Proof of Innocence for the Quintessential Noninnocent Ligand TCNQ in Its Tetranuclear Complex with Four [fac-Re(CO)3(bpy)]+ Groups: Unusually Different Reactivity of the TCNX Ligands (TCNX = TCNE, TCNQ, TCNB)

Inorganic Chemistry

Volumn 42, Issue 22, 2003, Pages 7018-7025

  Hartmann, Heiko ^a   Kaim, Wolfgang ^a   Wanner, Matthias ^a   Klein, Axel ^a   Frantz, Stéphanie ^a   Duboc Toia, Carole ^b   Fiedler, Jan ^c   Záliš, Stanislav ^c  

^a UNIVERSITY OF STUTTGART   (Germany)

^b CNRS   (France)

^c J HEYROVSKÝ INSTITUTE OF PHYSICAL CHEMISTRY   (Czech Republic)

Author keywords

[No Author keywords available]

Indexed keywords

1,2,4,5 TETRACYANOBENZENE; 2,2' BIPYRIDINE DERIVATIVE; 7,7,8,8 TETRACYANO 4 QUINODIMETHANE; BENZENE DERIVATIVE; COBALT DERIVATIVE; COORDINATION COMPOUND; LIGAND; METAL; METHANE; METHYL CHLORIDE; NITRILE; RHENIUM; TETRACYANOETHYLENE; UNCLASSIFIED DRUG;

ARTICLE; CALCULATION; CHEMICAL ANALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; CHROMATOPHORE; COMPLEX FORMATION; CORRELATION COEFFICIENT; ELECTRIC POTENTIAL; ELECTROCHEMISTRY; ELECTRON SPIN RESONANCE; ELECTRON TRANSPORT; ENERGY; INFRARED SPECTROSCOPY; MOLECULAR STABILITY; REACTION ANALYSIS; REDUCTION; STRUCTURE ANALYSIS; ULTRAVIOLET SPECTROSCOPY;

EID: 0242322073     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic034232l     Document Type: Article

References (62)

