Synthesis and Structural Elucidation of a "Free" Phosphinoamide Anion

European Journal of Inorganic Chemistry

Volumn , Issue 19, 2003, Pages 3527-3529

  Fei, Zhaofu ^a   Scopelliti, Rosario ^a   Dyson, Paul J ^a  

^a Institut de chimie moleculaire et biologique Ecole Polytechnique Federale de Lausanne   (Switzerland)

Author keywords

Crown ether; N,P ligands; Potassium; X ray structure

Indexed keywords

CHELATION; CRYSTAL STRUCTURE; LIGANDS; NEGATIVE IONS; POSITIVE IONS; POTASSIUM; SINGLE CRYSTALS; X RAY DIFFRACTION ANALYSIS;

18-CROWN-6; CO-CRYSTALS; CROWN-ETHERS; N,P LIGAND; P LIGANDS; PHOSPHINOAMIDES; SINGLE CRYSTAL X-RAY DIFFRACTION ANALYSIS; STRUCTURAL ELUCIDATION; TWO-PRODUCT; X-RAY STRUCTURE;

CROWN ETHERS;

18 CROWN 6 DERIVATIVE; AMIDE; CROWN ETHER DERIVATIVE; NITRILE; OXYGEN; PHOSPHINOAMIDE ANION; PHOSPHORAMIDIC ACID DERIVATIVE; POTASSIUM; UNCLASSIFIED DRUG; WATER;

ARTICLE; CHEMICAL BOND; CRYSTAL STRUCTURE; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; SOLID STATE; STRUCTURE ANALYSIS; SYNTHESIS; X RAY DIFFRACTION;

EID: 0142183561     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejic.200300257     Document Type: Article

References (23)

1. See, for example: [1a] E R. Hartley, The Chemistry of Organophosphorus Compounds, Vol. 1, John Wiley & Sons, Chichester, 1990.
2. [1b] O. J. Scherer, Multiple Bonds and Low Coordination in Phosphorus Chemistry, Georg Thieme Verlag, Stuttgart, 1990.
3. [2a] O. Scherer, W. M. Janssen, J. Organomet. Chem. 1969, 20, 111.
4. [2b] A. Schmidtpeter, G. Burget, Angew. Chem. Int. Ed. Engl. 1985, 24, 580.
5. [2c] A. H. Cowley, R. A. Kemp, J. Chem. Soc., Chem. Commun. 1982, 319.
6. [2d] A. H. Cowley, R. A. Kemp, Inorg. Chem. 1983, 22, 547.
7. M. T. Ashby, Z. Li, Inorg. Chem. 1992, 31, 1321.
8. [4a] N. Poetschke, M. Nieger, M. A. Khan, E. Niecke, M. T. Ashby, Inorg. Chem. 1997, 36, 4087.
9. [4b] I. Schranz, L. Stahl, R. J. Staples, Inorg. Chem. 1998, 37, 1493.
10. [4c] B. Eichhorn, H. Nöth, T. Seifert, Eur. J. Inorg. Chem. 1999, 12, 2355.
11. [5a] D. Fenske, B. Maczek, K. Maczek, Z. Anorg. Allg. Chem. 1997, 623, 1113.
12. [5b] T. G. Wetzel, S. Dehnen, P. W. Roesky, Angew. Chem. Int. Ed. 1999, 38, 1086.
13. [6a] A. H. Cowley, M. W. Taylor, M.-H. Whangbo, S. Wolfe, J. Chem. Soc., Chem. Commun. 1976, 838.
14. [6b] G. Tringuier, M. T Ashby, Inorg. Chem. 1994, 33, 1306.
15. [6c] T. Kremer, F. Hampel, F. A. Knoch, W. Bauer, A. Schmidt, P. Gabold, M. Schütz, J. Ellermann, P. v. R. Schleyer, Organometallics 1996, 15, 4776.
16. Z. Fei, R. Scopelliti, P. J. Dyson, Inorg. Chem. 2003, 42, 2125.
17. P. P. Power, Acc. Chem. Res. 1988, 21, 147.
18. J. Ellermann, W. Bauer, M. Schütz, F. W. Heinemann, M. Moll, Monatsh. Chem. 1998, 129, 547.
19. 1H NMR spectrum.
20. W. Wiegräbe, H. Boch, Chem. Ber. 1968, 101, 1414.
21. K. Issleib, B. Walter, E. Fluck, Z. Chem. 1968, 8, 67.
22. S. Wingerter, M. Pfeiffer, F. Baier, T. Stey, D. Stalke, Z. Anorg. Allg. Chem. 2000, 626, 1121.
23. W. Henderson, J. S. Mclndoe, B. K. Nicholson, P. J. Dyson, J. Chem. Soc., Dalton Trans. 1998, 519.