Formation of a Spiral-Shaped Inorganic-Organic Hybrid Chain, [Cu II(2,2′-bipy)(H2O)2Al(OH) 6Mo6O18]nn-: Influence of Intra- and Interchain Supramolecular Interactions

Inorganic Chemistry

Volumn 42, Issue 21, 2003, Pages 6604-6606

  Shivaiah, Vaddypally ^a   Nagaraju, M ^a   Das, Samar K ^a  

^a UNIVERSITY OF HYDERABAD   (India)

Author keywords

[No Author keywords available]

Indexed keywords

COORDINATION COMPOUND; HYDROGEN; INORGANIC COMPOUND; LIGAND; METAL COMPLEX; ORGANIC COMPOUND; OXYGEN; POLYANION; POLYMER; TRANSITION ELEMENT;

ARTICLE; CHEMICAL STRUCTURE; COMPLEX FORMATION; CRYSTAL STRUCTURE; HYDROGEN BOND; MOLECULAR INTERACTION; REACTION ANALYSIS; STRUCTURE ANALYSIS; SUPRAMOLECULAR CHEMISTRY; SYNTHESIS;

EID: 0142103857     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic034581f     Document Type: Article

References (20)

1. (a) Pope, M. T. Heteropoly and Isopoly Oxometalates; Springer-Verlag: Berlin, 1983.
2. (b) Pope, M. T.; Müller, A. Angew. Chem., Int. Ed. Engl. 1991, 30, 34.
3. (a) Yaghi, O. M.; Li, H.; Davis, C.; Richardson, D.; Groy, T. L. Acc. Chem. Res. 1998, 31, 474.
4. (b) Hagraman, P. J.; Hagraman, D.; Zubieta, J. Angew. Chem., Int. Ed. Engl. 1999, 38, 2638.
5. (c) Stupp, S. I.; Braun, P. V. Science 1997, 277, 1242.
6. Debord, J. R. D.; Haushalter, R. C.; Mayer, L. M.; Rose, D. J.; Zapf, P. J.; Zubieta, J. Inorg. Chim. Acta 1997, 256, 165.
7. Hagraman, D.; Zubieta, C.; Rose, D. J.; Zubieta, J.; Haushalter, R. C. Angew. Chem., Int. Ed. Engl. 1997, 36, 873.
8. Xu, Y.; Xu, J.-Q.; Zhang, K.-L.; Zhong, Y.; You, X.-Z. Chem. Commun. 2000, 153.
9. Lu, J.; Xu, Y.; Goh, N. K.; Chia, L. S. Chem. Commun. 1998, 2733.
10. Wu, C.-D.; Lu C.-Z.; Zhuang, H.-H.; Huang, J.-S. Inorg. Chem. 2002, 41, 5636.
11. Shivaiah, V.; Reddy, P. V. N.; Cronin, L.; Das, S. K. J. Chem. Soc., Dalton Trans. 2002, 3781.
12. Manikumari, S.; Shivaiah, V.; Das, S. K. Inorg. Chem. 2002, 41, 6953.
13. Perloff, A. Inorg. Chem. 1970, 9, 2228.
14. 2O (0.5 g, 2.06 mmol) were added, and the pH of the resulting mixture was adjusted to 2.6 with the concentrated HCl and filtrate kept at room temperature. Blue blocks appeared within a week and were washed with water and dried at room temperature. Yield: 0.48 g (12% based on Mo).
15. B.
16. -3.
17. (a) Kondo, H.; Kobayashi, A.; Sasaki, Y. Acta Crystallogr. 1980, B36, 661.
18. (b) Ito, F.; Ozeki, T.; Ichida, H.; Miyamae, H.; Sasaki, Y. Acta Crystallogr. 1989, C45, 946.
19. (c) Lee, H. Y.; Park, K. M.; Lee, U.; Ichida, H. Acta Crystallogr. 1991, C47, 1959.
20. (d) Rosu, C.; Dickman, M. H. Acta Crystallogr. 1999, C55, 11.