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The trans-form is calculated to be about 1 kcal/mol more stable than A, which central double bond is in the cis form. However, the trans form is difficult to achieve.
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In principle, a two-photon process at 245 nm (7.20 eV) would also lead to the formation of P4-B. However, the laser light intensity in our experiment was much weaker at 245 nm than at 344 nm, which made the two-photon process much less likely.
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82
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note
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As shown in the SI (Figure S3, (d)), HF elimination from I-1 requires at least 4.38 eV, which is unfavorable compared to that from I-3b.
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