Electrophilic Cyclization of 1,6-Dienes Containing an Allylsilane Moiety - Enantioselective Synthesis of cis- and trans-γ-Irone

European Journal of Organic Chemistry

Volumn , Issue 20, 2003, Pages 3958-3968

  Beszant, Stephen ^a   Giannini, Elios ^a   Zanoni, Giuseppe ^a   Vidari, Giovanni ^a  

^a UNIVERSITY OF PAVIA   (Italy)

Author keywords

Cyclization; Fragrances; Synthetic methods; Terpenoids; Total synthesis

Indexed keywords

CYCLOHEXANE DERIVATIVE; GAMMA IRONE DERIVATIVE; KETONE DERIVATIVE; LEWIS ACID; MERCURY DERIVATIVE; METHYLENECYCLOHEXANE DERIVATIVE; SILANE DERIVATIVE; TRIFLUOROACETATE MERCURY; UNCLASSIFIED DRUG;

ARTICLE; CIS TRANS ISOMERISM; CYCLIZATION; DIASTEREOISOMER; REACTION ANALYSIS; STEREOCHEMISTRY; SYNTHESIS;

EID: 0242291960     PISSN: 1434193X     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejoc.200300276     Document Type: Article

References (61)

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60. 2), ee = 97%.[3]
61. 2), ee > 99%[2e].