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This reagent has been used to electrophilically aminate ferrocenyl-lithium to give aminoferrocene in 13% yield, (a) A. N. Nesmeyanov, E. G. Perevalova, R. V. Golovnya and L. S. Shilovtseva, Dokl. Akad. Nauk. SSSR, 1955, 102, 353; (b) G. R. Knox, P. L. Pauson and D. Willison, Organometallics, 1990, 9, 301 and references therein.
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Noticeable decomposition did occur after 2 days in air at room temperature.
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45
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