Immiscibility in the Fe3O4-FeCr2O 4 spinel binary

Journal of Physics and Chemistry of Solids

Volumn 64, Issue 11, 2003, Pages 2081-2091

  Ziemniak, Stephen E ^a   Castelli, Roy A ^a  

^a Knolls Atomic Power Laboratory   (United States)

Author keywords

A. Magnetic materials; A. Oxides; D. Phase equilibria; D. Thermodynamic properties

Indexed keywords

FREE ENERGY; LATTICE CONSTANTS; PHASE EQUILIBRIA; POSITIVE IONS;

SPINEL BINARY;

IRON OXIDES;

EID: 0142075391     PISSN: 00223697     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-3697(03)00237-3     Document Type: Article

References (33)

1. O'Neill H.S.C., Navrotsky A. Cation distributions and thermodynamic properties of binary spinel solid solutions. Am. Miner. 68:1983;181-194 O'Neill H.S.C., Navrotsky A. Cation distributions and thermodynamic properties of binary spinel solid solutions. Am. Miner. 69:1984;733-753.
2. O'Neill H.S.C., Navrotsky A. Cation distributions and thermodynamic properties of binary spinel solid solutions. Am. Miner. 68:1983;181-194 O'Neill H.S.C., Navrotsky A. Cation distributions and thermodynamic properties of binary spinel solid solutions. Am. Miner. 69:1984;733-753.
3. 4 between 500 and 1000 °C. N. Jb. Miner. Abh. 111:1969;184-205.
4. 4 spinel binary, Submitted for publication.
5. Ziemniak S.E., Hanson M. Corrosion behavior of 304 stainless steel in high temperature, hydrogenated water. Corros. Sci. 44:2002;2209-2230.
6. Temkin M. Mixtures of fused salts as ionic solutions. Acta Physicochim. URSS. 20:1945;411-420.
7. Taylor J.R., Dinsdale A.T. A thermodynamic assessment of the Cr-Fe-O system. Z. Metallkd. 84:1993;335-345.
8. de Fontaine D., Fries S.G., Inden G., Miodownik P., Schmid-Fetzer R., Chen S.-L. Thermodynamic models and data for pure elements and other end members of solutions; Group 4: λ-transitions. CALPHAD. 19:1995;499-536.
9. Hillert M., Burton B., Saxena S.K., Degterov S., Hari Kumar K.C., Ohtani H., Aldinger F., Kussmaul A. Thermodynamic modelling of solutions and alloys; Group 4: modelling of oxides. CALPHAD. 21:1997;247-263.
10. Ansara I., Burton B., Chen Q., Hillert M., Fernandez-Guillermet A., Fries S.G., Lukas H.L., Seifert H.J., Oates W.A. Applications of computational thermodynamics; Group 2: models for composition dependence. CALPHAD. 24:2000;19-40.
11. Néel L. Magnetic properties of ferrites: ferrimagnetism and antiferromagnetism. Ann. Phys. (Paris). 3:1948;137-198.
12. 4. Phys. Rev. 167:1968;533-535.
13. 4). J. Phys. Chem. Solids. 32:1971;717-729.
14. Inden G. Determination of chemical and magnetic interchange energies in BCC alloys. Z. Metallkd. 66:1975;577-582.
15. Hillert M., Jarl M. A model for alloying effects of ferromagnetic metals. CALPHAD. 2:1978;227-238.
16. 4) from 300 to 1050 K. Ferrimagnetic transition and zero-point entropy. J. Chem. Thermodyn. 6:1974;859-872.
17. Sundman B. An assessment of the Fe-O system. J. Phase Equilib. 12:1991;127-140.
18. 3 at low temperatures and derived thermodynamic properties. Am. Miner. 85:2000;1686-1693.
19. 4. J. Appl. Phys. 35:1964;954-955.
20. JCPDS Powder Diffraction File, International Centre for Diffraction Data, Swarthmore, PA, (1989) Sets 1-39.
21. 4 spinel system. J. Chem. Phys. 22:1954;1196-1198.
22. Hill R.J., Craig J.R., Gibbs G.V. Systematics of the spinel structure type. Phys. Chem. Miner. 4:1979;317-339.
23. Shannon R.D. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallogr. A32:1976;751-767.
24. Verwey E.J.W., Haayman P.H., Romeijn F.C. Physical properties and cation arrangement of oxides with spinel structures. II. Electronic conductivity. J. Chem. Phys. 15:1947;181-187.
25. Daniels J.M., Rosencwaig A. Mössbauer spectroscopy of stoichiometric and non-stoichiometric magnetite. J. Phys. Chem. Solids. 30:1969;1561-1571.
26. Harrison R.J., Putnis A. The coupling between magnetic and cation ordering: a macroscopic approach. Eur. J. Miner. 9:1997;1115-1130.
27. Wu C.C., Mason T.O. Thermopower measurement of cation distribution in magnetite. J. Am. Ceram. Soc. 64:1981;520-522.
28. 4 spinels from thermopower and conductivity measurements. Am. Miner. 74:1989;339-351.
29. Navrotsky A., Kleppa O.J. The thermodynamics of cation distributions in simple spinels. J. Inorg. Nucl. Chem. 29:1967;2701-2714.
30. Dunitz J.D., Orgel L.E. Electronic properties of transition metal oxides. II. Cation distributions amongst octahedral and tetrahedral sites. J. Phys. Chem. Solids. 3:1957;318-323.
31. 4 spinels. Am. Miner. 76:1991;405-426.
32. 3 between 1000 and 1200 °C. N. Jb. Miner. Mh. 5:1976;214-228.
33. 4 spinel solid solutions. J. Am. Ceram. Soc. 65:1982;117-123.