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Volumn 125, Issue 40, 2003, Pages 12351-12357

Unusual chemistry of the complex Mg.+(2-fluoropyridine) activated by the photoexcitation of Mg.+

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL ACTIVATION; COMPLEXATION; ELECTROSTATICS; MAGNESIUM COMPOUNDS; PHOTOCHEMICAL REACTIONS; QUANTUM THEORY; REACTION KINETICS;

EID: 0141888548     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja036476a     Document Type: Article
Times cited : (10)

References (82)
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    • Baer, T.1    Hase, W.L.2
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    • Brody, F.; Ruby, P. R. Heterocyclic Compounds; Klingsberg E., Ed; Pyridine and Derivatives, Part 1; Interscience Publishers: New York, 1960; pp 99.
    • (1960) Heterocyclic Compounds , pp. 99
    • Brody, F.1    Ruby, P.R.2
  • 44
    • 0004227284 scopus 로고
    • Abramovitch R. A., Ed; Suppl., Part 4; John & Sons: New York
    • (a) Coutts, R. T.; Casy, A. F. Pyridine and Its Deravatives: Abramovitch R. A., Ed; Suppl., Part 4; John & Sons: New York, 1975; p 445.
    • (1975) Pyridine and Its Deravatives , pp. 445
    • Coutts, R.T.1    Casy, A.F.2
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    • Holland, J. F., Frei, E., Eds; Lea & Febiger: Philadelphia
    • nd ed.; Holland, J. F., Frei, E., Eds; Lea & Febiger: Philadelphia, 1982; p 801.
    • (1982) nd Ed. , pp. 801
    • Heidelberg, C.1
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    • Neidleman, S. L.; Geigert, J., Ed; Ellis Horwood Limited: Chichester
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    • (1986) Biohalogenation
  • 77
    • 0141974376 scopus 로고    scopus 로고
    • note
    • The trans-form is calculated to be about 1 kcal/mol more stable than A, which central double bond is in the cis form. However, the trans form is difficult to achieve.
  • 81
    • 0142009043 scopus 로고    scopus 로고
    • note
    • In principle, a two-photon process at 245 nm (7.20 eV) would also lead to the formation of P4-B. However, the laser light intensity in our experiment was much weaker at 245 nm than at 344 nm, which made the two-photon process much less likely.
  • 82
    • 0141939704 scopus 로고    scopus 로고
    • note
    • As shown in the SI (Figure S3, (d)), HF elimination from I-1 requires at least 4.38 eV, which is unfavorable compared to that from I-3b.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.