1. (a) Jørgensen, C. K. Oxidation Numbers and Oxidation States; Springer: Berlin, 1969.
2. (b) Ward, M. D.; McCleverty, J. A. J. Chem. Soc., Dalton Trans. 2002, 275.
3. (c) Herebian, D.; Bothe, E.; Bill, E.; Weyhermüller, T.; Wieghardt, K. J. Am. Chem. Soc. 2001, 123, 10012.
4. Kaim, W.; Moscherosch, M. Coord. Chem. Rev. 1994, 129, 157.
5. (a) Miller, J. S.; Epstein, A. J. Angew. Chem. 1994, 106, 399; Angew. Chem., Int. Ed. Engl. 1994, 33, 385.
6. (a) Miller, J. S.; Epstein, A. J. Angew. Chem. 1994, 106, 399; Angew. Chem., Int. Ed. Engl. 1994, 33, 385.
7. (b) Miller, J. S.; Epstein, A. J. Chem. Eng. News 1995, 73, 30.
8. (c) Miller, J. S.; Epstein. A. J. Chem. Ind. 1996, 49,
9. (d) Miller, J. S. Interface 2002, 11, 22.
10. (a) Yee, G. T.; Manriquez, J. M.; Dixon, D. A.; McLean, R. S.; Groski, D. M.; Flippen. R. B.; Narayan, K. S.; Epstein, A. J.; Miller, J. S. Adv. Mater. 1991, 3, 309.
11. (b) Manriquez, J. M.; Yee, G. T.; McLean, R. S.; Epstein, A. J.; Miller, J. S. Science 1991, 252, 1415.
12. (c) Pokhodnya, K. I.; Epstein, A. J.; Miller, J. S. Adv. Mater. 2000, 12, 410.
13. Fortin, D.; Drouin, M.; Harvey, P. D. Inorg. Chem. 2000, 39, 2758 and references cited.
14. Sacher, W.; Nagel, U.; Beck, W. Chem. Ber. 1987, 120, 895.
15. Bartley, S. L.; Dunbar, K. R. Angew. Chem. 1991, 103, 447; Angew. Chem., Int. Ed. Engl. 1991, 30, 448.
16. Bartley, S. L.; Dunbar, K. R. Angew. Chem. 1991, 103, 447; Angew. Chem., Int. Ed. Engl. 1991, 30, 448.
17. Leirer, M.; Knör, G.; Vogler, A. Inorg. Chem. Commun. 1999, 2, 110.
18. 4-TCNQ: (a) Shields, L. J. Chem. Soc., Faraday Trans. 2 1985, 81, 1.
19. (b) O'Kane, S. A.; Clérac, R.; Zhao, H.; Ouyang, X.; Galán-Mascarós, J. R.; Heintz, R.; Dunbar, K. R. J. Solid State Chem. 2000, 152, 159.
20. (c) Campana, C.; Dunbar, K. R.; Ouyang, X. Chem. Commun. 1996, 2427.
21. (d) Miyasaka, H.; Campos-Fernández, C. S.; Clérac, R.; Dunbar, K. R. Angew. Chem. 2000, 112, 3989; Angew. Chem., Int. Ed. Engl. 2000, 39, 3831.
22. (d) Miyasaka, H.; Campos-Fernández, C. S.; Clérac, R.; Dunbar, K. R. Angew. Chem. 2000, 112, 3989; Angew. Chem., Int. Ed. Engl. 2000, 39, 3831.
23. (e) Heintz, R. A.; Zhao, H.; Ouyang, X.; Grandinetti, G.; Cowen, J.; Dunbar, K. R. Inorg. Chem. 1999, 38, 144.
24. (f) For a μ4-TCNE example see: Cotton, F. A.; Kim, Y. J. Am. Chem. Soc. 1993, 115, 8511.
25. Hartmann, H.; Kaim, W.; Hartenbach, I.; Schleid, T.; Wanner, M.; Fiedler, J. Angew. Chem. 2001, 113, 2927; Angew. Chem., Int. Ed. 2001, 40, 2842.
26. Hartmann, H.; Kaim, W.; Hartenbach, I.; Schleid, T.; Wanner, M.; Fiedler, J. Angew. Chem. 2001, 113, 2927; Angew. Chem., Int. Ed. 2001, 40, 2842.
27. 4-TCNX ligands: (a) Gross, R.; Kaim, W. Angew. Chem. 1987, 99, 257; Angew. Chem., Int. Ed. Engl. 1987, 26, 251.
28. 4-TCNX ligands: (a) Gross, R.; Kaim, W. Angew. Chem. 1987, 99, 257; Angew. Chem., Int. Ed. Engl. 1987, 26, 251.
29. (b) Moscherosch, M.; Waldhör, E.; Binder, H.; Kaim, W.; Fiedler, J. Inorg. Chem. 1995, 34, 4326.
