General model of assignment of the relative stereochemistry in the Nicholas reaction products resulting from chiral dicobalthexacarbonyl-1-alkoxy-propargylium cations

Magnetic Resonance in Chemistry

Volumn 40, Issue 4, 2002, Pages 261-272

  Montaña, Angel M ^a   Cano, Montserrat ^a  

^a UNIVERSITY OF BARCELONA   (Spain)

Author keywords

13C NMR; 1H NMR; Nicholas reaction; NMR; Propargyl dicobalthexacarbonyl complexes; Relative stereochemistry; Stereochemical assignment

Indexed keywords

ISOMERS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; REACTION PRODUCTS; STEREOSELECTIVITY; X RAY DIFFRACTION ANALYSIS;

13C NMR; 1H NMR; GENERAL MODEL; NICHOLAS REACTIONS; PROPARGYL; PROPARGYL DICOBALTHEXACARBONYL COMPLEX; RELATIVE STEREOCHEMISTRY; SILYL ENOL ETHERS; STEREOCENTERS; STEREOCHEMICAL ASSIGNMENT;

POSITIVE IONS;

CATION; COBALT DERIVATIVE;

ARTICLE; BINDING AFFINITY; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL REACTION; CHIRALITY; CONFORMATIONAL TRANSITION; CORRELATION ANALYSIS; CYCLIZATION; DIASTEREOISOMER; ENANTIOSELECTIVITY; MOLECULAR INTERACTION; MOLECULAR MODEL; NICHOLAS REACTION; PROTON NUCLEAR MAGNETIC RESONANCE; STEREOCHEMISTRY; X RAY DIFFRACTION;

EID: 0142024157     PISSN: 07491581     EISSN: None     Source Type: Journal    
DOI: 10.1002/mrc.1012     Document Type: Article

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