The effects of pH, ionic strength, and iron-fulvic acid interactions on the kinetics of non-photochemical iron transformations. II. The kinetics of thermal reduction

Geochimica et Cosmochimica Acta

Volumn 67, Issue 21, 2003, Pages 4079-4089

  Pullin, Michael J ^a   Cabaniss, Stephen E ^b  

^a UNIVERSITY OF NOTRE DAME   (United States)

^b UNIVERSITY OF NEW MEXICO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

COLLOID; FRESHWATER; FULVIC ACID; IONIC COMPOSITION; IRON; OXIDATION; PH; REACTION KINETICS; TEMPERATURE EFFECT;

EID: 0242306128     PISSN: 00167037     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0016-7037(03)00367-3     Document Type: Article

References (42)

1. Box, J. D. (1984). Observations on the use of iron(II) complexing agents to fractionate the total filterable iron in natural water samples. Water Res, 18 397-402.
2. Brick, C. M., & Moore, J. N. (1996). Diel variation of trace metals in the Upper Clark Fork River, Montana. Environ. Sci. Technol., 30 1953-1960.
3. Cabaniss, S. E. (1990). pH and ionic strength effects on nickel-fulvic acid dissociation kinetics. Environ. Sci. Technol., 24 583-588.
4. Collienne, R. H. (1983). Photoreduction of iron in the epilimnion of acidic lakes. Limnol. Oceanogr., 28 83-100.
5. Cotner, J. B., & Heath, R. T. (1990). Iron redox effects on photosensitive phosphorus release from dissolved humic materials. Limnol. Oceanogr., 35 1175-1181.
6. Emmenegger, L., Schönenberger, R., Sigg, L., & Sulzberger, B. (2001). Light-induced redox cycling of iron in circumneutral lakes. Limnol. Oceanogr., 46 49-61.
7. Francko, D. A., & Heath, R. T. (1982). UV-sensitive complex phosphorus: Association with dissolved humic material and iron in a bog lake. Limnol. Oceanogr., 27 564-569.
8. Goulet, R. R., & Pick, F. R. (2001). Diel changes in iron concentrations in surface-flow constructed wetlands. Water Sci. Technol., 44 421-426.
9. Hering, J. G., & Morel, F. M. (1988). Kinetics of trace metal complexation: Role of alkaline-earth metals. Environ. Sci. Technol., 22 1469-1478.
10. Hering, J. G., & Morel, F. M. (1990). Kinetics of trace metal complexation: Ligand-exchange reactions. Environ. Sci. Technol., 24 242-252.
11. Jackson, T. A., & Hecky, R. E. (1980). Depression of primary productivity by humic matter in lake and reservoir waters of the Boreal Forest zone. Can. J. Fisheries Aquat. Sci., 37 2300-2316.
12. Jones, R. I., Salonen, K., & De Haan, H. (1988). Phosphorus transformations in the epilimnion of humic lakes: Abiotic interactions between dissolved humic materials and phosphate. Freshwater Biol, 19 357-369.
13. Jones, R. I., Shaw, P. J., & De Haan, H. (1993). Effects of dissolved humic substances on the speciation of iron and phosphate at different pH and ionic strength. Environ. Sci. Technol., 27 1052-1059.
14. Langford, C. H., & Gray, H. B. (1965). Ligand Substitution Processes. : W. A. Benjamin Inc.
15. 3+ by a fulvic acid: A study by stopped flow methods. Can. J. Chem., 53 2979-2984.
16. Langford, C. H., Wong, S. M., & Underdown, A. W. (1981). The interaction of a soil fulvic acid with precipitating hydrous ferric oxide at pH = 6. Can. J. Chem., 59 181-186.
17. Langford, C. H., Kay, R., Quance, G. W., & Khan, T. R. (1977). Kinetic analysis applied to iron in a natural water model containing ions, organic complexes, colloids, and particles. Anal. Lett., 10 1249-1260.
18. Maranger R, Pullin M. J (2002) Elemental complexation by dissolved organic matter in lakes: Implications for Fe speciation and the bioavailability of Fe and P. In Dissolved Organic Matter in Aquatic Ecosystems (eds. S. Findlay and R. Sinsabaugh). Academic Press, San Diego, CA
19. McKnight, D., & Bencala, K. E. (1988). Diel variations in iron chemistry in acidic stream in the Colorado Rocky Mountains, U.S.A. Arctic Alpine Res, 20 492-500.
20. McKnight, D. M., Kimball, B. A., & Bencala, K. E. (1988). Iron photoreduction and oxidation in an acidic mountain stream. Science, 240 637-640.