30. (c) Waldhör, E.; Kaim, W.; Lawson, M.; Jordanov, J. Inorg. Chem. 1997, 36, 3248.
31. (d) Baumann, F.; Kaim, W.; Olabe, J. A.; Parisse, A.; Jordanov, J. J. Chem. Soc., Dalton Trans. 1997, 4455.
32. (e) Diaz, C.; Arancibia, A. Polyhedron 2000, 19, 137,
33. (f) Berger, S.; Hartmann, H.; Wanner, M.; Fiedler, J.; Kaim, W. Inorg. Chim. Acta 2001, 314, 22.
34. Kalyanasundaram, K.; Grätzel, M.; Nazeeruddin, Md. K. Inorg. Chem. 1992, 31, 5243.
35. Barra, A.-L.; Brunel, L.-C.; Robert, J.-B. Chem. Phys. Lett. 1990, 165, 107.
36. Krejčik, M.; Daněk, M.; Hartl, F. J. Electroanal. Chem. 1991, 317, 179.
37. Kaim, W.; Ernst, S.; Kasack, V. J. Am, Chem. Soc. 1990, 112, 173.
38. Abel, E. W.; Wilkinson, G. J. Chem. Soc. 1959, 1501.
39. Sheldrick, G. M. Program package SHELXTL; Bruker Analytical X-ray Systems: Madison, WI, 1998.
40. Programm X-SHAPE, Version 1.06; Fa. STOE & Cie GmbH: Darmstadt, Germany, 1999.
41. Fonseca Guerra, C.; Snijders, J. G.; Te Velde, G.; Baerends, E. J. Theor. Chim. Acta 1998, 99, 391.
42. (b) van Gisbergen, S. J. A.; Snijders, J. G.; Baerends, E. J. Comput. Phys. Commun. 1999, 118, 119.
43. Becke, A. D. Phys. Rev A 1988, 38, 3098.
44. Perdew, J. P. Phys. Rev. A 1986, 33, 8822.
45. (a) Fatiadi, A. J. Synthesis 1986, 249.
46. (b) Fatiadi, A. J. Synthesis 1987, 959.
47. (c) Hori, H.; Ishihara, J.; Koike, K.; Takeuchi, K.; Ibusuki, T.; Ishitani, O. Chem. Lett. 1997, 1249.
48. Dunbar, K. R.; Heintz, R. A. Prog. Inorg. Chem. 1997, 45, 283.
49. Calderazzo, F.; Mazzi, U.; Pampaloni, G.; Poli, R.; Tisato, F.; Zanazzi, P. F. Gazz. Chim. Ital. 1989, 119, 241.
50. (b) Stark, G. A.; Arif, A. M.; Gladysz, J. A. Organometallics 1997, 16, 2909.
51. (a) Kistenmacher, T. S.; Philips, J. E.; Cowan, D. O. Acta Crystallogr., Sect. B 1974, 30, 763.
52. (b) Kistenmacher, T. S.; Emge, T. J.; Bloch, A. N.; Cowan, D. O. Acta Crystallogr., Sect. B 1982, 38, 1193.
53. (c) Allen, D. P.; Bottomley, F.; Day, R. W.; Decken, A.; Sanchez, V.; Summers, D. A.; Thompson, R. C. Organometallics 2001, 20, 1840.
54. Chappell, J. S.; Bloch, A. N.; Bryden, W. A.; Maxfield, M.; Poehler, T. O.; Cowan, D. O. J. Am. Chem. Soc. 1981, 103, 2442.
55. Berger, S.; Klein, A.; Kaim, W.; Fiedler, J. Inorg. Chem. 1998, 37, 5664.
56. (a) Melby, L. R.; Harder, R. J.; Hertler, W. R.; Mahler, W.; Besnon, R. E.; Mochel, W. E. J. Am. Chem. Soc. 1962, 84, 3374.
57. (b) Schulz, A.; Kaim, W. Chem. Ber. 1991, 124, 129.
58. Suchanski, M. R.; Van Duyne, R. P. J. Am. Chem. Soc. 1976, 98, 250.
59. Bell, E. S.; Field, J. S.; Haines, R. I.; Moscherosch, M.; Matheis, W.; Kaim, W. Inorg. Chem. 1992, 31, 3269.
60. Frantz, S.; Hartmann, H.; Doslik, N.; Wanner, M.; Kaim, W.; Kümmerer, H.-J.; Denninger, G.; Barra, A.-L.; Duboc-Toia, C.; Fiedler, J.; Ciofini, I.; Urban, C.; Kaupp, M. J. Am. Chem. Soc. 2002, 124, 10563.
61. Summers, D. P.; Luong, J. C.; Wrighton, M. S. J. Am. Chem. Soc. 1981, 103, 5238.
62. Hawecker, J.; Lehn, J.-M.; Ziessel, R. J. Helv. Chim. Acta 1986, 69, 1990.