Spectroscopic study (TRLFS and EXAFS) of the kinetics of An(III)/Ln(III) humate interaction

Radiochimica Acta

Volumn 91, Issue 10, 2003, Pages 567-574

  Monsallier, Jean Marc ^a   Artinger, Robert ^a   Denecke, Melissa A ^a   Scherbaum, Franz J ^a   Buckau, Gunnar ^a   Kim, Jae Il ^a  

^a KARLSRUHE INSTITUTE OF TECHNOLOGY   (Germany)

Author keywords

Actinides; Humic acid; Kinetics; Laser spectroscopy EXAFS

Indexed keywords

ACTINIDE; CURIUM; EUROPIUM; GROUND WATER; HUMIC ACID; LANTHANIDE; METAL ION; TERBIUM;

ARTICLE; CATION EXCHANGE; CHEMICAL REACTION KINETICS; DISSOCIATION; FLOCCULATION; FLUORESCENCE SPECTROSCOPY; MOLECULAR INTERACTION; REACTION ANALYSIS; SPECTROSCOPY;

EID: 0141996556     PISSN: 00338230     EISSN: None     Source Type: Journal    
DOI: 10.1524/ract.91.10.567.22471     Document Type: Article

References (42)

1. Langford, C. H., Cook, R. L.: Kinetic versus equilibrium studies for the speciation of metal complexes with ligands from soil and water. Analyst 120, 591 (1995).
2. Buckau, G. (Ed.): Effects of Humic Substances on the Migration of Radionuclides: Complexation and Transport of Actinides (Final Report). Report EUR 19610 EN (2000).
3. Kim, S. D., Bu, M. B., Allen, H. E., Cha, D. K.: Physicochemical factors affecting the sensitivity of Ceriodaphnia dubia to copper. Environ. Monitoring Assessment 70(1/2), 105 (2001).
4. 2+-ions in humic acid. Z. Pflanzenern. Bodenk. 4, 475 (1976).
5. Clark, S. B., Choppin, G. R.: Kinetics of rare earth metal binding to aquatic humic acids. ACS Symp. Ser. 416 (Chem. Model. Aqueous Syst. 2) (1990) pp. 519-525.
6. Choppin, G. R., Clark, S. B.: The kinetic interactions of metalions with humic acids. Marine Chem. 36, 27 (1991).
7. Huizenga, D. L., Patterson, H. H.: A chemiluminescence technique for determination of rates of reaction of chromium(III) with carboxylate ligands and humic acid. Anal. Chim. Acta 206, 263 (1988).
8. Huizenga, D. L., Patterson, H. H.: A chemiluminescence study of the kinetics of reactions of Cr(III) with carboxylate ligands: oxalate, salicylate and humic acid. Ca. J. Chem. 68, 881 (1990).
9. 3+ by a fulvic acid: a study by stopped flow methods. Can. J. Chem. 53(20), 2979 (1975).
10. Bunzl, K., Schimmack, W.: Kinetics of Ion Sorption on Humic Substances. In: SSSA Special Publication 27 Rate Soil Chemical Processes, (1991) pp. 119-134.
11. Rao, L., Choppin, G. R., Clark, S. B.: A study of metal-humate interactions using cation exchange. Radiochim. Acta 66/67, 141 (1994).
12. Jin, X., Bailey, G. W., Yu, Y. S., Lynch, A. T.: Kinetics of single and multiple metal ion sorption processes on humic substances. Soil Sci. 161(8), 509 (1996).
13. King, S. J., Warwick, P., Hall, A., Bryan, N.: The dissociation kinetics of dissolved metal-humate complexes. Phys. Chem. Chem. Phys. 3, 2080 (2001).
14. Artinger, R., Schuessler, W., Schaefer, T., Kim, J.I. A kinetic study of Am(III)/humic colloid interactions. Environ. Sci. Techol. 36, 4358 (2002).
15. Cacheris, W. P., Choppin, G. R.: Dissociation kinetics of thorium-humate complex. Radiochim. Acta 42, 185 (1987).
16. Bonifazi, M., Pant, B. C., Langford, C. H.: Kinetic study of the speciation of copper(II) bound to humic acid. Environ. Technol. 17, 885 (1996).
17. Lavigne, J. A., Langford, C. H., Mak, M. K.: Kinetic study of speciation of nickel(II) bound to a fulvic acid. Anal. Chem. 59, 2616 (1987).
18. Langford, C. H., Gutzman, D. W.: Kinetic studies of metal ion speciation. Anal. Chim. Acta 256, 183 (1992).
19. Choppin, G. R., Nash, K. L.: Dissociation kinetics of thorium and humic acid. J. Inorg. Nucl. Chem. 43, 357 (1981).
20. Choppin, G. R., Cacheris, W. P.: Kinetics of thorium humate. J. Less Common Metals 122, 551 (1986).
21. 3+ and size exclusion chromatography - a feasibility study. Radiochim. Acta 78, 111 (1997).
