Effects of exchanged cation on the microporosity of montmorillonite

Clays and Clay Minerals

Volumn 45, Issue 4, 1997, Pages 534-543

  Rutherford, David W ^a   Chiou, Cary T ^a   Eberl, Dennis D ^a  

^a U S GEOLOGICAL SURVEY   (United States)

Author keywords

Exchanged Cation; Interlayer Accessibility; Microporosity; Montmorillonite; Surface Area

Indexed keywords

ALKALI METAL COMPOUNDS; AMMONIUM COMPOUNDS; CALCULATIONS; GAS ADSORPTION; ION EXCHANGE; POROSITY;

MICROPOROSITY; PORE VOLUME; SURFACE AREA;

CLAY MINERALS;

EXCHANGED CATION; MICROPOROSITY; MONTMORILLONITE;

EID: 0141918107     PISSN: 00098604     EISSN: None     Source Type: Journal    
DOI: 10.1346/CCMN.1997.0450405     Document Type: Article

References (17)

1. Aylmore LAG, Quirk JP. 1967. The micropore size distri-bution of clay mineral systems. J Soil Sci 18:1-17.
2. Aylmore LAG. Sills ID. Quirk JP. 1970a. Surface area of homoionic illite and montmorillonite clay minerals as measured by the sorption of nitrogen and carbon dioxide. Clays Clay Miner 18:91-96.
3. Aylmore LAG, Sills ID. Quirk JP. 1970b. Reply to comment of Thomas, Bohor and Frost on "The surface area of homoionic illite and montmorillonite clay minerals as measured by the sorption of nitrogen and carbon dioxide". Clays Clay Miner 18:407-409.
4. Brook CS. 1955. Nitrogen adsorption experiments on several clay minerals. Soil Sci 79:331-347.
5. Brunauer S, Emmett PH, Teller E. 1938. Adsorption of gases in multimolecular layers. J Am Chem Soc 60:309- 319.
6. 2 and EGME vapors on some soils, clays, and mineral oxides and determination of sample surface areas by use of sorption data. Environ Sci Technol 27:1587-1594.
7. Clementz DM, Mortland MM. 1974. Properties of reduced charge montmorillonite: Tetra-alkylammonium ion exchange forms. Clays Clay Miner 22:223-229.
8. 2-adsorption. J Colloid Interface Sci 21:405-414.
9. Eberl DD, Środon J, Northrop HR. 1986. Potassium fixation in smectites by wetting and drying. In: Davis JA, Hayes KF, editors. Geochemical processes at mineral surfaces, ACS Symp Series 323. Washington, DC: Am Chem Soc. p 296-326.
10. Gast RG, Mortland MM. 1971. Self-diffusion of alkylammonium ions in montmorillonite. J Colloid Interface Sci 37:80-92.
11. Gregg SJ, Sing KSW. 1982. Adsorption, surface area and porosity, 2nd ed. London: Academic Pr. p 61-84.
12. Lee J-F, Mortland MM, Chiou CT, Kile DE, Boyd SA. 1990. Adsorption of benzene, toluene, and xylene by two tetramethylammonium-smetites having different charge densities. Clays Clay Miner 38:113-120.
13. Mooney RW, Keenan AG, Wood LA. 1952. Adsorption of water vapor by montmorillonite. I. Heat of desorption and application of BET theory. J Am Chem Soc 74:1367-1371.
14. van Olphen H, Fripiat JJ. 1979. Data handbook for clay materials and other non-metallic minerals. New York: Pergamon Pr. p 16-25.
15. Remy MJ, Poncelet G. 1995. A new approach to the determination of the external surface and micropore volume of zeolites from the nitrogen adsorption isotherm at 77 K. J Phys Chem 99:773-779.
16. Sing KSW. 1969. Surface area determination. In: Everett DH, Ottewill RH, editors. Proc Int. Symp; 1970. London: Buttersworths. p 25.
17. Thomas J Jr. Bohor BE 1968. Surface area of montmorillonite from the dynamic sorption of nitrogen and carbon dioxide. Clays Clay Miner 16:83-91.