Approaches to bi- and trimetallic platinum and palladium complexes using the DPPEPM ligand

Inorganic Chemistry Communications

Volumn 6, Issue 10, 2003, Pages 1307-1310

  Nair, Padma ^a   Anderson, Gordon K ^a   Rath, Nigam P ^a  

^a UNIVERSITY OF MISSOURI ST LOUIS   (United States)

Author keywords

Crystal structure(s); Platinum and palladium complexes; Tetraphosphine ligands

Indexed keywords

BIMETALLIC PLATINUM DERIVATIVE; BIS[(DIPHENYLPHOSPHINOETHYL)PHENYLPHOSPHINO]METHANE; LIGAND; PALLADIUM CHLORIDE; PALLADIUM COMPLEX; PHOSPHINE DERIVATIVE; PHOSPHORUS; PLATINUM CHLORIDE; PLATINUM DERIVATIVE; TRIMETALLIC PLATINUM DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; CRYSTAL STRUCTURE; OXIDATION;

EID: 0141995026     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2003.08.004     Document Type: Article

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10. PtP = 1733 Hz).
11. PP = 16 Hz).
12. PP = 374, 26 Hz).
13. 1 = 0.0301.
14. +, 1869.3509.
15. 1 = 0.0323. Due to the small sizes of the methyl and chloride ligands attached to platinum, the ligands show positional disorder. The disorder was resolved using partial occupancies of 50% for the ligands on both metals.