22. Geckeis, H., Rabung, Th., Ngo Manh, T., Kim, J. I., Beck, H. P.: Humic colloid-borne natural polyvalent metal ions: dissociation experiment. Environ. Sci. Technol. 36, 2946 (2002).
23. Bondietti, E. A., Reynolds, S. A., Shanks, M. H.: Interaction of Plutonium with Complexing Substances in Soils and Natural Waters. In: Proceedings of IAEA Symposium Transuranium Nuclides in the Environment, IAEA (1976) pp. 273-287.
24. Rate, A. W., McLaren, R. G., Swift, R. S.: Dissociation Kinetics of Copper(II)-Humic Acid Complexes. In: Trace Elements: Roles, Risks and Remedies, Proceedings of the New Zealand Trace Elements Group Conference (1992) pp. 57 -62.
25. Rate, A. W., McLaren, R. G., Swift, R. S.: Evaluation of log-normal distribution first-order kinetic model for copper(II)-humic acid complex dissociation. Environ. Sci. Technol. 26, 2477 (1992).
26. Marshall, S. J., Young, S. D., Gregson, K.: Humic acid proton equilibria: a comparison of two models and assessment of titration error. Europ. J. Soil Sci. 46, 471 (1995).
27. Buckau, G.: Komplexierung von Americium(III) mit Huminstoffen in natürlichen Grundwässern. Thesis, Free University of Berlin (1991).
28. Bidoglio, G., Omenetto, N., Robouch, P.: Kinetic studies of lanthanide interactions with humic substances by time resolved laser induced fluorescence. Radiochim. Acta 52/53, 57 (1991).
29. Figura, P., McDuffle, B.: Use of Chelex resin for determination of labile trace metal fractions in aqueous ligand media and comparison of the method with anodic stripping voltametry. Anal. Chem. 51(1), 120 (1979).
30. Clark, S. B., Choppin, G. R.: A comparison of the dissociation kinetics of rare earth element complexes with synthetic polyelectrolytes and humic acid. In: ACS Symposium Series 651 (Humic and Fulvic Acids) (1996) pp. 207-219.
31. Kim, J. I., Buckau, G., Li, G. H., Duschner, H., Psarros, N.: Characterization of humic and fulvic acids from Gorleben groundwater. Fresenius J. Anal. Chem. 338, 245 (1990).
32. Kim, J. I., Buckau, G., Bryant, E., Klenze, R.: Complexation of americium(III) with humic acid. Radiochim. Acta 48, 135 (1989).
33. 241 Am migration in a sandy aquifer: Batch and column experiments with Gorleben groundwater/sediment systems. J. Contam. Hydrol. 35, 261 (1998).
34. Geckeis, H., Rabung, T., Kim, J. I.: Kinetic Aspects of the Metal Ion Binding to Humic Substances. In: Effects of humic substances on the migration of radionuclides: complexation and transport of actinides. (Buckau, G. ed.) Second Technical progress report, Karlsruhe (1999) pp.47-58.
35. Ressler, T. WinXAS: A new software package not only for the analysis of energy-dispersive XAS data, J. Phys. IV 7, C 2 (1997).
36. Zabinsky, S. I., Rehr, J. J., Ankudinov, A., Albers, R. C., Eller, M. J.: Multiple-scattering calculations of X-ray-absorption spectra. Phys. Rev. B 52, 2995 (1995).
37. Kim, J. I., Klenze, R., Wimmer, H.: Fluorescence spectroscopy of curium(III) and application. Eur. J. Solid State Inorg. Chem. 28, 347 (1991).
38. 3+) with humic acid: a comparison of different experimental methods. Radiochim. Acta 62, 35 (1993).
39. Stumpf, Th., Fanghänel, Th.: A time-resolved laser fluorescence spectroscopy (TRLFS) study of the interaction of trivalent actinides (Cm(III) with calcite. J. Colloid Interf. Sci. 249, 119 (2002).
40. Kimura, T., Choppin, G. R.: Luminescence study on determination of the hydration number of Cm(III). J. Alloys Compd. 213/214, 313 (1994).
41. Stumpf, Th., Fanghänel, Th., Grenthe, I.: Complexation of trivalent actinide and lanthanide ions by glycolic acid: a TRLFS study. J. Chem. Soc., Dalton Trans. 3799 (2002).
42. Panak, P., Klenze, R., Kim. J. I.: A study of ternary complexes of Cm(III) with humic acid and hydroxide or carbonate in neutral pH range by time-resolved laser fluorescence spectroscopy. Radiochim. Acta 74, 141 (1996).