Catalytic cleavage of the Si-Si bond of methylchlorodisilanes with nucleophiles: Evidences for a stabilised silylene reaction intermediate

Inorganica Chimica Acta

Volumn 350, Issue , 2003, Pages 407-413

  Garcia Escomel, Cristina ^b   Mekarbane, Pierre ^a   Martin, Christine ^a   Grenouillet, Pierre ^a   De Bellefon, Claude ^a  

^a LGPC CNRS   (France)

^b Rhodia Europe   (France)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYST ACTIVITY; CHEMICAL BONDS; CHLORINE COMPOUNDS; CONDENSATION; NUCLEOPHILES; PHOSPHORUS COMPOUNDS; POLYSILANES; REACTION INTERMEDIATES;

DISILANES; DISPROPORTIONATIONS; KINETIC STUDY; PHOSPHINE OXIDE; RATE LIMITING; SI-SI BONDS; TEST REACTIONS; TWO-STEP MECHANISMS;

SILICON;

DIMETICONE; METHYLCHLORODISILANE DERIVATIVE; PHOSPHINE DERIVATIVE; PHOSPHITE; SILANE DERIVATIVE; SILICON; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL BOND; CORRELATION ANALYSIS; DOWN REGULATION; KINETICS; ORDINATION ANALYSIS; POLYMERIZATION; REACTION ANALYSIS;

EID: 0142025237     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0020-1693(02)01576-1     Document Type: Article

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