Catalytic transfer hydrogenation of conjugated nitroalkenes using decaborane: Synthesis of oximes

Organic and Biomolecular Chemistry

Volumn 1, Issue 7, 2003, Pages 1099-1100

  Lee, Seung Hwan ^a   Park, Yong June ^a   Yoon, Cheol Min ^a  

^a Korea University   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

ADDITIVES; ALDEHYDES; CATALYSIS; COLUMN CHROMATOGRAPHY; HYDROGENATION; KETONES; METHANOL; NITROGEN; POLYMERIZATION; REDUCTION; SYNTHESIS (CHEMICAL);

CATALYTIC TRANSFER HYDROGENATION; DECABORANE; NITROALKENES; OXIMES;

OLEFINS;

EID: 0141940642     PISSN: 14770520     EISSN: None     Source Type: Journal    
DOI: 10.1039/b212746f     Document Type: Article

References (18)

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9. 6 gave an expected oxime and an unidentified side product in overall 83.8% yield; the ratio of oxime and side product is 2 : 1 according to NMR.
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12. (c) J. W. Bae, Y. J. Cho, S. H. Lee, C.-O. Maing Yoon and C. M. Yoon, Chem. Commun., 2000, 1857
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14. 4: B. C. Ranu and R. Chakraborty, Tetrahedron, 1992, 48, 5317 and references cited therein.
15. The reaction conditions are so mild that (4-chlorophenyl)acetaldehyde oxime (entry 4) was not decomposed and reduced even after stirring for 2 days under the reaction conditions.
16. (a) O. Schales and H. A. Graefe, J. Am. Chem. Soc., 1952, 74, 4486
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18. (c) C. B. Gairaud and G. R. Lappin, J. Org. Chem., 1953, 18, 1. Commercially available samples (entries 2, 6, 14) were used as received. Other nitroalkenes were prepared via published procedures.