Direct Determination of the Number of Electrons Needed to Reduce Coenzyme F430 Pentamethyl Ester to the Ni(I) Species Exhibiting the Electron Paramagnetic Resonance and Ultraviolet-Visible Spectra Characteristic for the MCRredl State of Methyl-coenzyme M Reductase

Journal of the American Chemical Society

Volumn 125, Issue 43, 2003, Pages 13120-13125

  Piskorski, Rafal ^a   Jaun, Bernhard ^a  

^a ETH ZURICH   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVE STATES;

CATALYSTS; ELECTRON SPIN RESONANCE SPECTROSCOPY; ESTERS; OXIDATION; RAMAN SCATTERING; STOICHIOMETRY; TITRATION; ULTRAVIOLET RADIATION;

ENZYMES;

COBALT DERIVATIVE; COENZYME A; COENZYME F430 PENTAMETHYL ESTER; DECAMETHYLCOBALTOCENE; MACROCYCLIC COMPOUND; METHYL COENZYME M REDUCTASE; METHYLENE BLUE; NICKEL; OXIDIZING AGENT; OXIDOREDUCTASE; TETRAHYDROFURAN; UNCLASSIFIED DRUG;

ANALYTIC METHOD; ARTICLE; CATALYSIS; CHEMICAL BINDING; CHROMATOPHORE; ELECTROCHEMICAL ANALYSIS; ELECTROLYSIS; ELECTRON SPIN RESONANCE; ELECTRON TRANSPORT; ENZYME ACTIVE SITE; ENZYME ANALYSIS; OXIDATION; PROCESS MODEL; RAMAN SPECTROMETRY; REDUCTION; REOXIDATION; SPECIES IDENTIFICATION; STOICHIOMETRY; TITRIMETRY; ULTRAVIOLET SPECTROSCOPY;

ELECTROCHEMISTRY; ELECTRON SPIN RESONANCE SPECTROSCOPY; METALLOPORPHYRINS; METHYLENE BLUE; NICKEL; OXIDATION-REDUCTION; OXIDOREDUCTASES; SPECTROPHOTOMETRY, ULTRAVIOLET; TITRIMETRY;

EID: 0142214613     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja037862v     Document Type: Article

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