21. McKnight, D. M., Kimball, B. A., & Runkel, R. L. (2001). pH dependence of iron photoreduction in a rocky mountain stream affected by acid mine drainage. Hydrol. Proc., 15 1979-1992.
22. McMahon, J. W. (1969). The annual and diurnal variation in the vertical distribution of acid soluble ferrous and total iron in a small dimictic lake. Limnol. Oceanogr., 14 357-367.
23. Miles, C. J., & Brezonik, P. L. (1981). Oxygen consumption in humic-colored waters by a photochemical ferrous-ferric catalytic cycle. Environ. Sci. Technol., 19 1089-1095.
24. Olsen, D. L., & Shuman, M. S. (1985). Copper dissociation from estuarine humic materials. Geochim. Cosmochim. Acta, 49 1371-1375.
25. Pullin, M. J., & Cabaniss, S. E. (2003). The effects of pH, ionic strength, and iron-fulvic acid interactions on the kinetics of non-photochemical iron transformations. I. Iron(II) oxidation and iron colloid formation. Geochim. Cosmochim. Acta, 67 0000-0.
26. Ridder, G. M., & Margerum, D. W. (1977). Simultaneous kinetic analysis of multicomponent mixtures. Anal. Chem., 49 2090-2098.
27. Scott, D. T., McKnight, D. M., Blunt-Harris, E. L., Kolesar, S. E., & Lovley, D. R. (1998). Quinone moieties act as electron acceptors in the reduction of humic substances by humics-reducing microorganisms. Environ. Sci. Technol., 32 2984-2989.
28. Shaw, P. J., Jones, R. I., & De Haan, H. (2000). The influence of humic substances on the molecular weight distributions of phosphate and iron in epilimnetic lake waters. Freshwater Biol, 45 383-393.
29. Sivan, O., Erel, Y., Mandler, D., & Mishri, A. (1998). The dynamic redox chemistry of iron in the epilimnion of Lake Kinneret (Sea of Galilee). Geochim. Cosmochim. Acta, 62 565-576.
30. Sojo, L. E., & De Haan, H. (1991). Multicomponent kinetic analysis of iron speciation in humic Lake Tjeukemeer: Comparison of fulvic acid from the drainage basin and lake water samples. Environ. Sci. Technol., 25 935-939.
31. Stookey, L. L. (1970). Ferrozine, a new spectrophotometric reagent for iron. Anal. Chem., 42 779-781.
32. Stumm, W., & Morgan, J. J. (1981). Aquatic Chemistry: An Introduction Emphasizing Chemical Equilibria in Natural Waters. New York: John Wiley.
33. Sullivan, A. B., & Drever, J. I. (2001). Spatiotemporal variability in stream chemistry in a high-elevation catchment affected by mine drainage. J. Hydrol., 252 237-250.
34. Sullivan, A. B., Drever, J. I., & McKnight, D. M. (1998). Diel variations in element concentrations, Peru Creek, Summit County, Colorado. J. Geochem. Explor., 64 141-145.
35. Sulzberger, B., Schnorr, J. L., Giovanoli, R., Hering, J. G., & Zobrist, J. (1990). Biogeochemistry of iron in an acidic lake. Aquat. Sci., 52 56-74.
36. Thompsen, J. C., & Mottola, H. A. (1984). Kinetics of the complexation of iron(II) with ferrozine. Anal. Chem., 56 755-757.
37. Tipping, E., Woof, C., & Ohnstad, M. (1982). Forms of iron in the oxygenated waters of Esthwaite Water, U.K. Hydrobiologia, 92 383-393.
38. Twiss, M. R., Auclair, J. -C, & Charlton, M. N. (2000). An investigation into iron-stimulated phytoplankton productivity in epipelagic Lake Erie during thermal stratification using trace metal clean techniques. Can. J. Fisheries Aquat. Sci., 57 86-95.
39. Voelker, B. M., & Sulzberger, B. (1996). Effects of fulvic acid on Fe(II) oxidation by hydrogen peroxide. Environ. Sci. Technol., 30 1106-1114.
40. Voelker, B. M., Morel, F. M.M, & Sulzberger, B. (1997). Iron redox cycling in surface waters: Effects of humic substances and light. Environ. Sci. Technol., 31 1004-1011.
41. Waite, T. D., & Morel, F. M. M (1984). Ligand exchange and fluorescence quenching studies of the fulvic acid-iron interaction. Anal. Chim. Acta, 162 263-274.
42. Weider, R. K. (1994). Diel changes in iron(III)/iron(II) in effluent from constructed acid mine drainage treatment wetlands. J. Environ. Qual., 23 730-738.