Influence of ligand steric bulk in the synthesis of transition-metal borylene complexes

Organometallics

Volumn 22, Issue 21, 2003, Pages 4213-4217

  Coombs, Deborah L ^a   Aldridge, Simon ^a   Coles, Simon J ^b   Hursthouse, Michael B ^b  

^a CARDIFF UNIVERSITY   (United Kingdom)

^b UNIVERSITY OF SOUTHAMPTON   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

COMPLEXATION; HYDROGEN BONDS; ORGANOMETALLICS; REACTION KINETICS; SUBSTITUTION REACTIONS; SYNTHESIS (CHEMICAL); TRANSITION METALS;

LIGAND STERIC BULK; MESITYL SUBSTITUENTS; NUCLEOPHILE; PHENYL SUBSTITUENTS; PHENYLBORYLENE LIGAND; TRANSITION METAL BORYLENE COMPLEXES;

BORON COMPOUNDS;

EID: 0142227768     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om030489f     Document Type: Article

References (52)

1. Nugent, W. A.; Mayer, J. M. Metal Ligand Multiple Bonds; Wiley-Interscience: New York, 1988.
2. Mork, B. V.; Tilley, T. D. J. Am. Chem. Soc. 2001, 123, 9702 and references therein.
3. (a) Irvine, G. J.; Lesley, M. J. G.; Marder, T. B.; Norman, N. C.; Rice, C. R.; Robins, E. G.; Roper, W. R.; Whittell, G.; Wright, L. J. Chem. Rev. 1998, 98, 2685.
4. (b) Smith, M. R., III. Prog. Inorg. Chem. 1999, 48, 505.
5. (c) Braunschweig, H.; Colling, M. Coord. Chem. Rev. 2001, 223, 1.
6. (a) Cowley, A. H.; Lomeli, V.; Voight, A. J. Am. Chem. Soc. 1998, 120, 6401.
7. (b) Braunschweig, H.; Kollann, C.; Englert, U. Angew. Chem., Int. Ed. 1998, 37, 3179.
8. (c) Braunschweig, H.; Colling, M.; Kollann, C.; Stammler, H. G.; Neumann, B. Angew. Chem., Int. Ed. 2001, 40, 2299.
9. (d) Braunschweig, H.; Colling, M.; Kollann, C.; Merz, K.; Radacki, K. Angew. Chem., Int. Ed. 2001, 40, 4198.
10. (e) Braunschweig, H.; Colling, M.; Hu, C.; Radacki, K. Angew. Chem., Int. Ed. 2003, 42, 205.
11. (f) Braunschweig, H.; Colling, M. Eur. J. Inorg. Chem. 2003, 383.
12. (g) Irvine, G. J.; Rickard, C. E. F.; Roper, W. R.; Williamson, A.; Wright, L. J. Angew. Chem., Int. Ed. 2000, 39, 948.
13. (h) Rickard, C. E. F.; Roper, W. R.; Williamson, A.; Wright, L. J. Organometallics 2002, 21, 4862.
14. (a) Ehlers, W.; Baerends, E. J.; Bickelhaupt, F. M.; Radius, U. Chem. Eur. J. 1998, 4, 210.
15. (b) Radius, U.; Bickelhaupt, F. M.; Ehlers, A. W.; Goldberg, N.; Hoffmann, R. Inorg. Chem. 1998, 37, 1080.
16. (c) Bickelhaupt, F. M.; Radius, U.; Ehlers, A. W.; Hoffmann, R.; Baerends, E. J. New J. Chem. 1998, 1.
17. (d) Macdonald, C. L. B.; Cowley, A. H. J. Am. Chem. Soc. 1999, 121, 12113.
18. (e) Uddin, J.; Boehme, C.; Frenking, G. Organometallics 2000, 19, 571.
19. (f) Frenking, G.; Fröhlich, N. Chem. Rev. 2000, 100, 717.
20. (g) Uddin, J.; Frenking, G, J. Am. Chem. Soc. 2001, 123, 1683.
21. (h) Chen, Y.; Frenking, G. J. Chem. Soc., Dalton Trans. 2001, 434.
