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The latest reports by Kim and Russell (Ref. 9) on the immiscibility loop with both LDOT and UODT observed in the polystyrene-b-poly(n-pentyl methacrylate) melts raise a question about the origin of LDOT phenomena (compressibility difference or directional interaction) in this and other homologous block Copolymers. A manuscript dealing with this topic is in preparation now.
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Olvera de la Cruz reported the failure in minimizing a Landau free energy and its Hartree correction in the incompressible situation for deep quenches if chain stretching is allowed, or in other words, the minimization procedure with respect to the scattering vector (q*) is allowed. See (a) M. Olvera de la Cruz, Macromolecules 24, 3975 (1991); (b) Phys. Rev. Lett. 95, 1281 (1991).
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Olvera de la Cruz reported the failure in minimizing a Landau free energy and its Hartree correction in the incompressible situation for deep quenches if chain stretching is allowed, or in other words, the minimization procedure with respect to the scattering vector (q*) is allowed. See (a) M. Olvera de la Cruz, Macromolecules 24, 3975 (1991); (b) Phys. Rev. Lett. 95, 1281 (1991).
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φ of Eq. (A5) in the bulk thermodynamic spinodal condition.
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0142111907
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cRPA in Eq. (20) is also harmonious with the effective χ suggested by Yeung et al. (Ref. 8).
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0142111906
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12 by ∼ 0.03%.
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53
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0142048529
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note
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The blend of PEE and PDMS having the degrees of polymerization of 30.5 and 29.2, respectively, revealed the cloud point of 417 K (Ref. 28).
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