The trifluoromethyltrioxy radical, CF3OOO

Angewandte Chemie - International Edition

Volumn 42, Issue 38, 2003, Pages 4690-4693

  Von Ahsen, Stefan ^a   Willner, Helge ^a   Francisco, Joseph S ^b  

^a UNIVERSITY OF DUISBURG ESSEN   (Germany)

^b PURDUE UNIVERSITY   (United States)

Author keywords

Atmospheric chemistry; Density functional calculations; Reaction mechanisms; Trioxy radicals; Vibrational spectroscopy

Indexed keywords

LOW TEMPERATURE EFFECTS; REACTION KINETICS; THERMOANALYSIS;

THERMOLYSIS;

FREE RADICALS;

OXYGEN RADICAL; RADICAL; TRIFLUOROMETHYLTRIOXY RADICAL; UNCLASSIFIED DRUG;

ARTICLE; ATMOSPHERE; CALCULATION; CHEMISTRY; DENSITY FUNCTIONAL CALCULATION; REACTION ANALYSIS; SPECTROSCOPY; VIBRATION; VIBRATIONAL SPECTROSCOPY;

EID: 0142056064     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200351909     Document Type: Article

References (29)

1. J. S. Francisco, M. M. Maricq, Adv. Photochem. 1995, 20, 79.
2. R. Atkinson, J. Phys. Chem. Ref Data 1997, 26, 215.
3. R. Atkinson, Atmos. Environ. 2000, 34, 2063.
4. M. D. King, C. E. Canosa-Mas, R. P. Wayne, Atmos. Environ. 2001, 35, 2081.
5. P. D. Lightfoot, R. A. Cox, J. N. Crowley, M. Destriau, G. D. Hayman, M. E. Jenkin, G. K. Moortgat, F. Zabel, Atmos. Environ. Part A 1992, 28, 1805.
6. F. Cacace, G. de Petris, F. Pepi, A. Trojani, Science 1999, 285, 81.
7. B. Nelander, A. Engdahl, T. Svensson, Chem. Phys. Lett. 2000, 332, 403.
8. E. Y. Misochko, A. V. Akimov, C. A. Wight, J. Phys. Chem. A 1999, 103, 7972.
9. T. W. P. Jungkamp, J. H. Seinfeld, Chem. Phys. Lett. 1996, 263, 371.
10. X. Xu, R. P. Müller, W. A. Goddard III, Proc. Natl. Acad. Sci. USA 2002, 99, 3376.
11. A. E. Croce, C. J. Cobos, E. Castellano, J. Fluorine Chem. 1997, 82, 91.
12. J. S. Francisco, I. H. Willams, Int. J. Chem. Kinet. 1988, 20, 455.
13. M. K. W. Ko, N. D. Sze, J. M. Rodriguez, D. K. Weistenstein, C. W. Heisey, R. P. Wayne, P. Biggs, C. E. Canosa-Mas, H. Sidebottom, Geophys. Res. Lett. 1994, 21, 101.
14. P. Biggs, C. E. Canosa-Mas, D. E. Shallcross, A. Vipond, R. P. Wayne, J. Chem. Soc. Faraday Trans. 1997, 93, 2477.
15. R. W. Fessenden, J. Chem. Phys. 1968, 48, 3725.
16. M. C. R. Symons, J. Am. Chem. Soc. 1969, 91, 5924.
17. G. A. Argüello, H. Willner, F. E. Malanca, Inorg. Chem. 2000, 39, 1195.
18. G. A. Argüello, H. Willner, J. Phys. Chem. A 2001, 105, 3466.
19. A. D. Becke, Phys. Rev. A 1988, 38, 3098.
20. J. A. Pople, M. Head-Gordon, J. Chem. Phys. 1987, 87, 5968.
21. Gaussian98 (Revision A.7), M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria, M. A. Robb, J. R. Cheeseman, V. G. Zakrzewski, J. A. Montgomery, R. E. Stratmann, J. C. Burant, S. Dapprich, J. M. Millam, A. D. Daniels, K. N. Kudin, M. C. Strain, O. Farkas, J. Tomasi, V. Barone, M. Cossi, R. Cammi, B. Mennucci, C. Pomelli, C. Adamo, S. Clifford, J. Ochterski, G. A. Petersson, P. Y. Ayala, Q. Cui, K. Morokuma, D. K. Malick, A. D. Rabuck, K. Raghavachari, J. B. Foresman, J. Cioslowski, J. V. Ortiz, B. B. Stefanov, G. Liu, A. Liashenko, P. Piskorz, I. Komaromi, R. Gomperts, R. L. Martin, D. J. Fox, T. Keith, M. A. Al-Laham, C. Y. Peng, A. Nanayakkara, C. Gonzalez, M. Challacombe, P. M. W. Gill, B. G. Johnson, W. Chen, M. W. Wong, J. L. Andres, M. Head-Gordon, E. S. Replogle, J. A. Pople, Gaussian, Inc., Pittsburgh, PA, 1998.
22. 3OO′O″ are -0.79 (O), + 0.85 (O′), and +0.98 (O″).
23. R. G. W. Norrish, J. Chem. Soc. 1934, 1864.
24. S. S. Prasad, Nature 1980, 285, 152.
25. D. T. Shindell, J. Atmos. Chem. 1997, 20, 323.
26. R. Kopitzky, H. Grothe, H. Willner, Chem. Eur. J. 2002, 8, 5601.
27. S. S. Prasad, T. J. Lee, J. Geophys. Res. [Atmos.] 1994, 99, 8225.
28. H. Schnöckel, H. Willner in Infrared and Raman Spectroscopy, Methods and Applications (Ed.: B Schrader), VCH, Weinheim, 1994, p. 297.
29. S. von Ahsen, J. Hufen, H. Willner, J. S. Francisco, Chem. Eur. J. 2001, 8, 1189.