Evidence of a surprising channeling of ring-opening energy to the H2 product in the H + c-C3H6 → H2 + C3H5 abstraction reaction

Journal of Physical Chemistry A

Volumn 107, Issue 41, 2003, Pages 8380-8382

  Shuman, Nicholas S ^a   Srivastava, Abneesh ^a,b   Picconatto, Carl A ^a,c   Danese, David S ^a   Ray, Paresh C ^a,d   Valentini, James J ^a  

^a Och Spine at New York Presbyterian Hospitals   (United States)

^b LAWRENCE LIVERMORE NATIONAL LABORATORY   (United States)

^c MITRE CORPORATION   (United States)

^d Black Light Power Inc   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; CHEMICAL BONDS; CHEMICAL REACTIONS; DEPOSITION; ELECTRON ENERGY LEVELS; ISOMERIZATION; MOLECULAR VIBRATIONS; PHOTOLYSIS; QUANTUM THEORY;

ABSTRACTION REACTION; CYCLOPROPANE; RING OPENING OF ENERGY;

ORGANIC COMPOUNDS;

EID: 0242306152     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp035431t     Document Type: Letter

References (23)

1. Tsang, W. Heats of Formation of Organic Free Radicals by Kinetic Methods In Energetics of Organic Free Radicals; Martinho Simoes, J. A., Greenberg, A., Liebman, J. F., Eds.; Blackie Academic and Professional: London, 1996; pp 22-58.
2. Greig, G.; Thynne, J. C. J. Trans. Faraday Soc. 1996, 62, 3338.
3. Greig, G.; Thynne, J. C. J. Trans. Faraday Soc. 1967, 63, 1369.
4. Kerr, J. A.; Smith, A.; Trotman-Dickenson, A. F. J. Chem. Soc. A 1969, 1400.
5. Baghal-Vayjooee, M. H.; Benson, S. W. J. Am. Chem. Soc. 1979, 101, 2838-2840.
6. Hudgens, J. W.; Dulcey, C. S. J. Phys. Chem. 1985, 89, 1505, 1509.
7. Parker, J. H. Int. J. Chem. Kinet. 1975, 7, 433.
8. Arnold, P. A.; Cosofret, B. R.; Dylewski, S. M.; Houston, P. L.; Carpenter, B. K. J. Phys. Chem. A 2001, 105, 1693-1701.
9. Oh, C. H.; Shin, S. K.; Kim, H. L.; Park, C. R. Chem. Phys. Lett. 2002, 363, 404-408.
10. Germann, G. J.; Huh, Y.-D.; Valentini, J. J. J. Chem. Phys. 1992, 96, 5746-5757.
11. Picconatto, C. A.; Srivastava, A.; Valentini, J. J. J. Chem. Phys. 2001, 114, 4837-4845.
12. Srivastava, A.; Picconatto, C. A.; Valentini, J. J. J. Chem. Phys. 2001, 115, 2560-2565.
13. Srivastava, A.; Picconatto, C. A.; Valentini, J. J. Chem. Phys. Lett. 2002, 354, 25-30.
14. Choen, N. Int. J. Chem. Kinet. 1991, 23, 683-700.
15. Wiley, W. C.; McLaren, I. H. Rev. Sci. Instrum. 1955, 25, 1150
16. Daly, N. R. Rev. Sci. Instrum. 1960, 31, 264-267.
17. Arnold, P. A.; Carpenter, B. K. Chem. Phys. Lett. 2000, 328, 90-96.
18. Olivella, S.; Sole, A.; Bofill, J. M. J. Am. Chem. Soc. 1990, 112, 2160-2167.
19. Marshall, R. M.; Purnell, H.; Satchell, P. W. J. Chem. Soc., Faraday Trans. 1 1984, 80, 2395-2403.
20. Marshall, R. M.; Purnell, H.; Sheppard, A. J. Chem. Soc., Faraday Trans. 2 1986, 82, 929-935.
21. Huang, J. Quasiclassical Trajectory Studies of Polyatomic Reaction Dynamics. Ph.D. Thesis, Columbia University, New York, NY, 1995.
22. Dixon, D. N. Private communication.
23. Yamauchi, N.; Miyoshi, A.; Kosaka, K.; Koshi, M.; Matsui, H. J. Phys. Chem. A 1999, 103, 2723-2733.