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i) For a recent review on anion recognition, see: P. D. Beer, P. A. Gale, Angew. Chem. 2001, 113, 502; Angew. Chem. Int. Ed. 2001, 40, 486.
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i) For a recent review on anion recognition, see: P. D. Beer, P. A. Gale, Angew. Chem. 2001, 113, 502; Angew. Chem. Int. Ed. 2001, 40, 486.
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For another sensor approach that used the affinity of fluoride to silicon see: S. Yamaguchi, S. Akiyama, K. Tamao, J. Am. Chem. Soc. 2000, 122, 6793.
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0034143327
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The alternative approach to develop PPE based on the 3,6-diethynyl-2-hydroxy-benzaldehyde was not pursued, as o-phenoxyacetylenes could undergo tandem cyclization to the corresponding benzofuran by use of TBAF or CsF, for example, see: A. Sakai, T. Aoyama, T. Shioiri, Heterocycles 2000, 52, 643.
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32
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0142245920
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See Supporting Information for details
-
See Supporting Information for details.
-
-
-
-
33
-
-
0142245932
-
-
note
-
2 at -40°C (79%). See also Supporting Information.
-
-
-
-
34
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0142214963
-
-
note
-
Triisopropylsilyl group (TIPS) was used instead of tert-butyldimethylsilyl (TBS) as the thermal polymerization conditions required a more stable protecting group for phenol.
-
-
-
-
35
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0000400199
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1,4-Diiodobenzene with ortho-dialkoxy side-chains 13 was chosen as a comonomer to produce a sensory polymer with higher frequencies (blue-shifted). Z. Zhu, T. M. Swager, Org. Lett. 2001, 3, 3471.
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