Ligand exchange and substitution at platinum(II) complexes: Evidence for a dissociative mechanism

Inorganica Chimica Acta

Volumn 350, Issue , 2003, Pages 143-151

  Romeo, Raffaello ^a   Scolaro, Luigi Monsù ^a,b   Plutino, Maria Rosaria ^a   De Biani, Fabrizia Fabrizi ^c   Bottari, Giovanni ^a   Romeo, Andrea ^a,b  

^a Sezione di Messina   (Italy)

^b INFM   (Italy)

^c UNIVERSITY OF SIENA   (Italy)

Author keywords

Dissociative mechanism; Kinetics; Phosphane effects; Platinum(II) complexes

Indexed keywords

CHLORINE COMPOUNDS; DIMETHYL SULFOXIDE; DISSOCIATION; ENZYME KINETICS; LIGANDS; ORGANIC SOLVENTS; PYRIDINE; REACTION RATES;

COMPENSATION EFFECTS; DEUTERATED CHLOROFORMS; DISSOCIATIVE MECHANISMS; LIGAND CONCENTRATION; PHOSPHANES; PLATINUM COMPLEXES; RATE DETERMINING STEP; SQUARE PLANAR COMPLEX;

PLATINUM COMPOUNDS;

ALKANE DERIVATIVE; CHLOROFORM; COORDINATION COMPOUND; DIMETHYL SULFOXIDE; DIMETHYL(DIMETHYLSULFOXIDE)(TRIPHENYLPHOSPHANE)PLATINUM; DIMETHYL(DIMETHYLSULFOXIDE)[TRIS(4 CHLOROPHENYL)PHOSPHANE]PLATINUM; DIMETHYL(DIMETHYLSULFOXIDE)[TRIS(4 FLUOROPHENYL)PHOSPHANE]PLATINUM; DIMETHYL(DIMETHYLSULFOXIDE)[TRIS(4 METHOXYPHENYL)PHOSPHANE]PLATINUM; DIMETHYL(DIMETHYLSULFOXIDE)[TRIS(4 METHYLPHENYL)PHOSPHANE]PLATINUM; DIMETHYL(DIMETHYLSULFOXIDE)[TRIS(4 TRIFLUOROMETHYLPHENYL)PHOSPHANE]PLATINUM; DIMETHYLPYRIDINE(TRIPHENYLPHOSPHANE)PLATINUM; DIMETHYLPYRIDINE[TRIS(4 CHLOROPHENYL)PHOSPHANE]PLATINUM; DIMETHYLPYRIDINE[TRIS(4 FLUOROPHENYL)PHOSPHANE]PLATINUM; DIMETHYLPYRIDINE[TRIS(4 METHOXYPHENYL)PHOSPHANE]PLATINUM; DIMETHYLPYRIDINE[TRIS(4 METHYLPHENYL)PHOSPHANE]PLATINUM; DIMETHYLPYRIDINE[TRIS(4 TRIFLUOROMETHYLPHENYL)PHOSPHANE]PLATINUM; PLATINUM COMPLEX; PYRIDINE DERIVATIVE; SOLVENT; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION KINETICS; CIS ISOMER; DISSOCIATION; ENTROPY; HIGH TEMPERATURE; ISOTOPE LABELING; LOW TEMPERATURE; PROTON NUCLEAR MAGNETIC RESONANCE; SPECTROPHOTOMETRY; SUBSTITUTION REACTION; THERMODYNAMICS;

EID: 0142088973     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0020-1693(02)01505-0     Document Type: Article

References (45)

