Unusual electrochemical properties of the inclusion complexes of ferrocenium and cobaltocenium with cucurbit[7]uril

Organometallics

Volumn 22, Issue 21, 2003, Pages 4181-4183

  Ong, Winston ^a   Kaifer, Angel E ^a  

^a Department of Biology   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

COBALTOCENIUM; CUCURBIT URIL; FERROCENIUM;

COBALT COMPOUNDS; COMPLEXATION; ELECTROCHEMISTRY; ELECTROLYTIC REDUCTION; INCLUSIONS; IRON COMPOUNDS; PHASE EQUILIBRIA;

ORGANOMETALLICS;

EID: 0142258792     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om030305x     Document Type: Article

References (18)

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11. The limiting currents in the NPV measurements of both Fc+ and Cob+ significantly decreased in the presence of CB7. This observation is consistent decrease of their diffusion coefficient upon encapsulation.
12. 5 for a neural CB7 complex has also been reported. Marquez, C.; Nau, W. N. Angew. Chem., Int. Ed. 2001, 40, 4387.
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17. The electrostatic surface potential contour was generated using SYBYL molecular mechanics calculations (Titan software package, Wavefunction, Inc.). At the time of the writing of this paper, Kim also reported a similar contour map. For details, see: Lee, J. W.; Samal. S; Salvapalam, N.; Kim, H.-J.; Kim, K. Acc. Chem. Res. 2003, 36, 621.
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