A novel IPN hydrogel based on poly (N-isopropylacrylamide) and β-cyclodextrin polymer

Journal of Macromolecular Science - Pure and Applied Chemistry

Volumn 40 A, Issue 10, 2003, Pages 1095-1105

  Liu, Yu Yang ^a   Fan, Xiao Dong ^a   Zhao, Qiang ^a,b  

^a NORTHWESTERN POLYTECHNICAL UNIVERSITY   (China)

^b TIANJIN UNIVERSITY   (China)

Author keywords

cyclodextrin polymer; Hydrogel; Interpenetrating polymeric network; Poly(N isopropylacrylamide)

Indexed keywords

CROSSLINKING; DIFFERENTIAL SCANNING CALORIMETRY; HYDROGELS; INFRARED SPECTROSCOPY; MONOMERS; PHASE TRANSITIONS; POLYAMIDES; POLYMERIZATION; SOLUTIONS; SWELLING; THERMAL EFFECTS; THERMOGRAVIMETRIC ANALYSIS;

CYCLODEXTRIN POLYMER; ELEMENT ANALYSIS; EPICHLOROHYDRIN; EQUILIBRIUM SWELLING RATIO; POLYISOPROPYLACRYLAMIDE;

INTERPENETRATING POLYMER NETWORKS;

EID: 0142054853     PISSN: 10601325     EISSN: None     Source Type: Journal    
DOI: 10.1081/MA-120024466     Document Type: Article

References (25)

1. Kwon, I.C.; Bae, Y.H.; Kim, S.W. Electrically erodible polymer gel for controlled release of drugs. Nature 1991, 354 (28), 291-293.
2. Akoi, T.; Kawashiko, M.; Katono, H.; Sanui, K.; Ogata, N.; Okano, T.; Sakurai, Y. Temperature-responsive interpenetrating polymer networks constructed with poly (acrylic acid) and poly(N,N-dimethyacrylamide). Macromolecules 1994, 27 (4), 947-952.
3. Zhang, J.; Peppas, N.A. Synthesis and characterization of pH- and temperature-sensitive poly(methacrylic acid)/poly(n-isopropylacylamide) interpenetrating polymeric networks. Macromolecules 2000, 33 (1), 102-107.
4. Kokufuta, E.; Wang, B.; Yoshida, R.; Khokhlov, A.R.; Hirata, M. Volume phase transition of polyelectrolyte gels with different charge distributions. Macromolecules 1998, 31 (20), 6878-6884.
5. Ju, H.K.; Kim, S.Y.; Lee, Y.M. pH/temperature-responsive behaviors of semi-IPN and comb-type graft hydrogels composed of alginate and poly(N-isopropylacrylamide). Polymer 2001, 42, 6851-6857.
6. Shibayama, M.; Mizutani, S.Y.; Nomura, S.J. Thermal properties of copolymer gels containing N-isopropylacrylamide. Macromolecules 1996, 29, 2019-2024.
7. Lee, W.F.; Shieh, C.H. pH-thermoreversible hydrogel. II. Synthesis and swelling behaviors of N-isopropylacrylamide-co-acrilic acid-co-sodium acrylate hydrogels. J. Appl. Polym. Sci. 1999, 73, 1955-1967.
8. Liu, Y.Y.; Fan, X.D. Synthesis and characterization of pH- and temperature-sensitive hydrogel of N-isopropylacrylamide/cyclodextrin based copolymer. Polymer 2002, 43 (18), 4997-5003.
9. Liu, Y.Y.; Fan, X.D. Preparation and characterization of a novel responsive hydrogel using a β-Cyclodextrin based macromonomer. J. Appl. Polym. Sci. 2003, 89 (2), 361-367.
10. Nozaki, T.; Maceda, Y.; Ito, K.; Kitano, H. Cyclodextrin modified with polymer chains which are responsive to external stimuli. Macromolecules 1995, 28 (2), 522-524.
11. Nozaki, T.; Maeda, Y.; Kitano, H. Cyclodextrin gels which have a temperature responsiveness. J. Polym. Sci. A: Polym. Chem. 1997, 35, 1535-1541.
12. Sreenivasan, K. On the restriction of the release of water-soluble component from polyvinyl alcohol film by blending β-cycliodextrin. J. Appl. Polym. Sci. 1997, 65, 1829-1832.
13. Baille, W.E.; Huang, W.Q.; Nichifor, M.; Zhu, X.X. Functionalized β-cyclodextrin polymers for the sorption of bile salts. J. Macromol. Sci.-Pure & Appl. Chem. 2000, A (7), 677-690.
14. He, B.L.; Zhao, X.B. Studies on synthesis of novel polymers carrying β-cyclodextrin. Science in China (Ser. B) 1992, 12, 1240-1247.
15. Dubois, M.; Gilles, K.A.; Hamilton, J.K.; Pebers, P.A.; Smith, F. Colorimetric method for determination of sugars and related substances. Anal. Chem. 1956, 28 (3), 350-356.
16. Franson, N.M.; Peppas, N.A. Influence of copolymer composition on non-Fickian water transport through glassy copolymers. J. Appl. Polym. Sci. 1983, 28, 1299-1310.
17. Korsmeyer, R.W. Solute and penetrant diffusion in swellable polymer. II. Verification of theoretical models. J. Polym. Sci.: Polym. Phys. Ed. 1986, 24, 409-434.
18. Bajpai, A.K.: Shrivastava, M. Dynamic swelling behavior of polyacrylamide based three component hydrogels. J. Macromol. Sci.-Pure & Appl. Chem. 2000, A37 (9), 1069-1088.
19. Renard, E.; Deratani, A.; Volet, G.; Sebilie, B. Preparation and characterization of water soluble high molecular weight β-Cyclodextrin-epichlorohydrin polymer. Euro. Polym. J. 1997, 33 (1), 49-57.
20. Liu, Y.Y.; Fan, X.D.; Cao, Z. State of water in β-cycliodextrin/epichlorohydrin hydrogel and swelling behavior of the crosslinked polymer. J. Functional Polymer 2001, 14 (2), 169-173.
21. Katime, I.; Apodaca, E.D. Acrylic acid/methyl methacrylate hydrogels. II. Effect of composition on mechanical and thermodynamic properties. J. Macromol. Sci.-Pure & Appl. Chem. 2000, A37 (4), 307-321.
22. Gündogan, N.; Okay, O. Reentrant phase transition of poly(N-isopropylacrylamide) gel in polymer solutions: thermodynamic analysis. J. Appl. Polym. Sci. 2002, 85, 801-813.
23. Fan, X.D.; Uludag, H. Synthesis and characterization of thermo-reversible and protein-conjugation functional copolymers of poly(N-isopropylacrylamide-co-N-acryloxysucci-nimide). Polymer Preprints 1999, 41 (1), 361-362.
24. Chen, G.H.; Hoffman, A.S. Graft copolymers that exhibit temperature-induced phase transitions over a wide range of pH. Nature 1995, 373 (5), 49-52.
25. Yoshida, R.; Uchida, K.; Kaneko, Y.; Sakai, K.; Kikuchi, A.; Sakural, Y.; Okano, T. Comb-type grafted hydrogels with rapid de-swelling response to temperature changes. Nature 1995, 374 (16), 240-242.