, K. N.; Strain, M. C.; Farkas, O.; Tomasi, J.; Barone, V.; Cossi, M.; Cammi, R.; Mennucci, B.; Pomelli, C.; Adamo, C.; Clifford, S.; Ochterski, J.; Petersson, G. A.; Ayala, P. Y.; Cui, Q.; Morokuma, K.; Malick, D. K.; Rabuck, A. D.; Raghavachari, K.; Foresman, J. B.; Cioslowski, J.; Ortiz, J. V.; Stefanov, B. B.; Liu, G.; Liashenko, A.; Pikorz, P.; Komaromi, I.; Gomperts, R.; Martin, R. L.; Fox, D. J.; Keith, T.; Al-Laham, M. A.; Peng, C. Y.; Nanayakkara, A.; Gonzalez, C.; Challacombe, M.; Gill, P. M. W.; Johnson, B. G.; Chen, W.; Wong, M. W.; Andres, J. L.; Head-Gordon, M.; Repglogle, E. S.; Pople, J. A. Gaussian 98; Gaussian, Inc.: Pittsburgh, PA, 1998.
9. Hartwig, J. F.; Jones, M., Jr.; Moss, R. A.; Lawrynowicz, W. Tetrahedron Lett. 1986, 27, 5907.
10. Doblier, W. R.; Burkholder, C. R. J. Org. Chem. 1990, 55, 589.
11. Closs, G. L.; Moss, R. A., J. Am. Chem. Soc. 1964, 86, 4042.
12. Moss, R. A.; Fan, H.; Gurumurthy, R.; Ho, G.-J. J. Am. Chem. Soc. 1991, 113, 1435.
13. Smith, C. E.; Milligan, D. E.; Jacox, M. E. J. Chem. Phys. 1971, 54, 2780.
14. Schwartz, M.; Peebles, L. R.; Berry, R. J.; Marshall, P., J. Chem. Phys. 2003, 118, 557.
15. He, Y.; Lemal, D. A. J. Fluorine Chem. 2003, 119, 75.
16. For references discussing the consequences of geminal difluoro substitution, see (a) Getty, S. J.; Hrovat, D. A.; Xu, J. D.; Barker, S. A.; Borden, W. T. J. Chem. Soc., Faraday Trans. 1994, 90, 1689.
17. (b) Wiberg, K. B.; Marquez, M. J. J. Am. Chem. Soc. 1998, 120, 2932.
18. (c) Greenberg, A.; Liebman, J.; Dolbier, W. R., Jr.; Medinger, K. S.; Skancke, A. Tetrahedron 1983, 39, 1533.
19. Tippmann, E. M.; Platz, M. S. Org. Lett., submitted for publication.
20. Likhotvorik, I.; Zhu, Z.; Tae, E. L.; Tippmann, E.; Hill, B. H.; Platz, M. S. J. Am. Chem. Soc. 2001, 123, 6061.