1. Collman J.P., Hegedus L.S., Norton J.R., Finke R.C. Principle and Applications of Organotransition Metal Chemistry. 1987;University Science Books, Mill Valley, CA.
2. Crabtree R.H. The Organometallic Chemistry of the Transition Metals. 1994;Wiley-Interscience, New York.
3. Parshall G.W. Homogeneous Catalysis. 1980;Wiley-Interscience, New York.
4. Yamamoto A. Organotransition Metal Chemistry. 1986;Wiley, New York.
5. Romeo R. Comm. Inorg. Chem. 11:1990;21.
6. Alibrandi G., Cusumano M., Minniti D., Monsù Scolaro L., Romeo R. Inorg. Chem. 28:1989;342. and references therein.
7. For general reviews of β-elimination reactions, see R.J. Cross, in: F.R. Hartley, S. Patai, (Eds.), The Chemistry of the Metal-Carbon Bond, vol. 2, Wiley, New York, 1985, Chapter 8, and Refs. [8,9].
8. Whitesides G.M. Pure Appl. Chem. 53:1981;287.
9. Yamamoto A., Yamamoto T., Komiya S., Ozawa F. Pure Appl. Chem. 56:1984;1621.
10. Romeo R., Alibrandi G., Monsù Scolaro L. Inorg. Chem. 32:1993;4688.
11. Coussens B.B., Buda F., Oevering H., Meier R.J. Organometallics. 17:1998;795. and references therein.
12. Paonessa R.S., Trogler W.C. J. Am. Chem. Soc. 104:1982;3529.
13. Alibrandi G., Romeo R. Inorg. Chem. 36:1997;4822. and references therein.
14. Casado A.L., Casares J.A., Espinet P. Inorg. Chem. 37:1998;4154.
15. Romeo R., Plutino M.R., Elding L.I. Inorg. Chem. 36:1997;5909. and references therein.
16. Holtcamp M.W., Labinger J.A., Bercaw J.E. Inorg. Chim. Acta. 265:1997;117.
17. Stahl S.S., Labinger J.A., Bercaw J.E. J. Am. Chem. Soc. 118:1996;5961.
18. Rendina L.M., Puddephatt R.J. Chem. Rev. 97:1997;1735.
19. Scott J.D., Puddephatt R.J. Organometallics. 2:1983;1643. and references therein.
20. Casares J.A., Coco S., Espinet P., Lin Y.S. Organometallics. 14:1995;3058.
21. A. Gelling, K.G. Orrell, A.G. Osborne, V. Sik, J. Chem. Soc., Dalton Trans. (1998) 937.
22. Romeo R., Fenech L., Monsù Scolaro L., Albinati A., Macchioni A., Zuccaccia C. Inorg. Chem. 40:2001;3293.
23. Romeo R., Fenech L., Carnabuci S., Plutino M.R., Romeo A. Inorg. Chem. 41:2002;2839.
24. Basolo F. Coord. Chem. Rev. 154:1996;151.
25. Plutino M.R., Monsù Scolaro L., Romeo R., Grassi A. Inorg. Chem. 39:2000;2712. and references therein.
26. Romeo R., Grassi A., Monsù Scolaro L. Inorg. Chem. 31:1992;4383.
27. Wendt O.F., Deeth R.J., Elding L.I. Inorg. Chem. 39:2000;5271.
28. Minniti D., Alibrandi G., Tobe M.L., Romeo R. Inorg. Chem. 26:1987;3596.
29. C. Eaborn, K. Kundu, A.J. Pidcock, J. Chem. Soc., Dalton Trans. (1981) 933.
30. Van Geet A.L. Anal. Chem. 40:1968;2227.
31. Van Geet A.L. Anal. Chem. 42:1970;679.
32. SCIENTIST, Micro Math Scientific Software, Salt Lake City, UT.
33. A.L. Fernandez, A. Prock, W.P. Giering, The QALE Web Site, http://www.bu.edu/qale/ .
34. Bartik T., Himmler T., Schulte H.G., Seevogel K. J. Organomet. Chem. 272:1984;29.
35. Wilson M.R., Woska D.C., Prock A., Giering W.P. Organometallics. 12:1993;1742.
36. Tolman C.A. Chem. Rev. 77:1977;313.
37. Romeo R., Arena G., Monsù Scolaro L. Inorg. Chem. 31:1992;4879.
38. Romeo R., Plutino M.R., Monsù Scolaro L., Stoccoro S. Inorg. Chim. Acta. 265:1997;225.
39. F.H. Allen, A. Pidcock J. Chem. Soc. (A) (1968) 2700.
40. Appleton T.G., Clark H.C., Manzer L.E. Coord. Chem. Rev. 10:1973;335.
41. Romeo R. Comm. Inorg. Chem. 23:2002;79.
42. Haar C.M., Nolan P.S., Marshall W.J., Moloy K.G., Prock A., Giering W.P. Organometallics. 18:1999;474.
43. Alibrandi G., Bruno G., Lanza S., Minniti D., Romeo R., Tobe M.L. Inorg. Chem. 26:1987;185.
44. Linert W., Jameson R.F. Chem. Soc. Rev. 477:1989;18.
45. Linert W. Inorg. Chim. Acta. 233:1988;141.