22. (a) Dohmeier, C.; Loos, D.; Schnöckel, H. Angew. Chem., Int., Ed. Engl. 1996, 35, 127.
23. (b) Weiss, J.; Stetzkamp, D.; Nuber, B.; Fischer, R. A.; Boehme, C.; Frenking, G. Angew. Chem., Int., Ed. Engl. 1997, 36, 70.
24. (a) Su, J.; Li, X.-W.; Crittendon, R. C.; Campana, C. F.; Robinson, G. H. Organometallics 1997, 16, 4511.
25. (b) Cotton, F. A.; Feng, X. Organometallics 1998, 17, 128.
26. (c) Jutzi, P.; Neumann, B.; Reumann, G.; Stammler, H.-G. Organometallics 1998, 17, 1305.
27. (a) Haubrich, S. T.; Power, P. P. J. Am. Chem. Soc. 1998, 120, 2202.
28. (b) Jutzi, P.; Neumann, B.; Reumann, G.; Schebaum, L. O.; Stammler, H.-G. Organometallics 1999, 18, 2550.
29. (a) He, X.; Bartlett, R. A.; Power, P. P. Organometallics 1994, 13, 548.
30. (b) Yamaguchi, T.; Ueno, K.; Ogino, H. Organometallics 2001, 20, 501.
31. Cowley, A. H.; Decken, A.; Olazabal, C. A.; Norman, N. C. Z. Anorg. Allg. Chem. 1995, 621, 1844.
32. (a) Braunschweig, H.; Wagner, T. Angew. Chem., Int. Ed. Engl. 1995, 34, 825.
33. (b) Braunschweig, H.; Ganter, B. J. Organomet. Chem. 1997, 545, 163.
34. (c) Braunschweig, H.; Müller, M. Chem. Ber. 1997, 130, 1295.
35. (d) Braunschweig, H.; Kollann, C.; Englert, U. Eur. J. Inorg. Chem. 1998, 465.
36. (e) Shimoi, M.; Ikubo, S.; Kawano, Y. J. Am. Chem. Soc. 1998, 120, 4222.
37. (f) Braunschweig, H.; Colling, M. J. Organomet. Chem. 2000, 614, 18.
38. (g) Braunschweig, H.; Colling, M.; Hu, C.; Radacki, K. Angew. Chem., Int. Ed. Engl. 2002, 41, 1359.
39. 3) borylenes are known: Okamura, R.; Tada, K.; Matsubara, K.; Oshima, M.; Suzuki, H. Organometallics 2001, 20, 4772.
40. Golden, J. T.; Peterson, T. H.; Holland, P. L.; Bergman, R. G.; Andersen, R. A. J. Am. Chem. Soc. 1998, 120, 223.
41. Aldridge, S.; Coombs, D. L.; Jones, C. Chem. Commun. 2002, 856.
42. Coombs, D. L.; Aldridge, S.; Jones, C. J. Chem. Soc., Dalton Trans. 2002, 3851.
43. Coombs, D. L.; Aldridge, S.; Jones, C. Appl. Organomet. Chem. 2003, 17, 356.
44. Coombs, D. L.; Aldridge, S.; Jones, C.; Willock, D. J. J. Am. Chem. Soc. 2003, 125, 6356.
45. (a) King, R. B.; Bisnette, M. B. J. Organomet. Chem. 1967, 8, 287.
46. (b) King, R. B. Acc. Chem. Res. 1970, 3, 417.
47. Otwinowski, Z.; Minor, W. Methods in Enzymology; Carter, C. W., Sweet, R. M., Eds.; Academic Press: New York, 1996, Vol. 276, p 307.
48. COLLECT: Data Collection Software; Nonius B.V., 1999.
49. Sheldrick, G. M. SHELX97: Programs for Crystal Structure Analysis (Release 97-2); University of Göttingen, Göttingen, Germany, 1998.
50. Hartwig, J. F.; Huber, S. J. Am. Chem. Soc. 1993, 115, 4908.
51. Greenwood, N. N.; Earnshaw, A. Chemistry of the Elements; Pergamon Press: Oxford, U.K., 1990.
52. Aldridge, S.; Coombs, D. L. Unpublished results.