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Volumn 125, Issue 42, 2003, Pages 12676-12677

Regioselective Bond Cleavage in the Dissociative Electron Transfer to Benzyl Thiocyanates

Author keywords

[No Author keywords available]

Indexed keywords

ACETONITRILE; BENZYL THIOCYANATE; TETRABUTYLAMMONIUM;

EID: 0142104255     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja036710x     Document Type: Article
Times cited : (25)

References (28)
  • 3
    • 0001887557 scopus 로고
    • Dissociative Electron Transfer
    • Mariano, P. S., Ed.; JAI Press: New York
    • (c) Savéant, J.-M. Dissociative Electron Transfer. In Advances in Electron Transfer Chemistry; Mariano, P. S., Ed.; JAI Press: New York, 1994; Vol. 4, pp 53-116.
    • (1994) Advances in Electron Transfer Chemistry , vol.4 , pp. 53-116
    • Savéant, J.-M.1
  • 4
    • 35449001112 scopus 로고    scopus 로고
    • Electron Transfer, Bond Breaking and Bond Formation
    • Tidwell, T. T., Ed.; Academic Press: New York, and references therein
    • Savéant, J.-M. Electron Transfer, Bond Breaking and Bond Formation. In Advances in Physical Organic Chemistry; Tidwell, T. T., Ed.; Academic Press: New York, 2000; Vol. 35, pp 117-192 and references therein.
    • (2000) Advances in Physical Organic Chemistry , vol.35 , pp. 117-192
    • Savéant, J.-M.1
  • 9
    • 0142019322 scopus 로고    scopus 로고
    • note
    • (a) Formation of both disulfides and sulfides from reactions of thiolates with thiocyanates have been already reported.5b-g
  • 18
    • 0142019321 scopus 로고    scopus 로고
    • note
    • 0 = -0.45 V vs SCE) using data for related radicals.7b
  • 22
    • 0142083139 scopus 로고    scopus 로고
    • note
    • 0 = 0.65 V/SCE (from CV data).
  • 28
    • 0142114601 scopus 로고    scopus 로고
    • note
    • The α bond is weaker than the β bond in aryl5b and allyl8b thiocyanates. The α bond in the benzyl thiocyanates is even weaker.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.